• Polymer(Korea)
• /
• v.38 no.2
• /
• pp.257-264
• /
• 2014

In this study, we modified silica nanoparticles with bis[3-(trimethoxysilyl)propyl]ethylenediamine (BTPED) silane coupling agent, which has two secondary amino groups in a molecule, to introduce amino groups on the silica surface. After modification of silica, we used acrylate group containing 3-(acryloyloxy)-2-hydroxypropyl methacrylate (AHM) to introduce polymerizable methacrylate groups by Michael addition reaction. We used Fourier transform infrared spectroscopy (FTIR), elemental analysis (EA) and liquid and solid state cross polarization magic angle spinning (CP/MAS) nuclear magnetic resonance spectroscopy (NMR) to understand the reactions between N-H groups of BTPED modified silica surface and acrylate groups of AHM monomer. We confirmed Michael addition reaction between BTPED modified silica and AHM completed in 2 hr reaction time. We also found increased methacrylate group introduction with increase of mol ratio of the acrylate group of AHM to N-H group of BTPED modified silica by increase of C=O peak area of measured FTIR spectra. These results were also supported by EA and solid state $^{13}C$ and $^{29}Si$ NMR results.

• The Journal of the Korea Contents Association
• /
• v.7 no.11
• /
• pp.76-83
• /
• 2007

In the sequentially rotated array antennas, the characteristics of antenna gain, axial ratio and cross polarization have been analyzed with a varying of sequential array constant(number of array element, figure of rotation) respectively. Where the antenna element of array is a probe feeding, LHCP truncated microstrip antenna whose resonant frequency is in 11.85GHz. The simulation results of 23 SRA antennas((M=2, 3, 4, 6, 8), $(1\leqP\leqM)$) has shown as follows. The widest 3dB bandwidth of axial ratio appears at P=2 which is in-dependant of M, the highest antenna gain appears when a sequential array constant has a pair of (2, 1), (3, 2), (4, 1), (6, 3), (8, 1) respectively. Specially, all of the SRA antenna appear very poor characteristics in case of M=P. Therefore the SRA antenna has to be designed as selecting a optimal sequential array constant among a lot of simulation data.

• Journal of the Institute of Electronics Engineers of Korea TC
• /
• v.46 no.7
• /
• pp.52-60
• /
• 2009

In this pater, a CP-DRA(Circularly Polarized Dielectric Resonator Antenna) using cross-slot-feed is studied to enhance the gain and axial ratio bandwidth. First, a single layer CP-DRA is studied as a reference for comparison. Then a new type of multilayer CP-DRA is proposed to enhance the gain and axial ratio bandwidth. In consideration of the antenna gain enhancement, the spacing between the elements of the multilayer CP-DRA is examined through analysis of the radiation performance of a 2$\times$2 planar amy of DRAs with a spacing of 0.7$\lambda_0$ and 1.2$\lambda_0$ using CST Microwave Studio. The measured result shows that the gain and bandwidth of the multilayer structure is approximately twice that of the single layer one. In the case of the array antenna in which the spacing between multilayer CP-DRA element is 1.2$\lambda_0$, a grating lobe is reduced, in contrast to what we can expect from a conventional antenna array. The gain is 13.4dBi and axial ratio bandwidth is 0.8GHz.

• Korean Journal of Materials Research
• /
• v.19 no.2
• /
• pp.90-94
• /
• 2009

The development of low-k materials is essential for modern semiconductor processes to reduce the cross-talk, signal delay and capacitance between multiple layers. The effect of the $CH_4$ concentration on the formation of SiOC(-H) films and their dielectric characteristics were investigated. SiOC(-H) thin films were deposited on Si(100)/$SiO_2$/Ti/Pt substrates by plasma-enhanced chemical vapor deposition (PECVD) with $SiH_4$, $CO_2$ and $CH_4$ gas mixtures. After the deposition, the SiOC(-H) thin films were annealed in an Ar atmosphere using rapid thermal annealing (RTA) for 30min. The electrical properties of the SiOC(-H) films were then measured using an impedance analyzer. The dielectric constant decreased as the $CH_4$ concentration of low-k SiOC(-H) thin film increased. The decrease in the dielectric constant was explained in terms of the decrease of the ionic polarization due to the increase of the relative carbon content. The spectrum via Fourier transform infrared (FT-IR) spectroscopy showed a variety of bonding configurations, including Si-O-Si, H-Si-O, Si-$(CH_3)_2$, Si-$CH_3$ and $CH_x$ in the absorbance mode over the range from 650 to $4000\;cm^{-1}$. The results showed that dielectric properties with different $CH_4$ concentrations are closely related to the (Si-$CH_3$)/[(Si-$CH_3$)+(Si-O)] ratio.

• Korean Journal of Clinical Pharmacy
• /
• v.7 no.2
• /
• pp.51-63
• /
• 1997

The effect of cimetidine administration on the pharmacokinetic parameters of cyclosporine were determined in healthy voluteers. This study was performed in 10 volunteers of age ranged 22-48 years and body weight 48-62 kg. This study was performed with cross-over design. Mono cyclosporine and cyclosporine metabolites was extracted from whole blood analysed by fluororescence polarization immune assay (TDX-FLX, Abbott). After coadministration of cimetidine (300 mg) with cyclosporine (300 mg) orally, maximum concentration of mono cyclosporine was significantly increased $1221{\pm}143\;ng/ml\;to\;1562{\pm}184\;ng/ml$ (P<0.05), area under the time curve of cyclosporine (12 hr) also was significantly increased $7478{\pm}829\;ng/ml{\cdot}hr\;to\;9721{\pm}879\;ng/ml{\cdot}hr$ (P<0.05) and absolute baioavailability of cyclosporine was increased $50\pm5.6\%\;to\;57.6\pm6.1\%\;(P<0.05)$ compared to control group. The blood concentrations of cyclopsorine metabolites were significantly decrased (P<0.05) after coadministration of cimetidine. In cimetidine pretreated group, blood mono cyclosporine concentrations were increased significan시y $1220.0\pm203.00\;ng/ml\;to\;1510.0\pm204.00\;ng/ml$ compared with control group (P<0.05). In the mono cyclosporine pharmacokinetic parameter after oral administration absorption rate and maximum concentration were significantly higher in cimetidine coadministered and pretreated group than control group (P<0.05). The ratio of metabolites and mono cyclosporine concentrations was decreased significantly from $70.8\%\;in\;control\;to\;34.8\%$ in coadministration of cimetidine orally. As matter of facts these reults are considered to inhibition of cyclosporine hepatic metabolism and increasing of cyclosporine absorption rate in gastrointestinal tract because of maintaining cyclosporine stability in elevated gastric pH by cimetidine. We considered, it appeares that cimetidine increase bioavailability of cyclosporine by increasing oral absorption and by decreasing hepatic clearance. But the absorption and clearance of cyclosporine was highly variable individually, and therefore we consider that cyclosporine blood level monitoring would be essential in patients with cimetidine co-administration.

• Journal of the Korea Institute of Information and Communication Engineering
• /
• v.14 no.7
• /
• pp.1529-1536
• /
• 2010

In this paper, we propose a Axially displaced ellipse gregorian antenna with conical feed horn operating in Ku-band. For fast searching satellite position, it is designed the sub-reflector rotates about $1.5^{\circ}$ tilted by the central axis. the curvature and feed center of the main-reflector and sub-reflector are optimized to achieve maximum antenna efficiency. The designed reflector antenna shows the gain of 33dB and the cross polarization level of less than -21dB and the side-lobe level of less than －14 dB at 12.2 GHz. and C/N ratio of 19dB is proved by reception experiment of Koreasat with fabricated antenna.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.42 no.1
• /
• pp.90-97
• /
• 2014

In this paper, we have designed the antenna for Korea SAT-5 Satellite Communication which can use Ka band in the earth station. The antenna structure consist of the the dual-offset gregorian reflector that has high gain and efficiency, the corrugated horn that has symmetric radiation patterns and low side lobe levels, the iris polarizer that make circular polarization and the OrthoMode Transducer that separate transmitting and receiving signals. The designed antenna gain is more than 45.7dBi in Tx-band which use LHCP and 42.0dBi in Rx-band which use RHCP. The co-polarized and cross-polarized radiation pattern comply with ITU-R S.580-6 and S.731-1 that are recommended by International Telecommunication Union in the geostationary satellite. The Axial ratio is less than 1.0dB in Tx-band and 1.5dB in Rx-band that meet MIL-STD-188-164A.

• Journal of the Institute of Electronics Engineers of Korea TC
• /
• v.45 no.1
• /
• pp.85-90
• /
• 2008

In this paper, we studied on dual reflector adjusted to monopulse antenna system. As a result, when the efficiency of main reflector is more than 70%, The size of reflector is 30 wavelength of maximum frequency and minimum frequency gain is 37.9dBi, and Maximum frequency gain is 38.6dBi. Also, when a radius is D and Focus-distance is $F_e$, a scheme for efficiency improvement of Sub Reflector is to increase the Focus-distance to Diameter Ratio. In this case, Cross polarization in Far field improved and spherical spreading loss in circumference of reflector reduced. The influence of Radiation pattern followed by the side displacement of feed antenna(at $x_sy_s$) is decreased, it is confirmed that performance of scanning is improved.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
• /
• v.19 no.7
• /
• pp.707-712
• /
• 2008

In this paper, the sequentially rotated array(SRA) antenna with 256 elements applicable for satellite broadcasting reception was designed by arraying this triple(4+8+4 element) SRA antenna as a sub-array antenna. The structure of a triple SRA antenna is a combination of three coaxial shells composed with 4 elements of inner shell and 8 elements of middle shell and 4 elements of outer shell. In accordance with the optimum design rules for realizing a high gain antenna, the sequential array factors(M, P) of inner shell and outer shell have been chosen M=4 and P=1 and that of middle shell has been chosen M=8 and P=1. The results of the simulation and the measurement for the proposed triple(4+8+4 element) SRA antenna and the SRA antenna with 256 elements show good characteristics on the integration, bandwidth of the axial ratio and the cross-polarization, the gain respectively.

• Tribology and Lubricants
• /
• v.20 no.6
• /
• pp.306-313
• /
• 2004

Many of the current development in surface modification engineering are focused on multilayered coatings, which have the potential to improve the tribological properties. Four different multilayered coatings were deposited on AISI D2 steel in this study. The prepared samples are designed as $WC-Ti_{0.6}Al_{0.4}N,\;WC-Ti_{0.53}Al_{0.47}N,\;WC-Ti_{0.5}Al_{0.5}N\;and\;WC-Ti_{0.43}Al_{0.57}N$. The multilayered coatings were investigated with respect to coating surface and cross-sectional morphology, roughness, adhesion, hardness, porosity and tribological behaviors. Especially, wear tests of four multilayered coatings were performed by using a ball-on-disc configuration with a linear sliding speed of 0.017 m/sec and a normal load of 5.38 N load. The tests were carried out at room temperature in air by employing AISI 52100 steel ball $(H_R\;=\;66) $ having a diameter of 10 mm. The surface morphology, and topography of the wear scars of samples and balls have been determined by using scanning electron spectroscopy (SEM). Also, wear mechanism was determined by using SEM coupled with energy-dispersive spectroscopy (EDS). Results have showed an improved wear resistance of the $WC-Ti_{1-x}Al_xN$coatings with increasing of Al (aluminum) concentration.