• Title/Summary/Keyword: Critical Surface Tension

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Characteristics of Biosurfactant Producing Pseudomonas sp. G314 (생물 계면활성제를 생산하는 Pseudomonas sp. G314의 특성)

  • Shim, So-Hee;Park, Kyeong-Ryang
    • Korean Journal of Microbiology
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    • v.42 no.4
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    • pp.286-293
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    • 2006
  • Three hundred thirty two bacterial colonies which were able to degrade crude oil were isolated from soil samples that were contaminated with oil in Daejon area. Among them, one bacterial strain was selected for this study based on its low surface tension ability, and this selected bacterial strain was identified as Pseudomonas sp. G314 through physiological-biochemical tests and analysis of its 16S rRNA sequence. Pseudomonas sp. G314 showed a high resistance to antibiotics such as ampicillin, chloramphenicol, spectinomycin, and streptomycin, and heavy metals such as Li, Cr, and Mn. It was found that the optimal pH and temperature for biosurfactant production of Pseudomonas sp. G314 were pH 7.0 and $30^{\circ}C$, respectively. After seven hours of inoculated, the biosurfactant activity reached the maximum, and surface tension of the culture broth was decreased from 72 to 25 dyne/cm. The crude biosurfactant was obtained from the culture broth by acid precipitation, followed by solvent extraction, evaporation and then freeze drying. The CMC (critical micelle concentration) value of the crude biosurfactant was 20 mg/L.

The Study for Surface Activity of Alkylquinolinium Halide Ⅰ. The Critical Micelle Concentration of Solution of Dodecylquinolinium Bromide (Alkylquinolinium Halide의 계면활성에 관한 연구 Ⅰ. Dodecylquinolinium Bromide 수용액의 Critical Micelle Concentration)

  • Lee Chong-Man
    • Journal of the Korean Chemical Society
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    • v.16 no.4
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    • pp.205-207
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    • 1972
  • Dodecylquinolinium bromide has been synthesized and the critical micelle concentrations of it in the aqueous solution have been determined by the measurement of the surface tension and the electrical conductance. The values are $3.34 {\times} 10^{-3}mole/l$ and 3.41 {\times} $10^{-3}$mole/l, respectively. Since dodecylquinolinium bromide has the larger hydrophobic group than dodecylpyridinium bromide, it is considered that the former has the smaller critical micelle concentration than the latter.

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Surface effects on vibration and buckling behavior of embedded nanoarches

  • Ebrahimi, Farzad;Daman, Mohsen;Fardshad, Ramin Ebrahimi
    • Structural Engineering and Mechanics
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    • v.64 no.1
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    • pp.1-10
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    • 2017
  • The present paper deals with the free vibration and buckling problem with consideration of surface properties of circular nanobeams and nanoarches. The Gurtin-Murdach theory is used for investigating the surface effects parameters including surface tension, surface density and surface elasticity. Both linear and nonlinear elastic foundation effect are considered on the circular curved nanobeam. The analytically Navier solution is employed to solve the governing equations. It is obviously detected that the natural frequencies of a curved nanobeams is substantially influenced by the elastic foundations. Besides, it is revealed that by increasing the thickness of curved nanobeam, the influence of surface properties and elastic foundations reduce to vanished, and the natural frequency and critical buckling load turns into to the corresponding classical values.

Onset of Marangoni Convection in a Ternary Mixture with Surfactant (계면활성제가 포함된 삼성분계 해석을 통한 마란고니 대류 발생 연구)

  • 김제익;강용태;최창균
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.11
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    • pp.964-969
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    • 2003
  • The objective of this study is to investigate the effect of surfactant on the onset of Marangoni convection adapting a non-linear surface equation of state. The surface tension gradient with respect to the absorbate concentration, ${\gamma}$, is linearly related to the surface concentration of a surfactant with a coeffcient $x_{A}$. The numerical results show that the role of the initial surfactant concentration to Marangoni instability changes from the stabilizer to the destabilizer depending on the change of the sign of $x_{A}$ from negative to positive. It is concluded that for $x_{A}$>0 there is a critical modified Marangoni number of surfactant $M_{Ac}$ $^{*}$ above which liquid layer is always unstable against long wave disturbances.rbances.

Anti-Foaming Properties of Polypropylene Glycol Oleates (올레산 폴리프로필렌글리콜 에스테르류의 소포특성)

  • Li, Hai-Yan;Choi, Hyoung-Chul;Jeong, Noh-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.2
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    • pp.146-151
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    • 2011
  • In this study, by using oleic acid and polypropylene glycol, good natured antifoaming agent for suitable electronics process under the alkaline conditions were synthesized. For the synthesized mono and diesters, acid value, hydroxyl value was measured, and identified by FT-IR and $^1H-NMR$ spectroscopy. Surface properties such as surface tension, critical micelle concentration(cmc) for diluted aqueous solution was measured, and tested the antifoaming properties according to the difference of alkyl chain length, various concentration, temperature and pH. The surface tension of synthesized antifoaming agent, PPMO(Polypropylene glycol monooleate) was 24.3 dyne/cm, PPDO(Polypropylene glycol dioleate) was 23.7 dyne/cm. By increasing of the alkyl chain length, surface tension was decreased slightly, and showed good antifoaming properties at 0.06 wt% concentration and $50^{\circ}C$, pH 11. These synthesized compounds are expected to apply as a suitable antifoaming agents in the semiconductor and the PCB(Printed Circuit Board) manufacturing process.

Synthesis and Properties of Glycolic Acid Ester Type Cationic Surfactant (글리콜산 에스테르계 양이온 계면활성제의 합성 및 물성)

  • Park, Jong-Kwun;Jeong, Noh-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.1
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    • pp.7-13
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    • 2014
  • A cationic ester type surfactant, namely N-2-hydroxy-3-(2-hydroxyacetoxy) proply-N,N-dimethyldodecylaminium chloride(HPDA) was synthesized and confirmed by FT-IR and $^1H$-NMR spectroscopy. Surface tensions on the diluted aqueous solutions of the synthetic compounds were measured and evaluated critical micelle concentration. Surface tension was 33~34 dyne/cm in the range of $10^{-3}{\sim}10^{-2}mol/L$ and critical micelle concentration(c.m.c) value was $8.5{\times}10^{-3}mol/L$ by surface tension method. Emulsifying properties of the synthetic surfactant(HPDA) and Sodium lauryl sulfate (SLS), tetradecyl trimethyl ammonium bromide (TTAB) was tested. As a results, synthetic glycolic acid ester type compounds(HPDA) has been confirmed as a good emulsifier. The foaming power and stability of synthesized ester type surfactant was measured by Ross-Miles method.

Isolation, Characterization, and Investigation of Surface and Hemolytic Activities of a Lipopeptide Biosurfactant Produced by Bacillus subtilis ATCC 6633

  • Dehghan-Noudeh Gholamreza;Housaindokht Mohammadreza;Bazzaz Bibi Sedigeh Fazly
    • Journal of Microbiology
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    • v.43 no.3
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    • pp.272-276
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    • 2005
  • Bacillus subtilis ATCC 6633 was grown in BHIB medium supplemented with $Mn^{2+}$ for 96 h at $37^{\circ}C$ in a shaker incubator. After removing the microbial biomass, a lipopeptide biosurfactant was extracted from the supernatant. Its structure was established by chemical and spectroscopy methods. The structure was confirmed by physical properties, such as Hydrophile-Lipophile Balance (HLB), surface activity and erythrocyte hemolytic capacity. The critical micelle concentration (cmc) and erythrocyte hemolytic capacity of the biosurfactant were compared to those of surfactants such as SDS, BC (benzalkonium chloride), TTAB (tetradecyltrimethylammonium bromide) and HTAB (hexadecyltrimethylammonium bromide). The maximum hemolytic effect for all surfactants mentioned was observed at concentrations above cmc. The maximum hemolytic effect of synthetic surfactants was more than that of the biosurfactant produced by B. subtilis ATCC 6633. Therefore, biosurfactant would be considered a suitable surface-active agent due to low toxicity to the membrane.

Physiochemical Properties of Extracellular Lipid Produced by Rhodotorula glutinis K-501 as a Biosurfactant (Rhodotorula glutinis K-501에 의해 생산된 세포외지질의 생체계면활성제로서 물리화학적 특성)

  • 박평규;채희정;김의용
    • KSBB Journal
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    • v.13 no.1
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    • pp.65-70
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    • 1998
  • The physiochemical properties of extracellular lipid produced by an oleaginous yeast, Rhodotorula glutinis K-501 were examined. From the analytical experiments, it was suggested that the extracellular lipid produced is glycolipidic compound. Critical micelle concentration and minimum surface tension of the extracellular lipid in aqueous solution were 89mg/L and 31dyne/cm, respectively. Surface tension was also constant throughout wide range of pH. The emulsifying abilities and dispersing power of the extracellular lipid were much greater than those of commercial surfactants such as Tween 80 and Triton X-100 by factors of 2-3 and 1.3, respectively.

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Synthesis and Properties of Polyoxyethylene Reactive Surfactant (폴리옥시에틸렌계 반응성 계면활성제의 합성 및 물성)

  • Cho, Jung-Eun;Lee, Sang-Chul;Park, Jong-Kwon;Kim, Kyung-Sil;Shin, Hye-Lin;Kim, Yu-Ri;Shin, Seung-Hoon;Jeong, Noh-Hee
    • Applied Chemistry for Engineering
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    • v.30 no.2
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    • pp.241-246
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    • 2019
  • In this paper, reactive surfactants were synthesized by using acrylic acid or 3-butenoic acid as nonionic surfactants, polyoxyethylene(23) lauryl ether (Brij 35) and polyoxyethylene(20) stearyl ether (Brij S20). The synthesis of surfactants was confirmed by FT-IR and $^1H$-NMR. The surface tension, emulsifying property, and foam power and stability were also measured. The surface tension value was 35~41 dyne/cm at an critical micelle concentration (cmc) which was measured as $1.0{\times}10^{-4}{\sim}9.7{\times}10^{-5}mol/L$ using a surface tension method. The emulsifying power of synthesized surfactant was measured with benzene, soybean oil and monomer. Also, the initial height of the bubbles and the height after 5 minutes were measured and the values were compared with each other.

Instabilities of Natural Convection in a Shallow Fluid Layers (얇은 유체층(流體層)에 있어서 자연대류(自然對流)의 불안정성(不安定性))

  • Yang, Soong-Hyo;Park, Chan-Kuk
    • Solar Energy
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    • v.8 no.1
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    • pp.33-40
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    • 1988
  • The characteristics of thermal instabilities of natural convection in a horizontal fluid layer bounded below by a rigid plate and above by an interface with a passive gas is presented. The critical Grashof number decreases as the surface tension gradient effect (Marangoni effect) at the interface increases and the flow remains unstable for a critical Marangoni number depending on Prandtl numbers. These results are in substantial agreement with those of Smith and Davis.

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