• Title/Summary/Keyword: Cu Powder

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Design of Nanocluster Based Material with Catalytic Properties

  • Tadachika Nakayama;Kim, Chang-Yeoul;Tohru Sekino;Choa, Yong-Ho;Takafumi Kusunose;Yamato Hayashi;Koichi Niibara
    • Journal of Powder Materials
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    • v.8 no.3
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    • pp.197-200
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    • 2001
  • Modified inert gas condensation method was used to produce the nanocluster composites of $CuO/CeO_2$. High-resolution TEM, SEM and catalytic measurements have been used to characterize the samples and study the synergistic effect between the CuO phase and $CeO_2$(ceria) support. By varying the He pressure, the heating temperature and configuration of the heating boats inside the modified gas condensation chamber, nanoclusters of varying sizes, shapes and composition can be produced. The composition and nanostructured morphology were shown to influence the catalytic properties of the system. A copper content around 10 at% with a morphology that favors high-energy surfaces of ceria is shown to be beneficial for a high catalytic activity.

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EL Devices for LCD Backlight Based on ZnS:Cu Phosphor (혼합파우더 및 절연박막층을 이용한 PELD의 광학특성)

  • 박수길;조성렬;전세호;엄재석;이주성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.391-394
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    • 1998
  • Electroluminescence is the light emission obtained by an electrical excitation energy passing through a phosphor under an applied high electrical field. EL are paid much attention on flat panel display as a backlight and indicator, which are divided into ACPRL(alternating-current powder electroluminescent) and ACTFEL(alternating-current powder electroluminescent). In this paper, Electric and emission properties on ACPEL are investigated based on ZnS:Cu phosphor. The basic structure on this is ITO glass/phosphor/insulator/ backelectrode, CR-M which has high efficiency on thermal properties and dielectric Properties was introduced and BaTiO$_3$ as a insulating layer in order to increase app1ied electric field on phosphor. Changing on Dielectric and emission Properties was caused by a different viscosity of binder which filled on space between phosphor particle. 60cd/$m^2$ under 60V, 2kHz sinusoidal was gotten from ACPELD prepared in this work.

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Fabrication and Photocatalytic Properties of Visible Light Responsive Cuprous Oxide Cubes

  • Lin, Jiudong;Tao, Feifei;Sheng, Congcong;Li, Jianwei;Yu, Xiaoding
    • Bulletin of the Korean Chemical Society
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    • v.35 no.4
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    • pp.1110-1116
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    • 2014
  • The cuprous oxide cubes with the special porous surface constructed by nano-prisms have been successfully fabricated by a solvothermal method. The template-free method is simple and facile without any surfactant. The X-ray powder diffraction (XRD) pattern suggests that the as-prepared product is the pure primitive cubic $Cu_2O$. The effects of the experimental parameters, such as the reaction temperature, reaction time and the concentration of sodium acetate anhydrous, on the morphologies of the products were investigated in detail by the scanning electron microscopy (SEM). Based on the time-dependent experiments, the possible formation mechanism was proposed. Using photocatalytic degrading reactive dyes as the model reaction and xenon lamp to simulate sunlight, the $Cu_2O$ cubes with the porous surface might possess higher photocatalytic activity than those of the commercial $Cu_2O$ powder in the visible-light region, indicating the excellent photocatalytic performance.

The Effect of SnO2 Addition on Sintering Behaviors in a Titanium Oxide-Copper Oxide System

  • Lee, Ju-Won;Oh, Kyung-Sik;Chung, Tai-Joo;Paek, Yeong-Kyeun
    • Journal of Powder Materials
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    • v.29 no.5
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    • pp.357-362
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    • 2022
  • The low-temperature sinterability of TiO2-CuO systems was investigated using a solid solution of SnO2. Sample powders were prepared through conventional ball milling of mixed raw powders. With the SnO2 content, the compositions of the samples were Ti1-xSnxO2-CuO(2 wt.%) in the range of x ≤ 0.08. Compared with the samples without SnO2 addition, the densification was enhanced when the samples were sintered at 900℃. The dominant mass transport mechanism seemed to be grain-boundary diffusion during heat treatment at 900℃, where active grain-boundary diffusion was responsible for the improved densification. The rapid grain growth featured by activated sintering was also obstructed with the addition of SnO2. This suggested that both CuO as an activator and SnO2 dopant synergistically reduced the sintering temperature of TiO2.

Enhancement of critical current density in $BaCeO_3$ doped $YBa_2Cu_3O_{7-\delta}$ thin Films deposited by TFA-MOD process (TFA-MOD공정에서 $BaCeO_3$ 첨가에 의한 $YBa_2Cu_3O_{7-\delta}$ 박막의 임계전류밀도 증가)

  • Lee, Jong-Beom;Kim, Byeong-Joo;Lee, Hee-Gyoun;Hong, Gye-Won
    • Progress in Superconductivity and Cryogenics
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    • v.10 no.1
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    • pp.1-5
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    • 2008
  • The effect of $BaCeO_3$ doping on the critical current density of YBCO film by TFA-MOD method was studied. $BaCeO_3$ doping was made by two method; one is direct addition of $BaCeO_3$ nano-sized powder prepared by citrate process followed by grinding with planetary ball mill for 10 hours. Another is addition of Ba-Ce precursor solution prepared with Ba-acetate and Ce acetate dissolved in TFA to the YBCO-TFA precursor solution. The film was made by standard dip coating and heat treatment process with conversion temperature of $790^{\circ}C$ in 1000 ppm oxygen containing moisturized Ar gas atmosphere. The direct addition of $BaCeO_3$ powder resulted in YBCO film with good epitaxial growth and no evidence of second phase formation. The addition through precursor solution resulted in the increase of critical current density upto 30 at% doping and uniform dispersion of $BaCeO_3$ fine inclusion was confirmed by SEM-EDX.

The Mordant Effects Used by Natural Tannin Dyed with Lac powder: Tara and Myrobalan (락(Lac) 염색시 천연탄닌의 매염효과: 타라와 미로발란)

  • Bai, Sangkyoung
    • Journal of Fashion Business
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    • v.18 no.4
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    • pp.114-124
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    • 2014
  • This research was carried out to find the mordant effects by Tara and Myrobalan as natural tannins on the cow leather dyed with Lac powder. The cow leathers were treated with Tara, Myrobalan, Al, Cu, and Fe mordants by changing treatment orders. It was examined for K/S value, surface color changes, and color difference. The K/S value generally has higher Myrobalan than Tara, and pre-mordant than post-mordanted condition. Cu is the strongest among the three mordants. As a results of the treatment order, the K/S value is higer in pre-tannin-mordant agent than in pre-mordant agent-tannin. In the post mordant, K/S value is higher in mordant agent-tannin than in tannin-mordant agent. The color difference and color factors such as H, V and C were various according to the mordant agents, treatment orders and mordant methods; and surface colors of dyed cow leathers were R and RP. It was difficult to find some significant means of mordant orders.

Microstructures and Repeated Usage-Properties of de-$NO_{x}$ Transition Metals/ZSM-5 Catalyst Made by Mechanical Alloying Method (기계적합금화법을 이용하여 제조된 $NO_{x}$ 제거용 천이금속/ZSM-5촉매의 미세구조 및 반복사용특성)

  • 조규봉;안인섭;남태현
    • Journal of Powder Materials
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    • v.5 no.4
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    • pp.273-278
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    • 1998
  • $De-NO_x$ transition metals(Cu, Co)/ZSM-5 catalyst was made by mechanical alloying method, and their microstructures and repeated usage-properties were investigated by scanning electron microscopy, transmission electron microscopy and X-ray diffraction. The conversions ability of NO in the catalyst was measured. A part of ZSM-5 in CO/ZSM-5 composite powders was amorphous and the amorphous phase became less stable with increasing Co content. Conversion ability of NO in 10Cu/ZSM-5 powders decreased from 89% to 12% and that in 10Co/ZSM-5 decreased from 22% to 17% by 7 times conversion tests.

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Columnar Structural Growth in Molten Filler Metal during Brazing of Dissimilar Materials (이종재의 브레이징 계면에서 주상 조직의 성장 기구)

  • 김정석
    • Journal of Powder Materials
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    • v.4 no.4
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    • pp.252-257
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    • 1997
  • Cu-brazed layer between the sintered-cam(Fe-5Cr-lMo-0.5P-2.5C, wt%) and seamless steelpipe(0.25-0.35C, 0.3-1.0 Mn, bal Fe, wt%) in the camshaft shows a columnar structure of $\gamma$-phase growing from the steel pipe. Liquid phase sintered 60Fe-40Cu alloys are carburized to simulate the brazing process giving rise to the columnar growth. Liquid film migrations and columnar growth of $\gamma$-grains are observed in the carburized regions. The $\gamma$-grains grow in the same direction as the C-diffusion. Fe-solubility in the liquid of carburized region is higher than in the uncarburized by about 0.3 at%. The columnar growth is driven by the gradient of the supersaturated Fe-solute in the liquid between two adjacent $\gamma$-grains.

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Peculiarities of SHS and solid state synthesis of $ReBa_{2}Cu_{3}O_{7-x}$ materials

  • Sho, Dea-Wha;Li, Yingmei;Cho, Yong-Joon;Kim, Tae-Wan;Korobova, N.;Isaikina, O.;Mansurov, Z.;Baydeldinova, A.;Ksandopoulo, G.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.620-623
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    • 2001
  • The peculiarities of using Self-propagating High-temperature Synthesis (SHS) and solid state phase synthesis for production of high temperature superconductor materials are discussed. Oxide superconductors with general formula $ReBa_2$$Cu_3$$O_{7-x}$ (Re= Y, Yb, Sm, Nd) have been made with using barium oxide initial powder instead of traditional barium carbonate. X-ray powder diffraction showed a single phase orthorhombic perovskite structure was produced in all reactions. Phenomena observed during the grinding of the reactant mixture are presented. Mechano-chemical activation - as a pretreatment of the reactant mixture - strongly influences the kinetic parameters, the reaction mechanism, and the composition and structure of the final product.

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