• Journal of Environmental Science International
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• v.23 no.6
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• pp.1157-1163
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• 2014

The solid phase extractant (PVC-D2EHPA bead) was prepared by immobilizing di-2-ethylhexyl-phosphoric acid (D2EHPA) with polyvinyl chloride (PVC). The prepared PVC-D2EHPA beads were characterized by using fourier transform infrared spectrometer (FTIR) and scanning electron microscopy (SEM). The removal experiments of Cu(II) by PVC-D2EHPA beads conducted batchwise. The removal kinetics of Cu(II) was found to follow the pseudo-second-order model. The equilibrium data fitted well with Langmuir isotherm model and the maximum removal capacity was 2.6 mg/g at $20^{\circ}C$. The optimum pH region was in the range of 3.5 to 6. and the standard free energy (${\Delta}G^{\circ}$) was between -4.67~-4.98 kJ/mol, indicating the spontaneous nature of Cu(II) removal by PVC-D2EHPA beads.

• Journal of Conservation Science
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• v.36 no.5
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• pp.405-420
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• 2020

A convergence research was conducted on glass beads excavated at the ruins of Hapgang-ri, Sejong, using the archeology and conservation approach. The period of appearance of Jugu Towangmyo in the ruins of Hapgang-ri can be estimated to begin in the late 2^nd century; for Jugu Towangmyo No. 15, the period spans from the late 2^nd to early 3^rd century. Form, color, and manufacturing techniques of complete glass beads were examined, and the cross-sections and chemical composition of 16 samples were observed. Based on these analyses, the glass beads were divided into blue, purple, and red colors. The blue-colored beads could be further sub-divided based on their gloss and brightness; in contrast, the red-colored beads were highly uniform with regard to these parameters. Based on the stripe and bubble arrangement on the surface of the glass beads, their drawing technique was identified. Traces of heat treatment or polishing were observed at the ends of the beads. According to their chemical composition, the 16 samples were classified into 3 potash glass and 13 soda glass groups; in the latter, the properties of the stabilizers were divided according to the blue and red bead colors. The stabilizers of the red beads are unique in that they allow the distinction among beads excavated in other areas in South Korea owing to their compositional differences. Colorants in blue- and red-colored beads are cobalt (containing MnO), and copper and iron, respectively.

• Transactions of the Korean Society of Mechanical Engineers
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• v.12 no.4
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• pp.825-832
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• 1988

An experiment was performed to study the heat pipe phenomenon of porous media heated above at one-dimensional steady state for the range of heat flux, 300 W/ $m^{2}$ ~ 2000w/ $m^{2}$. Glass beads, sand, and copper particles were used as porous media and distilled water was used as a working fluid. Result of experiment shows that the length of the two-phase zone increases with the decreasing particle size for the same heat flux. At relatively lower heat flux the length of the two-phase zone increases with the increasing heat flux, which contradicts the result of earlier work. However, its length remains nearly constant when the heat flux increases above a certain value. The length of the two-phase zone is proportional to the product of the heat flux by the hydrostatic capillary height under the limited value on heat flux, that is, $l_{t}$ = A(q. $l_{cap}$)+B, q.leg.1/A(C+B/ $l_{cap}$) where A is 1.7*10$^{-4}$ $m^{2}$/w, B is 1.9*10$^{-2}$ m, and C is 0.43 for copper particles and 0.31 for glass beads and sand.d.d.d.

• Carbon letters
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• v.11 no.2
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• pp.117-121
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• 2010

The composites of alginate, carbon nanotube, and iron(III) oxide were prepared for the removal of heavy metal in aqueous pollutant. Both alginate and carbon nanotube were used as an adsorbent material and iron oxide was introduced for the easy recovery after removal of heavy metal to eliminate the secondary pollution. The morphology of composites was investigated by FE-SEM showing the carbon nanotubes coated with alginate and the iron oxide dispersed in the alginate matrix. The ferromagnetic properties of composites were shown by including iron(III) oxide additive. The copper ion removal was investigated with ICP AES. The copper ion removal efficiency increased greatly over 60% by using alginate-carbon nanotube composites.

• Journal of Industrial and Engineering Chemistry
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• v.67
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• pp.448-460
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• 2018

Copper nanoparticle-doped and graphitic carbon nanofibers-covered porous carbon beads were used as an efficient catalyst for treating synthetic phenolic water by catalytic wet air oxidation (CWAO) in a packed bed reactor over 10-30 bar and $180-230^{\circ}C$, with air and water flowing co-currently. A mathematical model based on reaction kinetics assuming degradation in both heterogeneous and homogeneous phases was developed to predict reduction in chemical oxygen demand (COD) under a continuous operation with recycle. The catalyst and process also showed complete COD reduction (>99%) without leaching of Cu against a high COD (~120,000 mg/L) containing industrial wastewater.

• Fire Science and Engineering
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• v.22 no.5
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• pp.43-47
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• 2008

Recently SIMS has attracted interest as new technique to distinguish the primary and the secondary arc beads. A Cs+ primary ion beam was used to detect the $^{12}C^-$, $^{63}Cu^-$, $^{18}O^-$, $^{35}Cl^-$ secondary ions which are formed during depth profiles in the copper wires. In this work, we studied thermal diffusion in the copper wire which are occurred with supplying over-current. The results demonstrated that Carbon and Chloride are diffused in PVC-coated copper wire deeper than none PVC-coated. However Oxygen showed the reverse diffusion property.

• Journal of Advanced Marine Engineering and Technology
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• v.31 no.3
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• pp.243-251
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• 2007

This experiment was conducted to investigate the effect of particles on the heat transfer characteristics of fluids flowing in a cold water tube. Plastic beads with 3 different sizes were used as flowing particles with cold water. An experimental test section was composed of concentric double tubes having diameters of 25mm for the inner tube and 50mm for the outer tube. The materials for the inner and outer tubes are copper and PVC respectively. It was found that the particles enhanced the heat transfer coefficient by random and vortex motion in the fluid. Hence the heat transfer coefficients for the fluid with 2mm, 5mm and $2{\times}6mm$ particles were $7%{\sim}37%$ higher than the fluid without the particles.

• Fire Science and Engineering
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• v.32 no.6
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• pp.108-116
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• 2018

A melted bead microstructure can be divided into a deformed and undeformed layer. Measurement errors occur in the presence of a deformed layer, which should be removed through grinding/polishing whilst preserving the original structure. This paper proposes a grinding/polishing process to analyze the microstructure of copper melted beads. For the removal of the deformed layer, the correlation between the abrasive type/size, the polishing time and polishing rate was analyzed and the thickness of the deformed layer was less than $1{\mu}m$. The results suggest a new grinding/polishing procedure: silicon carbide abrasive $15{\mu}m$ (SiC P1200) 2 min, and $10{\mu}m$ (SiC P2400) 1 min; and diamond abrasive $6{\mu}m$ 8 min, $3{\mu}m$ 6 min, $1{\mu}m$ 10 min, and $0.25{\mu}m$ 8 min. In addition, a method of increasing the sharpness of the microstructure by chemical polishing with $0.04{\mu}m$ colloidal silica for 3 min at the final stage is also proposed. The overall grinding/polishing time is 38 min, which is shorter than that of the conventional procedure.

• Journal of the Korean Chemical Society
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• v.48 no.6
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• pp.590-598
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• 2004

The preconcentration and determination of trace Cu(II) and Pb(II) on calcium alginate beads in aqueous solution were studied. A calcium alginate beads were prepared by adding an alginic acid to sample solution contained Ca(II). Some following conditions were optimized: the pH of sample solution, amount of alginic acid, and stirring time for effective adsorption; the type and concentration of acid, and sonication time in an ultrasonic vibrator for the perfect de-sorption. A sample solution was prepared with Cu(II) and Pb(II) in DI water. And Ca(II) and ethanol was added into the sample solution. The pH of the final sample solution was controlled with buffer solution. The alginic acid were dispersed in the sample solution by a magnetic stirrer. This mixture was stored in room temperature for 30 min to form a calcium alginate. After the beads were filtered and washed on a membrane filter, the analytes were redissolved from the beads by an ultrasonic vibration of 10 minutes in 1.0M $HNO_3$ solution. The effect of diverse ions on the adsorption of analytes were studied. This procedure was applied for the analysis of two real samples. The recoveries in spiked samples were $90.4{\sim}104.3%$ for analytes.

• Journal of Conservation Science
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• v.7 no.1
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• pp.23-30
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• 1998

The examination of scientific analysis could give many information on the object of ancient glass. It would be allowed to understand the cultural situation and a course of inflow that the data of glass composition was classified by raw materials, technique of making, period and regional groups. Quantitative analysis conditions for SEM-EDS were set for glass and glaze on the pottery and 62 samples of glass beads excavated from Yangdong-ri remains at Kimhae were analyzed and classified. It was found that the glass beads were made of all alkali-glass. In addition, it was postulated that the potash glass was appeared from the 1st century A.D. and soda glass was appeared from the late second or early 3rd century A.D. in this region. The colors of glass were closely related to the concentration of metallic elements such as copper, iron and manganese. It was confirmed that the composition of glass beads could be classified and characterized by raw materials, color, period and regional groups.