• Title/Summary/Keyword: Corrosion rate measurement

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Electrical Measurement of SOx Dew Point (SOx노점의 전기적 측정)

  • Chun, Y.N.;Yong, K.J.;Chae, J.O.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.7 no.4
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    • pp.600-610
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    • 1995
  • When combustion gas is cooled down below the dew point of sulfuric acid vapor in the heat recovery systems, condensation occurs. Since the condensed sulfuric acid solution causes low-temperature corrosion in materials, it is important to measure the SOx dew point by electric measurement. In this study, two kinds of probes having electric gaps of 1mm or 2mm were used. and experiments were carried out by the parameters of sulfuric acid vapor and water vapor concentration. The changes of electric current caused by sulfuric acid condensed on the surface of probe according to the cooling rate and the probe head surface temperature were sudied. The opimum cooling rate was decreased with the increasing of water vaper concentration regardless of sulfuric acid concentration. The sensitivity of electric current is improved for the narrower gap(1mm) of ring electrodes, but it rarely affects the SOx dew point measuring of different probes according to the change of cooling rate.

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A Study of Non-destructive Measurement on the Reinforced Concrete Structure Damaged by Reinforcing Steel Corrosion (철근콘크리트구조물의 철근부식에 대한 비파괴 측정과 부식에 따른 균열거동)

  • 김성운;정한중;김창환;임선택
    • Proceedings of the Korea Concrete Institute Conference
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    • 1991.10a
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    • pp.80-85
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    • 1991
  • This experimental study was performed to derive the relationship between the measured values(corrosion potential) and the actual amount of corrosion products(reinforcing steel weight loss rate). Also the growth of crack due to the steel corrosion was oberved. First, the reinforcing steel of R/C specimen was corroded with chloride penetration and accelerated galvanostatic corrosion method. And then, the corrosion potential of reinforcing steel was measured with nondestructive tester.

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Effect of Ambient Temperature and Humidity on Corrosion Rate of Steel Bars in Concrete (환경 온·습도가 콘크리트 내 철근의 부식 속도에 미치는 영향 분석)

  • Du, Rujun;Jang, Indong;Cho, Junghyun;Yi, Chongku
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.05a
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    • pp.307-308
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    • 2021
  • Corrosion of reinforced steel inside concrete is an important cause of performance degradation of reinforced concrete structures and has a profound influence on the durability of structures. In this study, three groups of different reinforced concrete structures exposed to the natural environment were subjected to chloride ion accelerated corrosion tests for up to 180 days. The corrosion velocity and ambient temperature of the samples were measured and recorded every day. Based on Faraday's law, the corrosion speed of steel bars could be measured, and the ambient temperature and humidity around the structure in corresponding time were compared. Through the measurement of up to 180 days, the influence of external ambient temperature and humidity on the corrosion speed of steel bars inside the concrete structure was found out. The results show that there is a good direct proportional relationship between temperature and corrosion speed. When the ambient temperature increases by 15℃, the corrosion rate increases by about one time.

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Uncertainty in Potentiodynamic Polarization Resistance Measurement (동전위 분극저항 측정에서의 불확도)

  • Kim, Jong Jip
    • Corrosion Science and Technology
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    • v.8 no.5
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    • pp.193-196
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    • 2009
  • For the estimation of uncertainty in potentiodynamic polarization resistance measurement, the type A uncertainty was measured using type 316 stainless steel in an acidified NaCl solution. Sensitivity coefficients were determined for measurand such as scan rate of potential, temperature of solution, concentration of NaCl, concentration of HCl, surface roughness of specimen and flow rate of purging gas. Sensitivity coefficients were large for the measurand such as the scan rate of potential, temperature of solution and roughness of specimen. However, the sensitivity coefficients were not the major factors influencing the combined standard uncertainty of polarization resistance due to the low values of uncertainty in measurements of the measurands. A major influencing factor was the concentration of NaCl. The value of type A uncertainty was 1.1 times the value of type B uncertainty, and the combined standard uncertainty was 10.5 % of the average value of polarization resistance.

Cathodic Protection Behavior of Coastal Bridge Structure with Sacrificial Anode Cathodic Protection System (희생양극식 음극방식이 적용된 해안 교량 구조물의 방식거동)

  • Ha, Ji-Myung;Jin, Chung-Kuk;Jeong, Jin-A
    • Corrosion Science and Technology
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    • v.11 no.6
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    • pp.242-246
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    • 2012
  • This measurement represents the effectiveness of sacrificial anode cathodic protection (SACP) system in a coastal bridge structure. To verify the cathodic protection (CP) effect, the monitoring sensor (DMS-100) that could measure potential, corrosion rate, current, concrete resistivity, and temperature was embedded. The measurement conducted for three years after CP system was installed. Specifically, due to the fact that fresh water and sea water was repeated in the bridge structure, this bridge structure presented special CP behavior. Measurement factors were CP potential, CP current, concrete resistivity, and depolarization potential. In addition, visual inspection was also carried out. As a result of current and depolarization measurement, CP system was well activated in most piers.

Uncertainty evaluation in electrochemical noise resistance measurement (전기화학적 노이즈 저항 측정에서의 불확도 평가)

  • Kim, Jong Jip;Kang, Su Yeon
    • Corrosion Science and Technology
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    • v.12 no.5
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    • pp.220-226
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    • 2013
  • The uncertainty in statistical noise resistance measurement was evaluated for a type 316 stainless steel in NaCl solutions at room temperature. Sensitivity coefficients were determined for measurands or variables such as NaCl concentration, pH, solution temperature, surface roughness, inert gas flow rate and bias potential amplitude. The coefficients were larger for the variables such as NaCl concentration, pH, inert gas flow rate and solution temperature, and they were the major factors increasing the combined standard uncertainty of noise resistance. However, the contribution to the uncertainty in noise resistance measurement from the above variables was remarkably low compared to that from repeated measurements of noise resistance, and thus, it is difficult to lower the uncertainty in noise resistance measurement significantly by lowering the uncertainties related with NaCl concentration, pH, inert gas flow rate and solution temperature. In addition, the uncertainty in noise resistance measurement was high amounting to 17.3 % of the mean, indicating that the reliability in measurement of noise resistance is low.

Effect of Specimen Area on the Corrosion Rate of Low Alloy Steel (저합금강의 부식속도에 미치는 시편 면적의 영향)

  • Kim, Min-Jun;Jang, Young-Wook;Yoo, Yun-Ha;Kim, Jong-Jip;Kim, Jung-Gu
    • Journal of the Korean Electrochemical Society
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    • v.13 no.2
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    • pp.96-102
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    • 2010
  • Effects of specimen area on the corrosion rate of low alloy steel were studied in sulfuric acid solution. The corrosion behavior of specimen was tested by electrochemical impedance spectroscopy (EIS), linear polarization resistance measurement (LPR) and potentiodynamic polarization measurement. The surface was analyzed by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and electron probe X-ray micro analyzer (EPMA). As surface area was increased, corrosion rate was increased by the effect of small anode-large cathode.

Corrosion Behavior of Carbon Steel in Diluted Sulfuric Acid based on Seawater

  • Kim, Mun Su;Jeong, Jin-A
    • Corrosion Science and Technology
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    • v.18 no.3
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    • pp.78-85
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    • 2019
  • The International Maritime Organization (IMO) will administer a new 0.5% global sulfur cap on fuel content from 1 January 2020, lowering from the present 3.5% limit. Seawater $SO_x$ (sulfur oxide) scrubbing is especially spray scrubbing and a promising alternative to complying with the IMO regulation. However, the ionization of $SO_2$ (sulfur dioxide) and the $H_2SO_4$ (sulfuric acid) formed from $SO_3$ (sulfur trioxide) is proposed to accelerate corrosion of the internal seawater pipe. Apparently, the corrosion of the scrubber seawater piping system occurs in a severe and frequent manner. Hence, in this study, electrochemical measurement and weight loss of carbon steel (used as seawater pipe in most of the ships) in diluted sulfuric acid solution were investigated to determine corrosion rate, corrosion current density, corrosion potential, electrochemical behavior, and impressed-current density. Accordingly, the corrosion rate of carbon steel sheet in various diluted sulfuric acid solutions was observed to be greater than that in natural seawater, thus suggesting the fundamental data to deal with corrosion problems in scrubber seawater pipe.

Corrosion Property Evaluation of Copper Alloy Tubes against Sea Water

  • Pang, Beilli;Ong, Sang-Kil;Lee, Hong-Ro
    • Journal of the Korean institute of surface engineering
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    • v.42 no.6
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    • pp.280-286
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    • 2009
  • In this study, the corrosion property of copper alloy tubes in seawater has been investigated. Three copper alloys of nominal composition Cu-20Zn-2Al(Al-Brass), Cu-30Ni(CN70/30) and Cu-10Ni(CN90/10) were considered. The samples were immersed in 3%NaCl flowing solution at $90^{\circ}C$ for 30, 50 and 80 days. Corrosion rate of copper alloy tubes in 3%NaCl flowing solution was investigated by weight-loss measurements and electrochemical test. The CN70/30 showed lowest corrosion rate among three copper alloy tubes. Because of passive films formation, corrosion rates of three types of copper tubes were decrease with time. Surface characteristics of copper alloy tubes were analyzed by optical micrograph(OM), scanning electronic microscopy (SEM), energy dispersive X-ray analysis(EDAX) and X-ray diffraction patterns(XRD). CN70/30 showed partly pitting problem on the surface owing to high Fe content, even though having high resistant against corrosion. Cracks appeared on the surface of CN90/10 and CN70/30 after more than 50 days immersion, which could be derived from high nickel contents.

Performance indicator of the atmospheric corrosion monitor and concrete corrosion sensors in Kuwait field research station

  • Husain, A.;Al-Bahar, Suad Kh.;Salam, Safaa A. Abdul
    • Smart Structures and Systems
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    • v.17 no.6
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    • pp.981-994
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    • 2016
  • Two field research stations based upon atmospheric corrosivity monitoring combined with reinforced concrete corrosion rate sensors have been established in Kuwait. This was established for the purpose of remote monitoring of building materials performance for concrete under Kuwait atmospheric environment. The two field research sites for concrete have been based upon an outcome from a research investigation intended for monitoring the atmospheric corrosivity from weathering station distributed in eight areas, and in different regions in Kuwait. Data on corrosivity measurements are essential for the development of specification of an optimized corrosion resistance system for reinforced concrete manufactured products. This study aims to optimize, characterize, and utilize long-term concrete structural health monitoring through on line corrosion measurement and to determine the feasibility and viability of the integrated anode ladder corrosion sensors embedded in concrete. The atmospheric corrosivity categories supported with GSM remote data acquisition system from eight corrosion monitoring stations at different regions in Kuwait are being classified according to standard ISO 9223. The two nominated field sites where based upon time of wetness and bimetallic corrosion rate from atmospheric data where metals and rebar's concrete are likely to be used. Eight concrete blocks with embeddable anodic ladder corrosion sensors were placed in the atmospheric zone adjacent to the sea shore at KISR site. The anodic ladder corrosion rate sensors for concrete were installed to provide an early warning system on prediction of the corrosion propagation and on developing new insights on the long-term durability performance and repair of concrete structures to lower labor cost. The results show the atmospheric corrosivity data of the environment and the feasibility of data retrieval of the corrosion potential of concrete from the embeddable sets of anodic ladder corrosion sensors.