• Corrosion Science and Technology
• /
• 제15권6호
• /
• pp.271-280
• /
• 2016

An approach to achieving the ambitious goal of cost effectively extending the safe operation life of energy pipeline to 100 years is the application of health monitoring and life prediction tools that are able to provide both long-term remnant pipeline life prediction and in-situ pipeline condition monitoring. A critical step is the enhancement of technological capabilities that are required for understanding and quantifying the effects of key factors influencing buried steel pipeline corrosion and environmentally assisted materials degradation, and the development of condition monitoring technologies that are able to provide in-situ monitoring and site-specific warning of pipeline damage. This paper provides an overview of our current research aimed at developing new sensors and electrochemical cells for monitoring, categorising and quantifying the level and nature of external pipeline and coating damages under the combined effects of various inter-related variables and processes such as localised corrosion, coating cracking and disbondment, cathodic shielding, transit loss of cathodic protection.

• Computers and Concrete
• /
• 제15권3호
• /
• pp.411-436
• /
• 2015

In this work, a comprehensive approach to model the structural behaviour of Reinforced Concrete (RC) beams subjected to reinforcement corrosion is proposed. The coupled environmental - mechanical damage model developed by some of the authors is enhanced for considering the main effects of corrosion on concrete, on composite interaction between reinforcement bars and concrete and on steel reinforcement. This approach is adopted for reproducing a set of experimental tests on RC beams with different corrosion degrees. After the simulation of the sound beams, the main parameters involved in the relationships characterizing the effects of corrosion are calibrated and tested, referring to one degraded beam. Then, in order to validate the proposed approach and to assess its ability to predict the structural response of deteriorated elements, several corroded beams are analyzed. The numerical results show a good agreement with the experimental ones: in particular, the proposed model properly predicts the structural response in terms of both failure mode and load-deflection curves, with increasing corrosion level.

• Corrosion Science and Technology
• /
• 제18권5호
• /
• pp.155-167
• /
• 2019

In this study, two novel Schiff base compounds including (3-(4-Chlorophenyl isoxazole-5-yl) methanol and (3-(2,4 dichlorophenol isoxazole-5-yl) methanol as corrosion inhibitors for mild steel in 1 M hydrochloric acid solution were investigated by potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and density functional theory (DFT) computations. The results showed that the corrosion inhibition efficiency (IE) is remarkably enhanced with the growing concentration of the Schiff base inhibitors. The results from Tafel polarization and EIS methods showed that IE decreases with gradual increments of temperature. This process can be attributed to the displacement of the adsorption/desorption balance and hence to the diminution of the level of a surface coating. Also, the adsorption of two inhibitors over mild steel followed the Langmuir adsorption isotherm. Too, the results of the scanning electron microscope (SEM) images showed that the Schiff base inhibitors form an excellent protective film over mild steel and verified the results by electrochemical techniques. Additionally, the results from the experimental and those from DFT computations are in excellent accordance.

• Journal of Electrochemical Science and Technology
• /
• 제9권4호
• /
• pp.260-275
• /
• 2018

The corrosion inhibition of cast iron in 1 M HCl by Phenanthroline (Phen) was investigated using potentiodynamic polarization (PDP) curves, electrochemical impedance spectroscopy (EIS), surface analysis and theoretical calculations. It is found that Phen exhibits high inhibition activity towards the corrosive action of HCl and its adsorption obeys the Langmuir adsorption isotherm model. The results showed that inhibition efficiency increases with Phen concentration up to a maximum value of 96% at 1.4 mM, and decreases slightly with the increase in temperature. The free adsorption energy value indicates that Phen adsorbs on cast iron surface in 1 M HCl via a simultaneous physisorption and chemisorption mechanism. Scanning electron microscopy (SEM) micrographs, atomic force microscopy (AFM) and FTIR analysis confirmed the formation of a protective film on cast iron surface, resulting in the improvement of its corrosion resistance in the studied aggressive solution. Quantum chemical calculations at the DFT level were achieved to correlate electronic structure parameters of Phen molecules with their adsorption mode.

• Smart Structures and Systems
• /
• 제11권5호
• /
• pp.555-567
• /
• 2013

An Remote Corrosion Monitoring (RCM) system consists of an anode with low potential, the metallic structures against corrosion, an electrode to provide reference potential, and a data-acquisition system to ensure the potential difference for anticorrosion. In more detail, the data-acquisition (DAQ) system monitors the potential difference between the metallic structures and a reference electrode to identify the correct potential level against the corrosion of the infrastructures. Then, the measured data are transmitted to a central office to remotely keep track of the status of the corrosion monitoring (CM) system. To date, the RCM system is designed to achieve low power consumption, so that it can be simply powered by batteries. However, due to memory effect and the limited number of recharge cycles, it can entail the maintenance fee or sometimes cause failure to protect the metallic structures. To address this issue, the low-overhead energy harvesting circuitry for the RCM systems has designed to replenish energy storage elements (ESEs) along with redeeming the leakage of supercapacitors. Our developed energy harvester can scavenge the ambient energy from the corrosion monitoring environments and store it as useful electrical energy for powering local data-acquisition systems. In particular, this paper considers the energy harvesting from potential difference due to galvanic corrosion between a metallic infrastructure and a permanent copper/copper sulfate reference electrode. In addition, supercapacitors are adopted as an ESE to compensate for or overcome the limitations of batteries. Experimental results show that our proposed harvesting schemes significantly reduce the overhead of the charging circuitry, which enable fully charging up to a 350-F supercapacitor under the low corrosion power of 3 mW (i.e., 1 V/3 mA).

• 해양환경안전학회지
• /
• 제10권1호
• /
• pp.51-54
• /
• 2004

최근 양어 양식장은 증가하고 있으며 이러한 곳에 사용할 가열장치는 경울 수온 조절을 위해 사용된다. 해수 가열장치는 부식성이 높고 압력이 높은 곳에 사용하기 위하여 고강도와 내식성이 요구된다. 만약 저강도와 저내식성을 갖게 되면 결국 누설 또는 파손되어 해수오염을 일으킬 수 있다. 대부분의 부식은 정체된 액과 틈이 형성된 부위에서 부식의 발생이 일어난다. 이 연구에서는 430 스테인레스재를 크기 $15{\times}20{\times}3mmt$에 대하여 1N H2SO4 + 0.05N NaCl용액을 사용하여 틈부식을 시험하였다. 틈의 크기는 $0.24{\times}3{\times}15mmL$로 하였으며 외부에 300mV전위를 인가하였다. 실험 결과 틈 부식 유기 시간은 750초로 나타나고, 틈 전위 강화는 -320에서 -399mV로 나타나 부식의 주 원인이 전위강화 기구에 의해 발생하였다.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
• /
• pp.1069-1072
• /
• 2008

매립된 철근의 부식이 진행될 경우, 부착강도 및 강성이 감소되며, 구조물의 열화가 발생하여 사용 수명이 단축된다. 이러한 문제를 해결하기 위하여 RC 부재의 부착특성에 대한 평가가 인위적으로 철근을 빠르게 부식시키는 방법을 통하여 지금까지 연구되어왔다. 그러나, 이러한 인위적인 부식방법은 실제 부식 상황과 일치하지 않으며, 결과적으로 실제 상황에서의 RC 부재에 대한 부식 가능성을 과대평가할 수 있다. 따라서, 본 연구는 인위적인 방법과 자연적인 방법에 의해 RC 부재를 부식시킴으로써 부착 강성의 차이를 평가하고자 하였다. 자연적인 부식의 경우, 부식면적 50%에서 취성파괴가 발생했으며, 부식면적 80%이상에서는 부착강도가 약 10%이상 감소하였다. 특히, 자연적 부식의 경우 낮은 부식수준에서 콘크리트의 열화가 발생하였다. 따라서 향후 부식에 따른 부재의 성능저하를 평가하고자 할 경우에는 인위적으로 부식시킨 시험체로부터 평가하는 것은 곤란하며 반드시 자연적으로 부식시킨 시험체를 사용하여 성능을 평가해야 한다고 판단된다.

• Corrosion Science and Technology
• /
• 제19권4호
• /
• pp.203-210
• /
• 2020

The corrosion behavior of super austenitic stainless steel was studied by examining the characteristics of the sigma phase formed in the steel. A range of experimental and analytical methods was employed, including potentiodynamic polarization tests, critical pitting temperature tests, transmission electron microscopy, and energy-dispersive spectroscopy. Three steel samples with different sigma phase levels were obtained by intentionally adjusting the manufacturing process. The results showed that the corrosion resistance of the samples was strongly dependent upon the size and distribution of the sigma phase precipitated in the samples. The larger the size of the sigma phase, the higher the Mo content in the sigma phase and the higher the depletion level of Mo at the interface between the matrix/sigma phase, the more samples with a coarse-sized sigma phase were susceptible to localized pitting corrosion at the interface. These results suggest that various manufacturing processes, such as welding and the post-heat treatment of the steel, should be optimized so that both the size and fraction of the sigma phase precipitated in the steel are small to improve the resistance to localized corrosion.

• The Journal of Advanced Prosthodontics
• /
• 제5권1호
• /
• pp.44-50
• /
• 2013

PURPOSE. The aim of this study was to evaluate the effects of repeated porcelain firing process on the corrosion rates of the dental alloys. MATERIALS AND METHODS. Cr-Co, Cr-Ni and Pd-Ag alloys were used for this study. Each metal supported porcelain consisted of 30 specimens of 10 for 7, 9 and 11 firing each. Disc-shaped specimens 10 mm diameter and 3 mm thickness were formed by melting alloys with a propane-oxygen flame and casted with a centrifuge casting machine and then with the porcelain veneer fired onto the metal alloys. Corrosion tests were performed in quintuplicate for each alloy (after repeated porcelain firing) in Fusayama artificial saliva solution (pH = 5) in a low thermal-expansion borosilicate glass cell. Tamhane and Sheffe test was used to compare corrosion differences in the results after repeated firings and among 7, 9 and 11 firing for each alloy. The probability level for statistical significance was set at ${\alpha}$=0.05. RESULTS. The corrosion resistance was higher (30 mV), in case of 7 times firing (Commercial). On the other hand, it was lower in case of 11 times firing (5 mV) (P<.05). Conclusion. Repeated firings decreased corrosion resistance of Pd-Ag, Cr-Co and Cr-Ni alloys. The Pd-Ag alloy exhibited little corrosion in in vitro tests. The Cr-Ni alloy exhibited higher corrosion resistance than Cr-Co alloys in in vitro tests.

• 한국구조물진단유지관리공학회 논문집
• /
• 제20권2호
• /
• pp.10-17
• /
• 2016

RC(Reinforced Concrete) 부재는 인장영역에서 보강재가 하중을 지지해야 하므로, 철근부식은 내구성 뿐 아니라 안전성에서도 매우 중요하다. 본 연구에서는 최근 개발된 FRP Hybrid Bar와 일반 철근을 매립한 RC 보부재를 제작하였으며, ICM(Impressed Current Method)를 적용하여 철근부식을 촉진시켰다. 기존의 이론식인 Faraday 법칙을 이용하여 부식량을 평가하였으며, 일반설계강도를 가진 콘크리트 보부재에 대하여 휨시험을 수행하였다. 일반 철근에서는 부식량이 4.9~7.8% 수준으로 평가되었으며 이에 따른 휨 저항능력은 -25.4~-50.8% 수준으로 감소하였다. FRP Hybrid Bar를 매립한 RC 보에서는 부식과 휨 저항 감소가 평가되지 않았는데, 이는 에폭시 도료로 코팅된 철근의 우수한 내부식성에 기인한다. 촉진 부식실험에서는 FRP Hybrid Bar의 우수한 내부식성 및 부착성능을 확인하였는데, 실용화를 위해서는 장기적인 침지를 통한 내구성 평가가 필요하다고 판단된다.