• Journal of the Korean institute of surface engineering
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• v.17 no.1
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• pp.7-13
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• 1984

Carburizing of a 12%Cr steel containing 0.6%Si was performed at 950$^{\circ}C$ for various times, and the microstructure, hardness and the water characteristics of the carburized chromium steel were examined. The results obtained in this study are as follows: 1. Carbide-dispersed layer (CD layer) with fine dispersion of $Cr_7C_3$ in martensite matrix was formed by carburizing. The radius and amount of the carbides in the surface region of CD layer were about 0.3${\mu}m$ and 35% by volume, respectively. 2. Chromium steel carburized and quench-tempered showed better wear resistance and hardness than ordinary high chromium tool steel. It is concluded from these results that fine dispered carbides are very effective in improving wear resistance and hardness.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2012.05a
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• pp.190-191
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• 2012

철계 소결 부품은 성형의 용이성, 저렴한 가격, 특유의 기공성 입계조직으로 기능성 표면처리에 적합한 소재이다. 본 연구에서는 고온 부식 및 극심한 마모환경에 노출되는 발전소 터빈과 같은 부품의 표면처리에 주로 쓰이는 Pack-chromizing 법을 적용한 철계 소결부품의 내마모 특성을 알아보고자 한다. AFM 분석결과, Pack-chromizing 에 의해 Cr이 확산된 표층의 형상이 Peak-and-Valley 형태의 치밀한 dimple 구조로 변화된 것을 알 수 있었다. 또한, XRD 및 XPS 분석을 통해 chromium carbide 및 $Cr_2O_3$와 같은 고경도의 화합물 층이 형성됨을 알 수 있었다. 따라서, 이러한 dimple 구조를 띈 고경도의 화합물 층이 표면의 마찰계수를 저하시키는 주요 원인임을 본 연구에서 논하고자 한다.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.26 no.1
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• pp.55-60
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• 2002

For the development of a new creep test technique, the availability of SP-Creep test is discussed for 1Cr-0.5Mo boiler header material. And some results are also compared with those of 2.25Cr- 1Mo steel which widely uses as boiler superheater tube. The results can be summarized as follows. The load exponents(n) obtained by SP-Creep test for 1Cr-0.5Mo steel are decreased with increasing creep temperature and the values are 15.67, 13.89, and 17.13 at 550$^{circ}C$ ,575$^{circ}C$ and 600$^{circ}C$, respectively. The temperature dependence of the load exponent is given by n = 107.19 - 0.1108T. This reason that load exponents show the extensive range of 10∼16 is attributed to the fine carbide such as M$_{23}$C$_{6}$ in lath tempered martensitic structures. At the same creep condition, the secondary creep rate of 1Cr-0.5Mo steel is lower than the 2.25Cr-1Mo steel1 due to the strengthening microstructure composed by normalizing and tempering treatments. Through a SEM observation, it can be summarized that the primary, secondary, and tertiary creep regions of SP-Creep specimen are corresponding to plastic bending, plastic membrane stretching, and plastic instability regions among the deformation behavior of four steps in SP test, respectively.y.

• Journal of the Korean Society for Heat Treatment
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• v.23 no.4
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• pp.198-204
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• 2010

Modified 9Cr-1Mo steels possess excellent high-temperature mechanical properties and are widely used in energy conversion industries. However, in-service materials degradation, such as softening, carbide-induced embrittlement, temper embrittlement, etc., can take place during long-term operation. Evolution of microstructure due to service exposure to high temperature has a strong effect on the performance of heat resistant steels. In case of modified 9Cr-1Mo steels, precipitation of $Fe_2Mo$-type laves phases and coarsening of $M_{23}C_6$-type carbides are the primary cause of degradation of mechanical properties such as toughness, hardness, tensile strength and creep resistance. This study was aimed at finding reliable parameter for assessing the integrity of modified 9Cr-1Mo steels. Characteristic parameters were attained between mechanical and ultrasonic properties.

• Journal of the Korean Society for Heat Treatment
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• v.27 no.5
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• pp.242-252
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• 2014

A comparative study was performed on the microstructures and the mechanical properties of STD11 and 8Cr steel. The specimens were quenched from $1030^{\circ}C$ and tempered at $240^{\circ}C$ and $520^{\circ}C$. Vickers hardness, impact toughness and tensile tests were conducted at various tempering temperatures. Microstructural characterization to measure grain size, volume fraction of retained austenite and distribution of carbides was carried out by using SEM, EBSD, TEM and X-ray diffraction techniques. Due to finer $M_7C_3$ carbides dispersed, 8Cr steel showed larger impact toughness and plasticity than STD11 irrespective of the tempering temperature. While 8Cr steel had lower hardness in as-quenched state and after tempering at $240^{\circ}C$ owing to smaller carbide content and more retained austenite, it was harder after tempering at $520^{\circ}C$ due to larger precipitation hardening from finer $M_{23}C_6$.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.9 no.4
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• pp.154-160
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• 2000

Martensitic stainless steels containing 12%Cr are commonly used in quenched and tempered conditions. The quenching heat treatment involves annealing to obtain austenite and to dissolve the carbides , followed by cooling to transform the austenite into martensite and often to cause carbide predipitation. In this study, we used three different tempered specimens which were temperated at 30$0^{\circ}C$, 67$0^{\circ}C$ and 75$0^{\circ}C$ . The crack propagation and fracture toughness tests were performed on this three different specimens. The experimental results showed that the highest value of crack growth rate and the lowest value of fracture toughness were observed in the specimen which were temperated at $600^{\circ}C$, however, when the specimen were temperated at 75$0^{\circ}C$, the vale of crack growth rate was significantly decreased and the value of fracture toughness was significantly increased as compared to which were temperated at $600^{\circ}C$.

• Corrosion Science and Technology
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• v.12 no.6
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• pp.265-273
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• 2013

Ti-stabilized 11 wt% Cr ferritic stainless steels (FSSs) for automotive exhaust systems have been experienced intergranular corrosion (IC) in some heat-affected zone (HAZ). The effects of sensitizing heat-treatment and silicon on IC were studied. Time-Temperature-Sensitization (TTS) curves showed that sensitization to IC was observed at the steels heat-treated at the temperature lower than $650^{\circ}C$ and that silicon improved IC resistance. The sensitization was explained by chromium depletion theory, where chromium is depleted by precipitation of chromium carbide during sensitizing heat-treatment. It was confirmed with the results from the analysis of precipitates as well as the thermodynamical prediction of stable phases. In addition, the role of silicon on IC was explained with the stabilization of grain boundary. In other words, silicon promoted the formation of the grain boundaries with low energy where precipitation was suppressed and consequently, the formation of Cr-depleted zone was retarded. The effect of silicon on the formation of grain boundaries with low energy was proved by the analysis of coincidence site lattice (CSL) grain boundary, which is a typical grain boundary with low energy.

• Journal of Power System Engineering
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• v.19 no.6
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• pp.12-18
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• 2015

Austenitic stainless steels generally experience the occurrence of chromium-depleted zones at the boundaries, known as sensitization, caused by the carbide precipitation that takes place due to a welding process or heat treatment. Normally, the depleted zones become the focus of the intense corrosion. In this study, the Cr-free organic/inorganic hybrid solution was developed, and the artificially degraded STS316S and STS347H with the solution-coating investigated the corrosion resistance by salt spray test. Both the OIBD-1 and OIBD-2 solutions improved the corrosion resistance of STS310S and STS347H. The corrosion resistance with the OIBD-1 solution was better than that of OIBD-2 solution. Additionally, Both solutions have been proven excellence in adhesion ability, boiling water resistance and flexibility. However, a problem of rubbing after the boiling was found out to be overcome.

• Korean Journal of Metals and Materials
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• v.50 no.7
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• pp.517-522
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• 2012

In this study, a super carburizing treatment was applied to improve roller pitting fatigue life. It produced excellent properties of surface hardness and temper softening resistance by forming precipitation of fine and spherodized carbides on a tempered marstensite matrix through the repeated process of carburization and diffusion after high temperature carburizing step 1. The cycle II performed two times carburizing/diffusion cycle (process) after super carburization at $1,000^{\circ}C$ had fine and spherodized carbides to subsurface $200{\mu}m$. In this case, the carbide was $(Fe,Cr)_3C$ and there was not any massive carbides. In the case of Cycle II, the roller pitting fatigue life had a 6.15 million cycles. It was improved 48% compared to normal gas carburizing treatment.

• Korean Journal of Materials Research
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• v.23 no.3
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• pp.190-193
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• 2013

Spatial distributions of alloying elements of an Fe-based amorphous ribbon with a nominal composition of $Fe_{75}C_{11}Si_2B_8Cr_4$ were analyzed through the atom probe tomography method. The amorphous ribbon was prepared through the melt spinning method. The macroscopic amorphous natures were confirmed using an X-ray diffractometer (XRD) and a differential scanning calorimeter (DSC). Atom Probe (Cameca LEAP 3000X HR) analyses were carried out in pulsed voltage mode at a specimen base temperature of about 60 K, a pulse to base voltage ratio of 15 %, and a pulse frequency of 200 kHz. The target detection rate was set to 5 ions per 1000 pulses. Based on a statistical analyses of the data obtained from the volume of $59{\times}59{\times}33nm^3$, homogeneous distributions of alloying elements in nano-scales were concluded. Even with high carbon and strong carbide forming element contents, nano-scale segregation zones of alloying elements were not detected within the Fe-based amorphous ribbon. However, the existence of small sub-nanometer scale clusters due to short range ordering cannot be completely excluded.