• Title/Summary/Keyword: Corrosive Resistance

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An Electrochemical Evaluation on the Corrosion Property of Metallizing Film (용사 도막의 내식성에 관한 전기화학적 평가)

  • Shin, Joong-Ha;Moon, Kyung-Man
    • Corrosion Science and Technology
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    • v.9 no.6
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    • pp.325-330
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    • 2010
  • Many surface protection methods have been developed to apply for constructional steels used under severe corrosive environment. Thermal spray coating has been known to be an attractive technique due to its relatively high coating speed. Furthermore high corrosion resistance of coated film with thermal spray is required to expand its application. Four types of coated films(DFT:300 um) such as pure zinc, pure aluminum and two Al-Zn alloy (Al:Zn=85:15 and Al:Zn=95:5) onto the carbon steel (SS401) were prepared with arc spray, and the corrosion behavior of their samples were evaluated by electrochemical method in this study. Pure aluminum sample showed high corrosion resistance behavior exposed to sea water solution and pure zinc and alloy (Al:Zn=95:5) samples followed pure aluminum sample. The other alloy(Al:Zn=85:15) so called galvalume coated onto the carbon steel ranks the 4th corrosion resistance in this study. The results of porosity ratio of those samples by observation are well matched with the electrochemical data.

Corrosion Resistance and Thermo-optical Properties of Lithium Polysilicate Spray Coated Anodized AZ31B Magnesium Alloy for Space Applications

  • Ghosh, Rahul;Thota, Hari K.;Rani, R. Uma
    • Corrosion Science and Technology
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    • v.18 no.5
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    • pp.182-189
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    • 2019
  • A thin spray coating of inorganic black lithium polysilicate (IBLP) on black anodized AZ31B magnesium alloy was fabricated for better corrosion resistance and thermo-optical properties for thermal control of spacecraft components. The morphology of the specimens with and without IBLP-based spray coating was characterized by SEM-EDS techniques. Impedance and potentiodynamic measurements on the specimens revealed better corrosion resistance for the specimen with a thin coating of lithium polysilicate. This was primarily due to the presence of lithium polysilicate inside the micro-cracks of the black anodized specimen, restricting the diffusion paths for corrosive media. Environmental tests, namely, humidity, thermal cycling, thermo vacuum performance, were used to evaluate the space-worthiness of the coating. The thermo-optical properties of the coating were measured before and after each environmental test to ascertain its stability. The specimen with an IBLP-based spray coating showed enhanced thermo-optical properties, greater than ~0.90. Hence, the proposed coating demonstrated better handling, better corrosion resistance, and space-worthiness during the pre-launch phase owing to its improved thermo-optical properties.

Measurement of Localized Corrosion Resistance in Additively Manufactured Ti-6Al-4V Alloys Using Electrochemical Critical Localized Corrosion Temperature (E-CLCT) versus Electrochemical Critical Localized Corrosion Potential (E-CLCP) (적층가공 (3D 프린팅) Ti-6Al-4V합금의 국부부식 저항성 평가를 위한 임계국부부식온도와 임계국부부식전위 측정방법의 비교)

  • Seo, Dong-Il;Lee, Jae-Bong
    • Corrosion Science and Technology
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    • v.20 no.1
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    • pp.37-43
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    • 2021
  • Additively manufactured (AM) Ti-6Al-4V alloys exhibit a dominant acicular martensite phase (α'), which is characterized by an unstable energy state and highly localized corrosion susceptibility. Electrochemical critical localized corrosion temperature (E-CLCT, ISO 22910: 2020) and electrochemical critical localized corrosion potential (E-CLCP, ISO AWI 4631: 2021) were measured to analyze the localized corrosion resistance of the AM Ti-6Al-4V alloy. Although E-CLCP was measured under mild corrosive conditions such as human body, the validity of evaluating localized corrosion resistance of AM titanium alloys was demonstrated by comparison with E-CLCT. However, the mechanisms of resistance to localized corrosion on the as-received and heat-treated AM Ti-6Al-4V alloys under E-CLCT and E-CLCP differ at various temperatures because of differences in properties under localized corrosion and repassivation. The E-CLCT is mainly measured for initiation of localized corrosion on the AM titanium alloys based on temperature, whereas the E-CLCP yields repassivation potential of re-generated passive films of AM titanium alloys after breaking down.

A SCANNING ELECTRON MICROSCOPIC STUDY ON THE CORROSION RESIST ANCE OF CHEMICALLY AND THERMALLY RECYCLED METAL BRACKETS (화학처리(化學處理) 및 열처리(熱處理)한 재생금속(再生金屬) Bracket의 내식성(耐蝕性)에 관(關)한 주사전자현미경적(走査電子顯微鏡的) 연구(硏究))

  • Yoon, Young Joo;Lee, Dong-Joo
    • The korean journal of orthodontics
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    • v.19 no.2
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    • pp.85-93
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    • 1989
  • The purpose of this study was to evalute the corrosion resistance of chemically and thermally recycled metal brackets. In vivo, two types of recycled metal brackets and new brackets were directly bonded for 1 year, and then the microstructure of bracket surface was examined by S.E.M. (J.S.M.-840 Scanning Electron Microscope, Japan). The following results were obtained. 1) The microstructure of new and chemically recycled metal bracket surfaces showed regular structure without island formation and recrystallization; and after 1 year, the same appearance except some scratches. 2) The microstructure of thermally recycled metal bracket surfaces showed a beginning of island formation and recrystallization by annealing, and after 1 year, a typical corrosive appearance, completely island formation with some metal grains by recrystallization. 3) Chemically recycled metal brackets showed better corrosion resistance than thermally recycled metal brackets.

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Effect of Corrosion on Fatigue Life of Piping material under Repeating Load (반복하중을 받는 배관용 강재의 피로수명에 미치는 부식의 영향)

  • Park, Keyung-Dong;An, Jae-Pil
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.11a
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    • pp.228-229
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    • 2005
  • The compressive residual stress, which is induced by shot peening process, has the effect of increasing the intrinsic fatigue strength of surface and therefore would be beneficial in reducing the probability of fatigue damage. However, it was not known that the effect of shot peening in corrosion environment. In this study, the effect of shot peening on corrosion fatigue crack growth of sping steel immersed in 6% $FeCl_3$ solution and corrosion characteristics with considering fracture mechanics. The results of the experimental study corrosion fatigue characteristics of spring steel are as follows; the fatigue crack growth rate of the shot peening material was lower than of the un peening material. And fatigue life shows more improvement in the shot peening material than un peening material. This is because the compressive residual stress of surface operate resistance of corrosion fatigue crack propagation. It is assumed that the shot peening process improve corrosive resistance and mechanical property.

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Fire Resistance of Inorganic Polymer Composites for Repair and Rehabilitation (보수.보강에 사용하는 무기계 폴리머 복합재료의 내열성능)

  • Balaguru, P.N.;Chung, Lan
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.10a
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    • pp.647-652
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    • 1997
  • Repair and rehabilitation of existing structures is becoming a major part of construction, both in the industrially developed and developing countries. Advanced high strength composites are being utilized more and more for these applications because they are much stronger than steel, non-corrosive, and light. The light weight reduces the construction cost and time sustantially. The fibers are normally made of aramid, carbon, or glass and the binders are typically epoxies or esters. One major disadvantage of these composites is the vulnerability to fire. In most instance, the temperature cannot exceed $300^{\cire}C$. Since carbon and glass can substain high temperatures, an inorganic polymer is being evaluated for use as a matrix. The matrix can sustain more than $1000^{\cire}C$. The results reported in this paper deal with the mechanical properties of carbon composites made with the inorganic polymer and the behavior strengthened reinforced concrete beams. The results indicate that the new matrix can be successfully utilized for a number of applications.

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The corrosion-resistant of Al-coated xstainless in molten carbonate (알루미늄 코팅처리 스테인레스강의 융탄산염 내부식성)

  • 조남웅;장세기;전재호;신정철
    • Journal of the Korean institute of surface engineering
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    • v.31 no.1
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    • pp.3-11
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    • 1998
  • Molten Carbonate Fuel cell is a promising new type electric power generation system which can achieve high efficiency, lower matrrial cost and high operating temperature Making internal reforming possible. Although the development of the MCEC is progressing rapidly toward commercialization, two important tchological problems such as dissolution of NiO cathode and not corrosion of metallic separator plate must be resolved. Because MCFC is operated at $650^{\circ}C$ and the electrolyte is very corrosive, corrosion-resistance of separator plated against oxidation abd molten carbonate is required. Al-coating on separator material for corrosion-resistance was carried out by painting, thermal spraying. hot dipping and vacuum vapour deposition. The corrosion of Al-coated STS 316S and 316L in molten carbonate at $700^{\circ}C$was studied. Vacuum vapour deposition and thermal spraing for Al-coating on STS 310S and 316L were the most effective methods for protecting thestainless steel corrosion in molten carbonate.

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Fundamental Study of Polymer-modified Cement Mortar for Maintenance in Concrete Structure According to Ambient Temperature (온도에 따른 콘크리트 구조체 단면 보수용 폴리머 모르타르의 기초적 연구)

  • Seo, Jung-Pil;Kim, Jae-Won;Lee, Jung-Koo;Choi, Hun-Gug;Kang, Cheol;Kim, Jin-Man
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2007.04a
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    • pp.59-62
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    • 2007
  • Nowadays, polymer-cement mortars are widely used in construction field(floorings and pavements, water-proofings, adhesives, repair materials, deck coverings, anti-corrosive linings) Because of excellent performance such as high tensile and flexural strength, waterproofness, excellent adhesion, good durability, improved wear and chemical resistances. This article presents the results of experimental study that investigates the effect of ambient temperature on the strength properties of polymer-modified cement mortar. Results show that when increasing the polymer proportion in mortar on different ambient temperature, the compressive strength and flexural strength are decreased, and also alkali resistance is decreased.

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A Novel Under-film Corrosion Tester Using Current Interrupter Technique

  • Tanabe, Hiroyuki;Taki, Tohru;Nagai, Masanori;Ogawa, Osamu
    • Corrosion Science and Technology
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    • v.3 no.6
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    • pp.240-244
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    • 2004
  • Recently a variety of electrochemical techniques have been used for the measurement of under-film corrosion of coated steel. Each method has its own characteristic and is suitable to determine some kinds of anti-corrosive mechanisms of coating film. We developed a new under-film corrosion tester (UFCT) which adoped current interrupter technique in principle. Electrochemical parameters can be measured by UFCT. It is possible for the novel under-film corrosion tester to evaluate under-film corrosion of steel covered with high electric resistance coating film which has no defect and is not easy to evaluate it by other methods. Finally some experimental results of protective coating performance obtained by UFCT were discussed.

Life Cycle Cost Analysis of Steel Railroad Bridges Under Corrosive Environment (강철도교의 부식영향에 따른 생애주기비용분석)

  • 이종수;유선미;조선규;김만철
    • Proceedings of the KSR Conference
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    • 2002.10a
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    • pp.684-689
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    • 2002
  • This paper represents the life-cycle cost(LCC) of steel bridges which are located on the train-network. Corrosion problems are mainly considered in the steel members such as steel plate girder, box girder, truss and arch. Based on the current value, initial construction cost, maintenance cost and demolition cost are calculated and life-cycle costs are formulated for the several types of bridges. From the comparison on each LCC, an effective painting method is recommended for reducing the LCC of steel bridges. Even though the initial cost of Super Weather Resistance Heavy Duty Paintings (Resin Fluoride) is expensive, because of the long endurance, the LCC of steel bridges painted with Super Weather Resistance Heavy Duty Paintings (Resin Fluoride) is less than that painted with General Heavy Duty (Rubber Chloride).

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