• Corrosion Science and Technology
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• v.14 no.6
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• pp.253-260
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• 2015

The pitting behaviours of 304L and 316L stainless steels were investigated at $3^{\circ}C$ to $90^{\circ}C$ in 1 M solutions of NaCl, NaBr and NaI by potentiodynamic polarization. The temperature dependences of the pitting potential varied according to the anion, being near linear in bromide but exponential in chloride. As a result, at low temperatures grades 304L and 316L steel are most susceptible to pitting by bromide ions, while at high temperatures both stainless steels were more susceptible to pitting by small chloride anions than the larger bromide and iodide. Thus, increasing temperature appears to favour attack by smaller anions. This paper will attempt to rationalise both of the above findings in terms of the point defect model. Initial findings are that qualitatively this approach can be reasonably successful, but not at the quantitative level, possibly due to insufficient data on the mechanical properties of thin passive films.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.56 no.5
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• pp.876-883
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• 2007

The magnetic flux leakage(MFL) type nondestructive testing(NDT) method is widely used to detect corrosion, defects and mechanical deformation of the underground gas pipelines. The object pipeline is magnetically saturated by the magnetic system with permanent magnet and yokes. Hall sensors detect the leakage fields in the region of the defect. The defects are sometimes occurred in group. The accuracy of the detecting signals in this defect cluster become lowered because of the complexity of the defect cluster. In this paper, the effects of the multi -defects are analyzed. The detecting signals are computed by 3-dimensional finite element method and compared with real measurement. The results say that, rather than the size of the defects, the effects of the relative position of the multi-defects are very important on the detecting signals.

• International Journal of Automotive Technology
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• v.8 no.3
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• pp.343-349
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• 2007

One of the useful technologies for light-weightening of components required in the automobile and machine industry is to use high strength materials. To improve material properties, the carbonizing treatment, nitrifying treatment, and shot-peening method are representatively applied. However, the shot-peening method is generally used to remove surface defect on steel and to improve the fatigue strength of the surface. Benefits of shot-peening are increasing resistance against fatigue, stress corrosion cracking, fretting, galling, erosion and closing of pores. In this paper, the effect of shot-peening on the corrosion of SUP-9 steel immersed in a 3.5% NaCl solution and corrosion characteristics from heat treatment during the shot peening process has been investigated. The immersion test was performed on four kinds of specimens. Corrosion potential, the polarization curve, residual stress etc. Were analyzed from the experimental results.

• Corrosion Science and Technology
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• v.16 no.3
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• pp.151-159
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• 2017

The MA8 alloy (formula Mg-Mn-Се) has been shown to have greater corrosion stability than the VMD10 magnesium alloy (formula Mg-Zn-Zr-Y) in chloride-containing solutions by Scanning Vibrating Electrode Technique (SVET) and by optical microscopy, gravimetry, and volumetry. It has been established that the crucial factor for the corrosion activity of these samples is the occurrence of microgalvanic coupling at the sample surface. The peculiarities of the kinetics and mechanism of the corrosion in the local heterogeneous regions of the magnesium alloy surface were investigated by localized electrochemical techniques. The stages of the corrosion process in artificial defects in the coating obtained by plasma electrolytic oxidation (PEO) at the surface of the MA8 magnesium alloy were also studied. The analysis of the experimental data enabled us to determine that the corrosion process in the defect zone develops predominantly at the magnesium/coating interface. Based on the measurements of the corrosion rate of the samples with PEO and composite polymer-containing coatings, the best anticorrosion properties were displayed by the composite polymer-containing coatings.

• Journal of Advanced Marine Engineering and Technology
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• v.30 no.6
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• pp.731-739
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• 2006

Corrosion and lassitude are very important in the metal construction Currently, the shot peening is used much for removing the defect on the surface, improving the fatigue strength on surface. In this study. the influence of shot peening to the corrosion property were investigated in 3.5% NaCl, 10% HNO3 + 3% HF. 6% FeC13. The immersion test was performed on two kind of specimen(Removed corrosion product. RCP and Continuous immersed specimen: CIS). The immersion periods was 3600hours. Corrosion potential. weight loss, and fatigue crack growth characteristics were investigated. The result, shot peening in corrosion potential showed stable potential. Also, shot peening displayed small Weight loss than un peening. And Fatigue crack resistivity of shot peening in corrosion solution's fatigue crack appeared greatly than un peening.

• Journal of Ocean Engineering and Technology
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• v.24 no.4
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• pp.38-46
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• 2010

The wall thinning phenomenon of pipes was simulated as metal loss due to erosion and corrosion. Such wall thinning defects in the pipes of power plants are a very important safety consideration. In this study, we analyzed wall thinning defects that occurred by weld bead of weld zone of boost pump recirculation pipe. From the results of the analysis of pipe failures, numerical analysis was performed by Fluent v6.3.26 using the standard k-$\varepsilon$ model of the weld bead shape, such as an elliptical or a spherical shape, on the inner wall of the pipe. Using the results obtained, we showed the overlap effect by cavitations corrosion and erosion-corrosion at the bottom of the wall-thinning defect.

• Corrosion Science and Technology
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• v.3 no.6
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• pp.240-244
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• 2004

Recently a variety of electrochemical techniques have been used for the measurement of under-film corrosion of coated steel. Each method has its own characteristic and is suitable to determine some kinds of anti-corrosive mechanisms of coating film. We developed a new under-film corrosion tester (UFCT) which adoped current interrupter technique in principle. Electrochemical parameters can be measured by UFCT. It is possible for the novel under-film corrosion tester to evaluate under-film corrosion of steel covered with high electric resistance coating film which has no defect and is not easy to evaluate it by other methods. Finally some experimental results of protective coating performance obtained by UFCT were discussed.

• Corrosion Science and Technology
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• v.15 no.6
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• pp.290-296
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• 2016

This study was conducted in order to examine the effect of burn damage and the resultant anti-corrosion performance. The breakdown and defect of the paint film caused by burn damage are considered to affect not only the macroscopic appearance but also the adhesive force and the anti-corrosion performance of the paint film. The material of the paint film was epoxy paint that is used most widely for heavy-duty coating, and in order to induce burn damage, heat treatment with a torch was applied to the other side of the paint film. Surface and chemical structure changes according to aging were analyzed using FE-SEM and infrared absorption spectroscopy, and variation in the anti-corrosion performance was analyzed through the AC impedance test.

• Journal of the Korean Institute of Gas
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• v.20 no.6
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• pp.16-22
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• 2016

Coating pipe(PLP) has been generally used in buried site for protecting the corrosion. To prevent the damage by occurring the defect, other construction or execution works, an anti-oxidation environment was forcibly made by using protective potential. Coating and protective potential are applied simultaneously, but corrosion rate or defects are not easy to observe because soil composition has many uncertainty. Also, defect of coating pipe can not be directly observed. A corrosion coupon can easily measure a corrosion rate directly. The corrosion rate was measured with 6 scenarios using corrosion coupon during about 1 year(6 scenarios are based on soil type and protective potential or not in this research. Resultingly, the corrosion coupon has not occurred in the case of protected by potential current, but corrosion has occurred in a non-protected site. The corrosion rate was measured at least in the clay, and the propensity of corrosion rate was similar in other soil(sand and loams). The local corrosion has occurred in the clay because of high water content. On the other hand, general corrosion was occurred in sand and loams. Commonly, sand is not to corrosive soil. Although, corrosion occurred in sand can be estimated by chemical component and valid with chemical analysis report.

• Corrosion Science and Technology
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• v.12 no.1
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• pp.40-49
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• 2013

Effects of magnesium and pH on corrosion of aluminum galvanically coupled to iron have studied by using potentio- dynamic and static tests for polarization curves, Mott-Schottky test for analysis of semiconductor property, and GD-AES and XPS for film analysis. Pitting potential was sensitive to magnesium as an alloying element but not to pH, while passive current was sensitive to pH but not to magnesium. It was explained with, instead of point defect model (PDM), surface charge model describing that the ingression of chloride depends on the state of surface charge and passive film at film/solution interface is affected by pH. In addition, galvanic current of aluminum electrically coupled to iron was not affected by magnesium in pH 8.4, 0.2M citrate solution but was increased by magnesium at the solution of pH 9.1. The galvanic current at pH 9.1 increased with time at the initial stage and after the exposure of about 200 minute, decreased and stabilized. The behavior of the galvanic current was related with the concentration of magnesium at the surface. It agreed with the depletion of magnesium at the oxide surface by using glow discharge atomic emission spectroscopy (GD-AES). In addition, pitting potential of pure aluminum was reduced in neutral pH solution where chloride ion maybe are competitively adsorbed on pure aluminum. It was confirmed by the exponential decrease of pitting potential with log of [$Cl^-$] around 0.025 M of [$Cl^-$] and linear decrease of the pitting potential. From the above results, unlike magnesium, alloying elements with higher electron negativity, lowering isoelectric point (ISE), are recommended to be added to improve pitting corrosion resistance of aluminum and its alloys in neutral solutions as well as their galvanic corrosion resistance in weakly basic solutions.