• Journal of the Korean Chemical Society
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• v.42 no.4
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• pp.443-448
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• 1998

The thermodynamic parameters for the interaction of metal ions with dibenzo-16-crown-5 and its derivatives have been determined by solution calorimetry in methanol at 25$^{\circ}C$. Thermodynamic properties of log K, ${\Delta}H$, and $T{\Delta}S$ have been determined for the complexation of metal cations by dibenzo-16-crown-5 and its derivatives. Dibenzo-16-crown-5 and its derivatives have been studied as metal cations carrier in bulk liquid membrane (BLM) and supported liquid membrane (SLM) system. $Ag^+$ has been much more transported using dibenzo-16-crown-5 derivatives as carriers and several other metal cations have been small transported using carrier in BLM and SLM system. Ligand structure, the length of side arm, donor atom, stability constant, and carrier concentration are also important parameters in the transport of cations.

• Proceedings of the Korean Society of Broadcast Engineers Conference
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• 2022.06a
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• pp.78-80
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• 2022

Strawberry (Fragaria × ananassa) cultivation methods are rapidly changing from traditional soil cultivation to high bed hydroponics, which are easy to agricultural working. The objective was to evaluate the growth characteristics of three strawberry cultivars cultivated high bed system. The "Seolhyang", "Altaking", and "Keumsil" strawberry plants were transplanted in a glass-type greenhouse at Kyungpook National University Gunwi Agricultural Field. The cultivation period was approximately seven months from September 17, 2021 to April 21, 2022. Growth parameters measured including the number of leaves, plant height, petiole length, leaf length, leaf width, and crown diameter at two-week intervals. The environmental parameters for each location in the greenhouse were collected. Plant height in all cultivars continued to decrease from the early stage to the late stage of growth. The crown diameter was increased by 50 DAT, and then gradually decreased until late growth stage in all cultivars. Results indicated that the growth parameters represented to vary according to the cultivar of strawberry plants.

• Journal of the korean academy of Pediatric Dentistry
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• v.27 no.1
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• pp.98-102
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• 2000

Ectopic eruption is out of a normal position by local eruption disturbance in the developing permanent molar. The prevalence of ectopic eruption is reported to be the between 2 and 6%, most often associated maxillary first permanent molar whereas, the occurrence for the mandibular is quite rare. The etiologic factors of ectopic eruption are inadequate arch length, lack of growth in the posterior region of the jaw, mesially inclined eruption path of first permanent molars, abnormally large first permanent molars, hereditary factor and a stainless steel crown which has been improperly restored. Ectopic eruption can be treated by the use of brass wire, separating elastics, distal disking and Humphrey appliance and the use of removable appliance and cervical traction headgear after extraction of the second primary molar. This case was that lower right first permanent molar was mesially tilted state by locking on the stainless steel crown of a lower right second primary molar. The stainless steel crown was removed and Humphrey appliance was set. Like this case, ectopic eruption could be happened by the stainless steel crown which improperly restored. In restoration of the stainless steel crown, selection of proper size, trimming and contouring are very important.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.36 no.3
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• pp.254-258
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• 1991

Experiment was conducted to investigate the effects of size of root crown at transplanting and fertilization on the growth and root yield of Angelica gigas Nakai. Plant height and fresh weight of shoots were increased by fertilizer application, but was not different in emergence rate. Size of root crown at transplanting was also affected the growth of shoot. Plant which had 7.2mm of root crown at transplanting showed highest in plant height and fresh weight of shoots. Growth of root in terms of root length, number of root branches, diameter of root crown, and fresh weight of root was increased by fertilizer application and 5.4mm of root crown at transplanting. Application of fertilizer accelerated the development and growth of node on the stem, which in turn resulted bolting and flowering. Plants which had greater than 7.2mm of root crown at transplanting and application of fertilizer were produced woody roots. Woody roots cannot be used for medicinal purpose. Therefore, yield of roots was highest at transplanting of 3.lmm root crown with fertilizer application.

• Journal of Oral Medicine and Pain
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• v.4 no.1
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• pp.22-30
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• 1979

In order to evaluate the normal eruption time of Korean permanent teeth, the uthor had examined the eruption phases of permanent central incisors in 714 malw and 581 female children aged from 4.5 to 9-year old and analysed. The eruption was divided into 3 phases; the tip of crown can be seen, the half of the crown can be easily seen, and full length of the crown can be seen. The obtained results were as follows : 1. It seemed that percentage of the erupting and erupted permanent central incisor in female by age was higher than that of male. 2. In general, percentage of the erupting and erupted lower central incisor by age was higher than that of upper first molar.

• Bulletin of the Korean Chemical Society
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• v.27 no.11
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• pp.1737-1740
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• 2006

The optimized structures and complexation energies of bis(18-crown-6-ether) analogue (2) of Trgers base (1) with a series of primary alkylbisammonium ions have been calculated by DFT B3LYP/6-31G(d,p) method. The calculated complexation efficiency (-142.84 kcal/mol) of 2 for butane-1,4-diylbisammonium guest is better than twice of the value (-61.40 kcal/mol) for butylammonium ion. The multiple hydrogen-bond abilities for the complexes are described as the function of the length of the alkyl substituents of the bisammonium guests with normal-alkyl chain [$-(CH_2)_{n-}$, n = 4-8]. The longer bisammonium guest shows the stronger hydrogen-bonding characterizations (the distance and the quasi-linear angle of the N-H…O) to the host 2 than the shorter bisammonium ions. These calculated results agree with the experimental data of the complexation of 2 with bisammonium salts ([$NH_3(CH_2)_nNH_3$] $Cl_2$).

• Bulletin of the Korean Chemical Society
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• v.25 no.11
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• pp.1641-1644
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• 2004

Several [2]- and [3]rotaxanes bearing some functional groups on their wheel components and spacers with different lengths between two ammonium centers on their dumbbell components were prepared in good yields from dibenzo-24-crown-8-ether derivatives and dumbbell-shaped bis(sec-ammonium salt)s having a centrally located disulfide linkage, by utilizing the reversible thiol-disulfide interchange reaction. The shuttling behaviors of the [2]rotaxanes were investigated by $^1H$ NMR by use of the spin polarization transfer-selective inversion recovery technique. It was found that the change in spacer length in the axle resulted in a drastic change in shuttling rate of the [2]rotaxanes, although the introduction of the functional groups to the wheels did not affect the shuttling behavior at all.

• Journal of Korean Port Research
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• v.9 no.2
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• pp.51-64
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• 1995

Generally, it is pointed out that the submerged breakwater with one row can not regulate the long period waves efficiently, because the crown width is very shorter than the wave length of the long period waves. Therefore, the wide crown is needed to raise the controlling efficiency for the long period waves. This study picks up the submerged breakwater with two rows which has smaller construction materials comparing to the one row and discusses the wave controlling function for the long period waves. Judging from the results obtained by using the strict dividing region method, the submerged breakwater with two rows can more regulate the long period waves than one row can, especially, in case that crown width and inner width of its construction come to be wider.

• Korean Journal of Agricultural and Forest Meteorology
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• v.21 no.4
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• pp.277-285
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• 2019

This study was conducted to understand the growth characteristics of Picea jezoensis that was one of representative subalpine species in Korea, in the light of the effects of wind and micro-topography in its habitats on Mt. Deogyu, Korea. The prevailing wind directions were southwest and west at the study sites. We randomly selected P. jezoensis (height ≥ 1.5 m) on windward, intermediate, and leeward slopes and measured diameter at breast height (DBH), height, crown length by 8 directions in upper, middle and lower sectors of the crown. We examined the micro-topography of P. jezoensis stood on and classified it into 3 types: type 1 was mounded and fully exposed to surrounding environments without neighboring trees; type 2 was somewhat wind-protected by surrounding rocks, but no neighboring vegetation; type 3 was on gentle slope or flat where P. jezoensis grew with neighboring trees or shrubs. The ratios of height to DBH, and estimated crown growth to actual crown growth (hereafter crown growth ratio) were compared among the three types of micro-topography on windward, intermediate and leeward sites. The height growth per DBH and crown growth ratio in the upper and middle crowns were the smallest on the windward site, and the highest on the leeward site (p < 0.01). The crown growth ratio on type 1 on the windward site was only 46% of that on type 3 on the leeward site. Although on the same windward slope, trees on type 1 had more deformed crown shapes than that on Type 3, showing asymmetric crown cross-sectional areas. Wind and micro-topography played critical roles on the crown growth of P. jezoensis.

• Korean Journal of Remote Sensing
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• v.36 no.6_1
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• pp.1291-1302
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• 2020

To verify the field-effectiveness of Terrestrial Laser Scanner (TLS), a terrestrial LiDAR was deployed to examine the damage properties of woods in forest fire area, then the data was compared with the results surveyed by a forestry expert. Four sample plots (30 m × 50 m, 0.15 ha) were set from the foot to the top of the mountain, and DBH, height, clear length, burned height, and crown length were investigated. Next, TLS collected information on damage characteristics found in the sample plots. This information was then compared with that amassed by the expert. The expert and the TLS survey results showed 30.8 cm and 29.9 cm for DBH, 15.8 m and 17.5 m for tree height, 8.4 m and 8.4 m for clear length, 4.0 m, 3.5 m for burned height, and 7.4 cm and 9.1 cm for crown length. With the exceptions of height and clear length, no notable discrepancy was observed between two methods. H/D ratio, CL/H ratio, and BH/CL ratio, all of which contribute to stability and decay rate of the stand, from the two methods were also compared. The human survey rated each ratio (H/D, CL/H, BH/CL in order) 51.3%, 47.1%, and 53.6%, while the TLS presented the results of 58.8%, 52.0%, and 38.7%.