• Corrosion Science and Technology
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• v.14 no.6
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• pp.261-266
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• 2015

The capacity of passive metal to repassivate after film damage determines the development of local corrosion and the resistance to corrosion failures. In this work, the repassivation kinetics of 316L stainless steel (316L SS) was investigated in borate buffer solution (pH 9.1) using a novel abrading electrode technique. The repassivation kinetics was analyzed in terms of the current density flowing from freshly bare 316L SS surface as measured by a potentiostatic method. During the early phase of decay (t < 2 s), according to the Avrami kinetics-based film growth model, the transient current was separated into anodic dissolution ($i_{diss}$) and film formation ($i_{film}$) components and analyzed individually. The film reformation rate and thickness were compared according to applied potential. Anodic dissolution initially dominated the repassivation for a short time, and the amount of dissolution increased with increasing applied potential in the passive region. Film growth at higher potentials occurred more rapidly compared to at lower potentials. Increasing the applied potential from 0 $V_{SCE}$ to 0.8 $V_{SCE}$ resulted in a thicker passive film (0.12 to 0.52 nm). If the oxide monolayer covered the entire bare surface (${\theta}=1$), the electric field strength through the thin passive film reached $1.6{\times}10^7V/cm$.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.28 no.5
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• pp.563-570
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• 2015

The existing research on the damage detection method for building structures has considered the damages from the excessive loadings such as the earthquake. However, the structural performance of building structures could be reduced due to the deterioration based on the chloride, carbonation during the long-term time. Thus, to effectively manage the healthiness of structures, the deterioration influences on the structures should be checked. In this study, the corrosion of rebars by the chloride is considered as the deterioration factor. To consider the structural performance reduction of the corroded rebars, the yield strength, cross-sectional area, rupture strain of rebars and the compressive strength of cover concrete based on the corrosion level are estimated. These properties of rebars and cover concrete are used for the procedure to evaluate the structural performance reduction of structural member level and the building level. The moment-curvature analysis is performed to evaluate the structural performance reduction of structural member level. Also, the eigenvalue analysis and the pushover analysis are performed to investigate the natural period and mode shape and the strength and deformation performance of buildings, respectively.

• Corrosion Science and Technology
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• v.3 no.5
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• pp.198-208
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• 2004

Although there has been no general agreement on the mechanism of primary water stress corrosion cracking (PWSCC) as one of major degradation modes of Ni-base alloys in pressurized water reactors (PWR's), common postulation derived from previous studies is that the damage to the alloy substrate can be related to mass transport characteristics and/or repair properties of overlaid oxide film. Recently, it was shown that the oxide film structure and PWSCC initiation time as well as crack growth rate were systematically varied as a function of dissolved hydrogen concentration in high temperature water, supporting the postulation. In order to understand how the oxide film composition can vary with water chemistry, this study was conducted to characterize oxide films on Alloy 600 by an in-situ Raman spectroscopy. Based on both experimental and thermodynamic prediction results, Ni/NiO thermodynamic equilibrium condition was defined as a function of electrochemical potential and temperature. The results agree well with Attanasio et al.'s data by contact electrical resistance measurements. The anomalously high PWSCC growth rate consistently observed in the vicinity of Ni/NiO equilibrium is then attributed to weak thermodynamic stability of NiO. Redox-induced phase transition between Ni metal and NiO may undermine the integrity of NiO and enhance presumably the percolation of oxidizing environment through the oxide film, especially along grain boundaries. The redox-induced grain boundary oxide degradation mechanism has been postulated and will be tested by using the in-situ Raman facility.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.1
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• pp.79-88
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• 2023

In this study, a development of the rust formation arising from steel corrosion was modelled to quantify the structural impact in steel reinforced concrete. The interfacial gap, cover depth and diameter of steel rebar were taken for variables in modelling. It was found that the interfacial gap was the most influencing on the structural limit at steel corrosion, followed by steel diameter and cover depth. At 75 mm of cover depth with 20 mm of the steel diameter, the rust amount to reach cracking accounted for 16.95-27.69 ㎛ to 1-10 ㎛ of the interfacial gap. It was found that there was no risk of cracking and structural limit until the rust was formed within the interfacial gap. With a further formation of rust, the concrete section was successively behaved to yielding, cracking and failure. Additionally, the interfacial gap was the most dominant parameter for the rust amount to reach the cracking of concrete at the interfacial zone, whilst the cover depth had a marginal effect on cracking but had a crucial influence on the rust to failure.

• Korea Science and Art Forum
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• v.30
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• pp.251-261
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• 2017

Metal is a material that has exerted a lot of influence on the development of human cultures, and has closely connected with our life from the past to the present. Types of metal we have used from the prehistoric times are varied, and iron relics take the largest percentage of metal relics excavated in our country. The biggest threat to the existence of iron relics ranging from excavated relics to the ones that are transmitted is the process of corrosion, and physical removal has been used the most for removing corroded oxides. For details for removal of corrosion oxides, this thesis aimed to research on the chemical corrosion oxides remover that protects parent material of iron relics but treats corrosion oxides only. For safe and effective removal of corrosion oxides of iron relics, this study was conducted aiming at finding the possibility of and optimized composition for removal of iron relics corrosion oxides by manufacturing new acid, alkaline and neutral oxides removers and changing their composition variously, exploring the possibility by applying the agents to modern relics. The results of this study are as follows: First, the acid solution removed only some part of corrosive substance oxidized on the surface of metal specimen. Second, the application of each of alkaline and neutral solution resulted in remaining black-colored corrosive substance, but it was removed when the quantity of the solution and the duration of application are increased. Third, All the three solutions did not cause any damage to parent material in the course of application, and showed the result that they are capable of removing unstable oxide layer while protecting parent material and stable corrosive layer as the solutions would be able to deal with situation by a relic only through the control of concentration of solution and duration of application.

• Proceedings of the KSR Conference
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• 2010.06a
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• pp.1898-1903
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• 2010

The hold clamp which is for holding feeder distribution line in direct current can be lengthened its span of life by inserting insulators(EDPM rubber) through improving its function such as preventing damage from temperature change and electric corrosion. This paper reviews the development background, design, manufacture and performance assessment of the hold clamp inserting insulators to prevent circulating current.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 2005.05a
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• pp.228-233
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• 2005

The damage of the pressure courage by degradation can become the reason of unexpected break down or failure accident and it is very important because safety accident, the production loss, environmental pollution, social problems are occur. Consequently The result to investigat of failure accident for domestic pressure vessel, the factor of degradation is SCC, Sorrosion, Cavity, Crack.

• Proceedings of KOSOMES biannual meeting
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• 2017.11a
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• pp.85-85
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• 2017

• Magazine of the Korea Institute for Structural Maintenance and Inspection
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• v.18 no.3
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• pp.27-31
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• 2014

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2002.10b
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• pp.465-466
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• 2002

In any mechanical system consisting of gears, shafts and/or bearings, the majority of metallic particles deposited into and carried by the lubrication system originate from the deterioration of oil-wetted working surfaces, even in proper lubrication system, due to failure mechanism (s) such as wear, fatigue and fretting corrosion. Determination of the point at which transition from normal to abnormal or to actual damage occurs has become a focus of attention in research activities for years, because it has been recognized that reliable, economic operation can be achieved through appropriate preventative measures. Known collectively from 'all size wear debris analysis' as early failure detection, the methods of testing for damage differ considerably, range from a micron or a submicron size debris analysis to Magnetic Chip Detector (MCD) ferrous debris analysis. This paper will be focused on the utilization of the low-cost analysis techniques for evaluation of industrial machinery condition.