• 한국정보디스플레이학회:학술대회논문집
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• 2003.07a
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• pp.585-588
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• 2003

We have studied how rubbing direction affects generation of disclination line in transmissive microdisplay for $90^{\circ}$ twisted nematic (TN) mode with pixel size of $22.2{\mu}m$. The rubbing direction of bottom substrate is changed from $0^{\circ}$ to $-135^{\circ}$ with a decrease step of $45^{\circ}$, and the results show that the generation regions of the disclination line are of a smallest size in $-135^{\circ}$ direction. The results were the same although the pixel size decreased. Consequently, the use of proper rubbing direction of liquid crystal can help overcome the problems of low aperture ratio and low contrast ratio in transmissive-type microdisplays. In addition, the pretilt angle of initial liquid crystal is found to make an important contribution to generation of the disclination line.

• Korean Chemical Engineering Research
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• v.55 no.3
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• pp.279-286
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• 2017

This review paper evaluates different kinds of synthesis methods for calcite precipitated calcium carbonates by using different materials. The various processing routes of calcite with different compositions are reported and the possible optimum conditions required to synthesize a desired particle sizes of calcite are predicted. This paper mainly focuses on that the calcite morphology and size of the particles by carbonation process using loop reactors. In this regard, we have investigated various parameters such as $CO_2$ flow rate, Ca $(OH)_2$ concentration, temperature, pH effect, reaction time and loop reactor mechanism with orifice diameter. The research results illustrate the formation of well-defined and pure calcite crystals with controlled crystal growth and particle size, without additives or organic solvents. The crystal growth and particle size can be controlled, and smaller sizes are obtained by decreasing the Ca $(OH)_2$ concentration and increasing the $CO_2$ flow rate at lower temperatures with suitable pH. The crystal structure of obtained calcite was characterized by using X-ray diffraction method and the morphology by scanning electron microscope (SEM). The result of x-ray diffraction recognized that the calcite phase of calcium carbonate was the dominating crystalline structure.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.6 no.3
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• pp.449-462
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• 1996

On the reaction crystallization of lanthanum oxalate effects of operation conditions of impeller speed, concentration and feed rate of reactant, and reaction temperature on the nucleation and growth of crystals were investigated experimentally. In general, at low supersation the analysis of crystallization processes is relatively clear. However, at high wupersaturation, which is usually applied in industrial crystallization, the processes are exhibited in much complication. In this study the lanthanum oxalate was crystallized by the reaction crystallization of high concentration of lanthanum chloride and oxalic acid in single-jet semi batch reactor. Agitation of solution and suspension in the reactor influenced to enhance the reaction process and crystal growth process which gave opposite effect on the crystallization of lanthanum oxalate. In our experiment since increase of impeller speed gave more influence on the reaction process rather than on the crystal growth process, the supersaturation concentration increased with increase of impeller speed, then resulted in decrease of mean crystal size. By the same effect of reactant concentration and feed rate, the decrease of mean crystall size of lanthanum oxalate was observed with increasing the reactant concentration and feed rate. In case of increasing reaction temperature, the mean crystal size increased. The morphology of lanthanum oxalate crystal was not changed within the variation ranges of the operation conditions which were applied in our experiment.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2001.05a
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• pp.209-212
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• 2001

It is known that the mim forming processes show somewhat different phenomena compared with the conventional metal forming processes, namely, the size effect, enhanced friction effect and etc. Such typical phenomena, however, are not predicted by the conventional finite element analysis, which has been an efficient numerical tool to predict the metal forming processes. It is due to the fact that the constitutive relations used does not describe the microstructural characteristics of the materials. In the present investigation, the finite element formulation using the rate-dependent rigid plastic crystal plasticity model of the face-centered cubic materials is conducted to predict the micro mechanical behaviors during the mim forming processes. The finite element analysis, however, provides mesh-dependent solutions for the intragranular deformations. Therefore, the couple stress energy is additionally introduced into the variational principle and formulated within the framework of the rigid plastic finite element method to obtain mesh-independent solutions. Micro deformations of single crystal and bicrystal with various orientations are calculated to show the potential of the developed formulation.

• Korean Journal of Materials Research
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• v.25 no.2
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• pp.81-89
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• 2015

A strain-gradient crystal plasticity constitutive model was developed in order to predict the Hall-Petch behavior of a Ni-base polycrystalline superalloy. The constitutive model involves statistically stored dislocation and geometrically necessary dislocation densities, which were incorporated into the Bailey-Hirsch type flow stress equation with six strength interaction coefficients. A strain-gradient term (called slip-system lattice incompatibility) developed by Acharya was used to calculate the geometrically necessary dislocation density. The description of Kocks-Argon-Ashby type thermally activated strain rate was also used to represent the shear rate of an individual slip system. The constitutive model was implemented in a user material subroutine for crystal plasticity finite element method simulations. The grain size dependence of the flow stress (viz., the Hall-Petch behavior) was predicted for a Ni-base polycrystalline superalloy NIMONIC PE16. Simulation results showed that the present constitutive model fairly reasonably predicts 0.2%-offset yield stresses in a limited range of the grain size.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.22 no.6
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• pp.265-268
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• 2012

The growth of AlN single crystals of large size and good quality is of prime importance for UV LEDs and power devices applications. However, the crystals having the size of more than 1 inch and high quality have not been reported in the world. In the PVT growth of AlN, the crystal morphology of as grown were important because the preferred orientation of growth of it was evaluated for growth rate increase. In the present study, the AlN single crystals grown by PVT process were evaluated by the side of the growth morphology. Optical microscopic characterization was carried out to observe the shape of the crystals and the growth facets. Furthermore the growth habit of it were discussed by observation of the surface of AlN crystals.

• Proceedings of the Korea Association of Crystal Growth Conference
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• 1999.06a
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• pp.253-269
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• 1999

The development of telecommunication and information technology requires to develop new piezoelectric materials with small size, low impedance, wide pass band width and high thermal stability of frequency. Langasite (La3Ga5SiO14) single crystal has been researched substitute of quartz and LiNbO3 for the applications of SAW filter, BAW filter and resonator. Its single crystal growth has been carried out by Czochralski Method. So, in order to get single crystal with higher quality, in this study, lnagasite (La3Ga5SiO14) single crystal was grown by using Floating Zone (FZ) method and characterized. For the growth of langasite single crystals, the langasite powder was synthesized at 135$0^{\circ}C$ for 5hrs and the feed rod was sintered at 135$0^{\circ}C$ for 5hrs. The growing rate was 1.5mm/h and the rotation speed was 15 rpm for an upper rotation and 13 rpm for a lower rotation. In order to prevent the evaporation of gallium oxide, Ar and O2 gas mixture was flowed. The growth direction was analyzed by Laue back-scattered analysis. The composition of grown crystal was analyzed suing XRD and WDS. The electrical properties of grown crystal at various frequencies and temperature were discussed.

• Journal of Information Display
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• v.3 no.3
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• pp.17-23
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• 2002

In this work we report methods of formation of three-dimensional structures of particles in a liquid crystal host. We found that, under the appropriate conditions, the particles are captured and dragged by the moving isotropic/nematic front during the phase transition process. This movement of the particles can be enhanced significantly or suppressed drastically with the influence of an electric field and/or with changing the conditions of the phase transition, such as the rate of cooling. As a result, a wide variety of particle structures can be obtained ranging from a fine-grained cellular structure to stripes of varying periods to a course-grained "root" structures. Changing the properties of the materials, such as the size and density of the particles and the surface anchoring of the liquid crystal at the particle surface, can also be used to control the morphology of the three-dimensional particle network and adjust the physical properties of the resulting dispersions. These particle structures may be used to affect the performance of LCD's much as polymers have been used in the past.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.4 no.1
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• pp.76-82
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• 1994

Single crystals of Potassium Titanyl Phosphate (KTP) were grown from the flux of $K_6P_4O_13(K_6)$ using a high temperatures solution growth method. To grow the large KTP crystal without inclusion, the temperature gradient in furnace, crystal rotation, orientation of seed crystal, and the cooling rate were controled. The KTP crystals are up to $10(a){\times}28(b){\times}33(c)mm^3$ in size. We investigated the optical inhomogeneity in this KTP crystal by the SHG power measurement and TEM analysis.

• Proceedings of the Korea Association of Crystal Growth Conference
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• 1997.10a
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• pp.13-19
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• 1997

From the formation of the monodispersed silica particle which is a valuable for the industry by Sol-Gel process, the effects of the parameters participated in the process, the growth mechanism and the characteristics of silica particles for each rection conditions are investigated. To investigate about the formation of final silica particles, the suspension which performs the polymerization is reacted with molybdic acid, and the evolutions of TEOS and silica particle size are investigated in the reaction time ？ 새 the characteristics of molybdic acid with the suspension. From the results, a constant number of silica particle is formed at early reaction stage. Silica particles grow through the aggregation of smaller particles and nucleation is rate-limiting step for the growth of particles. In the conditions of this study, spherical silica particles are formed, [NH$_3$] and [$H_2O$] concentration increase the particle size but particle size decrease with [$H_2O$] concentration which is a certain above region. Average particle sizes are 187.4~483.3 nm and standard deviations in the average particle size are 1.7~2.9% with each experimental condition. From the BET results, specific surface area is 5.5~23.4 $m^2$/g and these values decrease with increase size. The average pore size is 50~70$\AA$.