• Title/Summary/Keyword: Cr2O3

Search Result 1,270, Processing Time 0.029 seconds

Soil Characteristics and Management Proposal of the Monument Beobsoo Marsh, Korea (천연기념물 법수늪의 토양특성 및 관리방안)

  • Kim, Do-Gyun;Kim, Yong-Shik
    • Journal of the Korean Society of Environmental Restoration Technology
    • /
    • v.14 no.3
    • /
    • pp.15-32
    • /
    • 2011
  • This study was carried out to investigate the soil characteristics and propose the management for the Monument Beobsoo Marsh, Korea. The soil properties of O.M, $Ca^{2+}$, $Na^+$ and CEC were higher and the soil properties of pH_{1:5}$ and $P_2O_5$ were lower the studied sites than other marsh sites in Korea. Although the Heavy metals such as Pb, Hg, Cd, Cu, Zn, Cr and As were lower compare to the safety standard of soil pollution in Korea, the overall conservation management plan based on long-term monitoring should be considered just because it varied by the point and non-point source pollution within the studied marsh. The source of water pollution varied due to non-point polluting origins such as sewage inlet, degraded terrain for agriculture, fishing sites, sites of removed water grasses, pesticides, chemical fertilizers, as well as fallen leaves. The creation of an artificial marsh is recommended due to the soil environment of the studied sites may be changed owing to the accumulated contaminants from the sources of both of point or non-point contaminants. The establishment of the zones of core, buffer and transition which is basic management structure of the UNESCO MaB could be applied to manage the studied site. Simultaneously the promotion of voluntary participation and education of the local residents are needed.

Difluoromethane Synthesis over Fluorinated Metal Oxide (불화된 금속산화물 촉매상에서 이불화메탄의 합성)

  • Lee, Youn-Woo;Lee, Kyong-Hwan;Lim, Jong Sung;Kim, Jae-Duck;Lee, Youn Yong
    • Applied Chemistry for Engineering
    • /
    • v.9 no.5
    • /
    • pp.619-623
    • /
    • 1998
  • The influences of reaction temperature, HF/DCM mole ratio, contact time and catalyst type on activity and selectivity of difluoromethane synthesis via hydrofluoriation of dichloromethane over fluorinated catalyst have been studied. It has been found that fluorinated $Cr/Al_2O_3$ catalysts, show better performance compared to pure fluorinated $Al_2O_3$ catalyst and then, non-treated catalysts demonstrate better than catalysts pretreated with hydrogen and air. The results show that the optimum reaction conditions are found as follows : reaction temperature at $340^{\circ}C$, mole ratio of HF/DCM 5 or above and contact time 20 sec. or above. With these conditions the maximum attainable yield of difluoromethane has been found to be greater than 80%. In particular, the activity and the selectivity of difluoromethane do not change with the reaction time on stream up to 8 hours.

  • PDF

Fabrication of MFISFET Compatible with CMOS Process Using $SrBi_2Ta_2O_9$(SBT) Materials

  • You, In-Kyu;Lee, Won-Jae;Yang, Il-Suk;Yu, Byoung-Gon;Cho, Kyoung-Ik
    • Transactions on Electrical and Electronic Materials
    • /
    • v.1 no.1
    • /
    • pp.40-44
    • /
    • 2000
  • Metal-ferroelectric-insulator-semoiconductor field effect transistor (MFISFETs) were fabricated using CMOS processes. The Pt/SBT/NO combined layers were etched for forming a conformal gate by using Ti/Cr metal masks and a two step etching method, By the method, we were able to fabricate a small-sized gate with the dimension of $16/4{\mu}textrm{m}$ in the width/length of gate. It has been chosen the non-self aligned source and drain implantation process, We have deposited inter-layer dielectrics(ILD) by low pressure chemical vapor deposition(LPCVD) at $380^{circ}C$ after etching the gate structure and the threshold voltage of p-channel MFISFETs were about 1.0 and -2.1V, respectively. It was also observed that the current difference between the $I_{ON}$(on current) and $I_{OFF}$(off current) that is very important in sensing margin, is more that 100 times in $I_{D}-V_{G}$ hysteresis curve.

  • PDF

Selenium Effect on the Frequency of SCEs Induced by Heavy Metals in Human Lymphocytes (Selenium이 mercury, cadmium 및 chromium에 의한 자매염색분체교환(姉妹染色分體交換)의 빈도(頻度)에 미치는 영향(影響))

  • Koh, Dai-Ha;Ki, No-Suk
    • Journal of Preventive Medicine and Public Health
    • /
    • v.23 no.1 s.29
    • /
    • pp.1-10
    • /
    • 1990
  • The protective effect of sodium selenite($Na_2SeO_3$) against the cytogenetic toxicity of heavy metals was investigated on human whole-blood cultures in relation to induction of sister chromatid exchange (SCE) in secondary metaphase chromosome. Methylmercury chloride($CH_3HgCl$), cadmium chloride($CdCl_2$), potassium dichromate($K_2Cr_2O_7$), and sodium selenite caused to the typically dose-dependent increase in sister chromatid exchanges (SCEs) by the concentrations ranging from $0.3{\mu}M\;to\;10{mu}M$. However, the inductions of sister chromatid exchanges by methylmercury chloride or cadmium chloride were inhibited by the simultaneous addition of sodium selenite $1.2{mu}M$. The frequencies of SCE were decreased to the level of control in the molar ratios as 2:1, 1:1, 1:2, and 1:4 of selenium selenite vs. methylmercury chloride, and as 1:1 and 1:2 of selenium selenite vs. cadmium chloride, while the frequencies of SCE induced by potassium dichromate were not changed by the addition of sodium selenite in culture condition. Mitotic indices were decreased in the higher concentrations of chemicals and not significantly changed by the simultaneous addition of sodium selenite to the culture condition containing each chemicals.

  • PDF

Effect of Ohjeoksan-Decoction on Brain Metal Level in Rats (오적산을 투여한 흰쥐의 뇌중 금속농도변화에 관한 연구)

  • Min Dae Ki;Han Seong Nim;Ko Seong Gyu
    • Journal of Physiology & Pathology in Korean Medicine
    • /
    • v.16 no.5
    • /
    • pp.967-975
    • /
    • 2002
  • This study was to investigate the metal accumulation from Ohjeoksan-Decoction to rat brain(Sprague Dawley). 1. In Control group, each metal concentration was within 26.65mg/kg, and in each experimental groups, was within 28.39mg/kg. And, there were no significant metal concentration between control and experimental groups. Exceptionally, Cr and Ni level of control group was lower than experimental groups significantly. (p<0.05) and Cr and Ni level of experimental I group was lower than other experimental groups too.(p<0.05). But, Pb level of control group was higher than experimental groups significantly.(p<0.05) Pb level of experimental I group was higher than other experimental groups(p<0.01). 2. In non-hazardous, hazardous and total metal concentration, there was no increase tendency in brain according to the high dose of OD(Ohjeoksan-Decoction) intake. Reversely, in experimental groups, hazardous metal concentration was decrease by high OD intake.(p<0.05). 3. Correlation among each metal in brain was various in each groups. Briefly under the intake of Ohjeoksan-Decoction, that is very busy herb prescription, this study was defined within safety in brain metal level by P.O. during 10 days. But, there should be a more research about Pb increase by high dose OD intake

A STUDY ON THE POSTOPERATIVE STABILITY OF LEFORT I OSTEOTOMY IN THE TWO-JAW SURGERY OF THE SKELETAL CLASS III MALOCCLUSION PATIENTS (골격성 제 III급 부정교합 환자의 상하악 동시이동술시 LeFort I 상악골절단술의 술후 안정성에 관한 연구)

  • Im, Yang-Hee;Ko, Seung-O;Shin, Hyo-Keun
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
    • /
    • v.27 no.5
    • /
    • pp.397-403
    • /
    • 2001
  • Purpose: The purpose of this study was to evaluate the postoperative stability of LeFort I osteotomy in two-jaw surgery of skeletal class III malocclusion and to help the establishment of treatment planning in patients with a skeletal class III malocclusion in the future. Materials and Methods: The lateral cephalograms of 14 patients who had been underwent two-jaw surgery via one-piece LeFort I osteotomy were traced and the landmarks were identified. Repeated tracings and construction of reference planes were done. Comparisons were made from the immediate postoperative to late postoperative results of each landmarks on the horizontal and vertical directions. Conclusions: 1. The horizontal changes of landmark ANS, point A, PNS and Mx6Rt between immediate postoperative to late postoperative data were statistically insignificant(p>0.05). 2. The vertical changes of landmark ANS, point A, PNS, Mx6Cr and Mx6Rt between immediate postoperative to late postoperative data were statistically insignificant(p>0.05). 3. The horizontal change of landmark Mx6Cr between immediate postoperative to late postoperative data was statistically significant(p<0.05). 4. Results showed that it was stable that one-piece LeFort I osteotomy in two-jaw surgery of skeletal class III malocclusion.

  • PDF

Evaluation of the Nutrient Removal Performance of the Pilot-scale KNR (Kwon's Nutrient Removal) System with Dual Sludge for Small Sewage Treatment (소규모 하수처리를 위한 파일럿 규모 이중슬러지 KNR® (Kwon's nutrient removal) 시스템의 영얌염류 제거성능 평가)

  • An, Jin-Young;Kwon, Joong-Chun;Kim, Yun-Hak;Jeng, Yoo-Hoon;Kim, Doo-Eon;Ryu, Sun-Ho;Kim, Byung-Woo
    • Clean Technology
    • /
    • v.12 no.2
    • /
    • pp.67-77
    • /
    • 2006
  • A simple dual sludge process, called as $KNR^{(R)}$ (Kwon's Nutrient Removal) system, was developed for small sewage treatment. It is a hybrid system that consists of an UMBR (Upflow multi-layer bioreactor) as anaerobic and anoxic reactor with suspended denitrifier and a post aerobic biofilm reactor, filled with pellet-like media, with attached nitrifier. To evaluate the stability and performance of this system for small sewage treatment, the pilot-scale $KNR^{(R)}$ plant with a treatment capacity of $50m^3/d$ was practically applied to the actual sewage treatment plant, which was under retrofit construction during pilot plant operation, with a capacity of $50m^3/d$ in a small rural community. The HRTs of a UMBR and a post aerobic biofilm reactor were about 4.7 h and 7.2 h, respectively. The temperature in the reactor varied from $18.1^{\circ}C$ to $28.1^{\circ}C$. The pilot plant showed stable performance even though the pilot plant had been the severe fluctuation of influent flow rate and BOD/N ratio. During a whole period of this study, average concentrations of $COD_{cr}$, $COD_{Mn}$, $BOD_5$, TN, and TP in the final effluent obtained from this system were 11.0 mg/L, 8.8 mg/L, 4.2 mg/L, 3.5 mg/L, 9.8 mg/L, and 0.87/0.17 mg/L (with/without poly aluminium chloride(PAC)), which corresponded to a removal efficiency of 95.3%, 87.6%, 96.3%, 96.5%, 68.2%, and 55.4/90.3%, respectively. Excess sludge production rates were $0.026kg-DS/m^3$-sewage and 0.220 kg-DS/kg-BOD lower 1.9 to 3.8 times than those in activated sludge based system such as $A_2O$ and Bardenpho.

  • PDF

Effects of Paper Sludge Application on the Chemical Properties of Paddy Soil and Growth of Paddy Rice.;III. Effects of Paper Sludge Application in the Growth of Paddy Rice. (제지(製紙)슬러지의 시용(施用)이 논 토양(土壤)의 화학성(化學性)과 수도생육(水稻生育)에 미치는 영향(影響);III. 슬러지시용(施用)이 수도생육(水稻生育)에 미치는 영향(影響))

  • Heo, Jong-Soo;Kim, Kwang-Sik;Ha, Ho-Sung
    • Korean Journal of Environmental Agriculture
    • /
    • v.7 no.1
    • /
    • pp.26-33
    • /
    • 1988
  • To investigate the effects of paper sludge on the growth response of paddy rice, paper sludge was applied to pots at the rate of either 300, 600, 900 or 1,200 kg/l0a which was either preadjusted at a C/N ratio of 30 : 1 or not adjusted. The effects were compared with those of the control. 1. Plant heights, number of tillers and dry weight were significantly reduced with the increasing application of paper sludge in the early stages of rice growth, whereas opposite results were observed after the heading stage when treated with C/N ratio preadjusted paper sludge. 2. The uptake of $N,P_2O_5,K_2O$ and $SiO_2$ by rice plants grown in paper sludge treated soil was significantly reduced in the early stages of rice growth. Conversely, uptake was enhanced in the C/N ratio preadjusted plot in the young panicle formation stage. 3. Zn, Cu and Cd content in rice straw was in the range of $39{\sim}101$, $0{\sim}0.11$ and $0.03{\sim}0.14ppm$, respectively, and Pb and Cr in rice straw were not detected at all. However, there was no difference in the content of all these heavy metals in rice straw irrespective of treatment.

  • PDF

An Experimental Study of Retting Conditions of Domestic Ramie Fiber (국산 모시섬유의 침지조건에 관한 실험적 연구)

  • 이전숙;최경은
    • Korean Journal of Human Ecology
    • /
    • v.6 no.1
    • /
    • pp.27-34
    • /
    • 2003
  • We investigated the bacterial and chemical retting conditions of ramie grown in Hansan. Bacterial retting was done in troughs at a temperature of 30${\pm}$2$^{\circ}C$ for 1, 2, 3, 4, 5, 6 and 10 days. Chemical retting(CR) was done at the different conditions using sodium silicate (Na$_2$SiO$_3$), sodium carbonate(Na$_2$CO$_3$) and sodium hydroxide(NaOH) as alkali solutions. The retting solution was boiled during 1. 2, 4 and 6 hours respectively at the different concentration(0.5, 2.0, 4.0, 6.0. 8.0 %) with decorticated ramie stems submerged in it. The treated ramie was then rinsing with running tap water thoroughly, which was further soaker in 0.5% acetic acid (v/v) solution for three minutes and washed thoroughly with distilled water. Finally ramie was dried for 2 hours in vacuum oven at 100 $^{\circ}C$. To know change of ramie fiber characteristics retted at the different conditions, weight loss, fiber bundle strength were tested and color, texture, luster etc. were also sensually evaluated. The results were as follows. $.$ Weight loss of ramie retted in each alkali solutions were about 10%, 20% and 30% in sodium silicate, sodium carbonate and sodium hydroxide, respectively. $.$ Chemical retting was faster than bacterial retting, but the color of chemically retted ramies were worse than that of bacterially retted ramies. $.$ The combination of bacterial and chemical processing showed some merits. A combination of either 2 or 3 days of bacterial and then chemical retting might provide the best quality ramie. $.$ Ramie fiber became cottonized ramie when retted in 8% NaOH solution for 6-8hours.

  • PDF

Assessment of Soil Contamination and Hydrogeochemistry for Drinking Water Sites in Korea (국내 먹는샘물 개발지역의 토양 오염 평가 및 수리지구화학적 특성)

  • 이두호;전효택
    • Journal of the Korean Society of Groundwater Environment
    • /
    • v.4 no.1
    • /
    • pp.41-53
    • /
    • 1997
  • Geochemical data of soil and water samples were presented in order to assess the environmental impart for drinking water sites. Microscopic observation of rock samples and physical and chemical analysis of soil and water samples were undertaken. The geology of study areas are classified into three groups such as granitic rocks, meta-sedimentary rocks and sedimentary rocks. Enrichment of heavy metals derived from those rocks is not found in this study areas. Soils were analyzed for Cu, Pb, Zn, Cd and Cr using AAS extracted by HNO$_3$+HClO$_4$ and 0.1 N HCl. Heavy metal concentrations in soils are within the range of those in uncontaminated soils. In comparison of metal contents extracted by 0.1 N HCl and HNO$_3$+HC1O$_4$, less than 10% of the heavy metals are present in the exchangeable fraction. In particular, an pollution index has been proposed to assess the degree of soil contamination. Pollution index in soils are between 0.03 and 0.47 therefore, soils are not polluted with heavy metals. Deep groundwaters within granitic rocks have been evolved into Na$\^$+/-HCO$_3$$\^$-/ type, whereas other deep groundwaters evolved into Ca$\^$2+/-HCO$_3$$\^$-/ type. The predominance of Na$\^$+/ over Ca$\^$2+/ in deep groundwaters within granitic rocks is a result of dissolution of plagioclase, but for sedimentary and meta-sedimentary rocks, dissolution of calcite is a dominant factor for their hydrogeochemistry. The pH, conductivity and contents of the most dissolved ions in the water increase with depth. Shallow groundwaters, however, are highly susceptible to pollution owing to agricultural activities, considering the fact that high contents of nitrate, chloride and potassium, and high K/Na ratio are observed in some shallow groundwaters. In a thermodynamic approach, most natural water samples are plotted within the stability fields of kaolinite and smectite. Therefore, microcline and other feldspars will alter to form clay minerals, such as kaolinite and smectite. From the modelling for water-rock interactions based on mass balance equation, models accord well with behavior of the ions and results of thermodynamic studies are derived.

  • PDF