• Title/Summary/Keyword: Cross-Coupling Effect

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Ligand Effect in Recycled CNT-Pd Heterogeneous Catalyst for Decarboxylative Coupling Reactions

  • Kim, Ji Dang;Pyo, Ayoung;Park, Kyungho;Kim, Gwui Cheol;Lee, Sunwoo;Choi, Hyun Chul
    • Bulletin of the Korean Chemical Society
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    • v.34 no.7
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    • pp.2099-2104
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    • 2013
  • We present here an efficient and simple method for preparation of highly active Pd heterogeneous catalyst (CNT-Pd), specifically by reaction of dichlorobis(triphenylphosphine)palladium ($Pd(PPh_3)_2Cl_2$) with thiolated carbon nanotubes (CNTs). The as-prepared CNT-Pd catalysts demonstrated an excellent catalytic activity for the carbon-carbon (C-C) cross-coupling reactions (i.e. Suzuki, Stille, and decarboxylative coupling reactions) under mild conditions. The CNT-Pd catalyst could easily be removed from the reaction mixture; additionally, in the decarboxylative coupling of iodobenzene and phenylpropiolic acid, it showed a six-times recyclability, with no loss of activity. Moreover, once its activity had decreased by repeated recycling, it could easily be reactivated by the addition of phosphine ligands. The remarkable recyclability of the decarboxylative coupling reaction is attributable to the high degree of dispersion of Pd catalysts in CNTs. Aggregation of the Pd catalysts is inhibited by their strong adhesion to the thiolated CNTs during the chemical reactions, thereby permitting their recycling.

Fully Adaptive Feedforward Feedback Synchronized Tracking Control for Stewart Platform Systems

  • Zhao, Dongya;Li, Shaoyuan;Gao, Feng
    • International Journal of Control, Automation, and Systems
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    • v.6 no.5
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    • pp.689-701
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    • 2008
  • In this paper, a fully adaptive feedforward feedback synchronized tracking control approach is developed for precision tracking control of 6 degree of freedom (6DOF) Stewart Platform. The proposed controller is designed in decentralized form for implementation simplicity. Interconnections among different subsystems and gravity effect are eliminated by the feedforward control action. Feedback control action guarantees the stability of the system. The gains of the proposed controller can be updated on line without requiring any prior knowledge of Stewart Platform manipulator. Thus the control approach is claimed to be fully adaptive. By employing cross-coupling error technology, the proposed approach can guarantee both of position error and synchronization error converge to zero asymptotically. Because the actuators work in synchronous manner, the tracking performances are improved. The corresponding stability analysis is also presented in this paper. Finally, simulation is demonstrated to verify the effectiveness of the proposed approach.

Vibration Analysis of a Rotating Multi-Packet Blade System Having Tapered Cross Section (회전하는 테이퍼 단면 다중 패킷 블레이드 시스템의 진동 해석)

  • Kim, Min-Kwon;Yoo, Hong-Hee
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.832-837
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    • 2008
  • A modeling method for the modal analysis of a multi-packet blade system having tapered cross section undergoing rotational motion is presented in this paper. Blades are idealized as tapered cantilever beams that are fixed to a rotating disc. The stiffness coupling effects between blades due to the flexibilities of the disc and the shroud are modeled with discrete springs. Hybrid deformation variables are employed to derive the equations of motion. To obtain more general information, the equations of motion are transformed into dimensionless forms in which dimensionless parameters are identified. The effects of the dimensionless parameters including tapered ratio and the number of packets as well as blades on the modal characteristics of the system are investigated with some numerical examples.

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Coupling effects of vortex-induced vibration for a square cylinder at various angles of attack

  • Zheng, Deqian;Ma, Wenyong;Zhang, Xiaobin;Chen, Wei;Wu, Junhao
    • Wind and Structures
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    • v.34 no.5
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    • pp.437-450
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    • 2022
  • Vortex-induced vibration (VIV) is a significant concern when designing slender structures with square cross sections. VIV strongly depends on structural dynamics and flow states, which depend on the conditions of the approaching flow and shape of a structure. Therefore, the effects of the angle of attack on the coupling effects of VIV for a square cylinder are expected to be significant in practice. In this study, the aerodynamic forces for a fixed and elastically mounted square cylinder were measured using wind pressure tests. Aerodynamic forces on the stationary cylinder are firstly discussed by comparisons of variation of statistical aerodynamic force and wind pressure coefficient with wind angle of attack. The coupling effect between the aerodynamic forces and the motion of the oscillating square cylinder by VIV is subsequently investigated in detail at typical wind angels of attack with occurrence of three typical flow regimes, i.e., leading-edge separation, separation bubble (reattachment), and attached flow. The coupling effect are illustrated by discussing the onset of VIV, characteristics of aerodynamic forces during VIV, and interaction between motion and aerodynamic forces. The results demonstrate that flow states can be classified based on final separation points or the occurrence of reattachment. These states significantly influence coupling effects of the oscillating cylinder. Vibration enhances vortex shedding, which creates strong fluctuations in aerodynamic forces. However, differences in the lock-in range, aerodynamic force, and interaction process for angles of attack smaller and larger than the critical angle of attack revealed noteworthy characteristics in the VIV of a square cylinder.

Resonant Transmission through C-Shaped and H-Shaped Small Apertures and the Mutual Coupling Effect between Two C-Shaped Apertures (C-형태와 H-형태의 소형 개구에 의한 공진 투과 및 C-형태 개구 간의 상호 결합 효과)

  • Ko, Ji-Hwan;Cho, Young-Ki
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.23 no.12
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    • pp.1399-1405
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    • 2012
  • Transmission cross section characteristics as a measure of transmission efficiency has been analyzed numerically for the H-shaped and C-shaped small apertures in the infinite conducting plane when illuminated by a plane wave. It has been found that C-shaped aperture has the larger transmission cross section than that of H-shaped aperture under the condition of the same perforated aperture area. Main attention has been focused on studying the mutual coupling effect between two C-shaped apertures on the transmission cross section characteristic. Parallel configuration which is composed of two C-shaped apertures arranged along the x-axis and collinear configuration which is composed of two C-shaped arrayed along the y-axis have been investigated from the viewpoint of enhanced transmission cross section characteristics.

Vibration of vehicle-bridge coupling system with measured correlated road surface roughness

  • Han, Wanshui;Yuan, Sujing;Ma, Lin
    • Structural Engineering and Mechanics
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    • v.51 no.2
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    • pp.315-331
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    • 2014
  • The present study investigated the effect of the correlation of the measured road roughness profiles corresponding to the left and right wheels of a vehicle on the vibration of a vehicle-bridge coupling system. Four sets of road roughness profiles were measured by a laser road-testing vehicle. A correlation analysis was carried out on the four roughness samples, and two samples with the strongest correlation and weakest correlation were selected for the power spectral density, autocorrelation and cross-correlation analyses. The scenario of a three-axle truck moving across a rigid-frame arch bridge was used as an example. The two selected road roughness profiles were used as inputs to the vehicle-bridge coupling system. Three different input modes were adopted in the numerical analysis: (1) using the measured road roughness profile of the left wheel for the input of both wheels in the numerical simulation; (2) using the measured road roughness profile of the right wheel for both wheels; and (3) using the measured road roughness profiles corresponding to left and right wheels for the input corresponding to the vehicle's left and right wheels, respectively. The influence of the three input modes on the vibration of the vehicle-bridge system was analyzed and compared in detail. The results show that the correlation of the road roughness profiles corresponding to left and right wheels and the selected roughness input mode both have a significant influence on the vibration of the vehicle-bridge coupling system.

Decupling Vector Control for High Speed Synchronous Reluctance Motor (고속 동기 릴럭턴스 전동기 비간섭 벡터제어)

  • 김민태;백동기;최재동;성세진;전칠환
    • Proceedings of the KIPE Conference
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    • 1999.07a
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    • pp.155-158
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    • 1999
  • In the high speed range for Vector control of Synchronous Reluctance Motor, the effect of iron loss and the cross-coupling of dq axis currents is dependent on the increase of the operating frequency can not be negligible. In this paper, we propose a decupling Vector control of dq axis current that the effect of iron loss is eliminated, and confirm that through simulation results.

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Effects of Misalignment of High Speed Flexible Coupling on the Fighter Aircraft Transmission Characteristics

  • Samikkanu, Nagesh;Basha, Abu Muhammed Junaid
    • International Journal of Fluid Machinery and Systems
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    • v.5 no.2
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    • pp.91-99
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    • 2012
  • The Fighter aircraft transmission system consists of a light weight, High Speed Flexible Coupling (HSFC) known as Power Take-Off shaft (PTO) for connecting Engine gearbox (EGB) with Accessory Gear Box (AGB). The HSFC transmits the power through series of specially contoured metallic annular thin flexible plates whose planes are normal to the torque axis. The HSFC operates at high speed ranging from 10,000 to 18,000 rpm. The HSFC is also catered for accommodating larger lateral and axial misalignment resulting from differential thermal expansion of the aircraft engine and mounting arrangement. The contoured titanium alloy flexible plates are designed with a thin cross sectional profile to accommodate axial and parallel misalignment by the elastic material flexure. This paper investigates the effect of misalignment on the transmission characteristics of the HSFC couplings. A mathematical model for the HSFC coupling with misalignment has been developed for analyzing the torque transmission and force interaction characteristics. An extensive testing has been conducted for validating characteristics of the designed coupling under various misalignment conditions. With this the suitability of the model adapted for the design iteration of HSFC development is validated. This method will reduce the design iteration cycles of HSFC and can be extended for the similar development of flexible couplings.

Analysis of Coupled Horizontal-Torsional Vibrations of Container Ships (콘테이너선의 수평-비틂연성진동 해석)

  • K.C.,Kim;S.J.,Kim
    • Bulletin of the Society of Naval Architects of Korea
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    • v.23 no.4
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    • pp.1-10
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    • 1986
  • A container ship, due to wide hatch openings, has characteristics of poor torsional rigidity, strong coupling of horizontal-torsional modes and significant discontinuity in the longitudinal variation of hull sections. In the mathematical formulation of the problem the hull is modeled as a beam and the transfer matrix method is utilized. The cross decks between cargo hatch opening are separated from the main hull and regarded as equivalent springs restraining torsion of hull. The effect of shear deformation of ship-side plating on torsion is taken into account in addition to St. Venant's and bending torsional rigidities. Compatibility requirements at cross section discontinuity are approximately considered. Developing the practical calculation procedure and the computer programs for application to an actual ship, some parametric studies on modeling methods of the cross deck, the compatibility condition, added-mass center etc. are out for the purpose of comparison.

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Optical Disk Drive Servo System Using Dual Disturbance Observer

  • Lee, Sang-Han;Jeong, Dong-Seul;Chung, Chung-Choo
    • 제어로봇시스템학회:학술대회논문집
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    • 2005.06a
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    • pp.2087-2092
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    • 2005
  • Using disturbance observer (DOB) is effective in enhancing the performance of dynamic system in the presence of disturbances. Recently the definition of disturbance has been expanded to modeling uncertainty including parameter variation, internal disturbance. Various structures of DOB have been proposed to improve sensitivity of system for better disturbance rejection performance. However in the case of improvement of sensitivity function, it tends to bring poor transient response due to cross-coupling and phase lag. Furthermore it could be very sensitive to measurement noise due to increased peak of complementary sensitivity function. In this paper, a dual disturbance observer (Dual-DOB) is proposed to reduce the effect of such cross-coupling. It is possible for us to improve the sensitivity function with additional external DOB with hardly affecting complementary sensitivity function. Thus it is able to have robustness against measurement noise. Since we are able to design DOBs of internal and external loop independently, we could prevent transient response quality from degrading while improving the sensitivity function. The proposed Dual-DOB is applied to a commercial optical disk drive tracking servo system. The experimental result shows that the Dual-DOB is an effective method in rejecting the disturbance as well as improving the tracking performance.

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