• Title/Summary/Keyword: Copper/low k

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Experimental Characterization of Cyclic Deformation in Copper Using Ultrasonic Nonlinearity

  • Kim, C.S.;Park, Ik-Keun;Jhang, Kyung-Young;Kim, Noh-Yu
    • Journal of the Korean Society for Nondestructive Testing
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    • v.28 no.3
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    • pp.285-291
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    • 2008
  • We have experimentally investigated the cyclic deformation in copper using ultrasonic nonlinearity. The observation and characterization of dislocation substructure have been conducted using transmission electron microscope and electron backscattered diffraction technique. The ultrasonic nonlinearity (${\beta}/{\beta}_0$) was measured by the harmonic generation technique after various fatigue cycles. The microstructural effect on the nonlinearity was discussed regarding the extent of dislocation substructures evolved from low cycle fatigue. The ultrasonic nonlinearity of copper monotonically increased with the fatigue cycles due to the evolution of dislocation cell substructures.

Analysis and Optimization of Air-Core Permanent Magnet Linear Synchronous Motors with Overlapping Concentrated Windings for Ultra-precision Applications

  • Li, Liyi;Tang, Yongbin;Ma, Mingna;Pan, Donghua
    • Journal of international Conference on Electrical Machines and Systems
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    • v.2 no.1
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    • pp.16-22
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    • 2013
  • This paper presents the analysis and optimization of air-core permanent magnet linear synchronous motor with overlapping concentrated windings to achieve high thrust density, high thrust per copper losses and low thrust ripple. For the motor design, we adopt equivalent magnetizing current (EMC) method to analyze the magnetic field and give analytical formulae for calculation of motor parameters such as no-load back EMF, dynamic force, thrust density and thrust per copper losses. Further, we proposed a multi-objective optimization by genetic algorithm to search for the optimum parameters. The design optimization is verified by 2-D Finite Element analysis (FEA).

The survival rate, respiration and heavy metal accumulation of abalone (Haliotis discus hannai) rearing in the different copper alloy composition (동합금 조성에 따른 북방전복 (Haliotis discus hannai)의 생존, 호흡 및 중금속 축적률)

  • Shin, Yun-Kyung;Jun, Je-Cheon;Myeong, Jeong-In;Yang, Sung-Jin
    • The Korean Journal of Malacology
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    • v.30 no.4
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    • pp.353-361
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    • 2014
  • In order to investigate the effects of copper alloy on abalone physiology, we studied survival rate, respiration, excretion rate, and heavy metal accumulation in each organ of adults and spats. The survival rate of spats and adults showed 27-60% and 63-83% respectively, higher survival rate in adults. In particular, 100% of copper panel led to lowest survival rate and there was no sharp distinction according to copper alloy composition. The respiration rate and excretion rate of ammonia nitrogen was $1.81mgO_2/g$ D.W./h and 0.43 mg $NH_4-N/g$ D.W./h respectively at 100% of copper panel. In other words, there was a high significant difference at the level, but no significant difference at other test levels (P < 0.05). The atomic ratio (0: N) hit the lowest at the 100% of copper panel showing 3.79 and no significant differences were seen among other test groups with 6.57-7.18 of a very low range. This means that the species might have undergone nutritional stress. In case of copper accumulation, the 100% copper panel group showed the highest level in hepatopancreas and muscle showing 6.91 mg/kg and 1.60 mg/kg respectively but the rest of groups showed similar levels. Zinc accumulation raised at Cu-Zn alloy panel had high significance showing 18.50 mg/kg and 1.10 mg/kg in hepatopancreas and muscle respectively (P < 0.05). To sum up, a cage net made of 100% pure copper is expected to have a negative effect on abalone in light of survival rate, heavy metal accumulation, and atomic ratio (0: N). Moreover, given that the substratum used for the high adhesive species and nutritious stress that is represented through the atomic ratio need to be considered, the copper alloy net is thought not to be suitable for abalone aquaculture.

Effects of Selenium, Copper and Magnesium on Antioxidant Enzymes and Lipid Peroxidation in Bovine Fluorosis

  • Han, Bo;Yoon, Soonseek;Su, Jingliang;Han, H.R.;Wang, Mei;Qu, Weijie;Zhong, Daibin
    • Asian-Australasian Journal of Animal Sciences
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    • v.17 no.12
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    • pp.1695-1699
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    • 2004
  • The antioxidant enzymes, lipid peroxidation and free radicals assessment were made of the effects of selenium, copper and magnesium on bovine endemic fluorosis under high fluoride, low selenium and low copper productive conditions. Thirty-two beef cattle were selected from high fluoride area, and randomly divided into four groups with eight cattle each as follows: (1) high fluoride control group (HFC); (2) supplemented group with 0.25 mg/kg selenium (HFSe); (3) supplemented group with 15 mg/kg copper (HFCu) and (4) supplemented group with 0.25 mg/kg selenium+15 mg/kg copper+1 mg/kg magnesium (HFSeCuMg) per day for 83 days. Moreover, eight beef cattle were selected from non-high fluoride area as normal control group. Blood samples were collected from cattle on 0 d, 30 d and 83 d respectively, to analyze the enzyme activities and concentration of GSH-px, CAT, SOD, MDA and free radicals. The results showed that the contents of free radicals and MDA in HFC group were significantly higher, and the whole blood GSH-px, CAT, erythrocyte SOD activities were lower than the normal control group. Free radicals, metabolic imbalance and antioxidant disorder therefore, play an important role in fluorosis. However, GSH-px, CAT and SOD activities in HFSe group and HFSeCuMg group at 30 d and 83 d were markedly higher than the same groups at the 0 d and the HFC group at the same time. Likewise, there was a corresponding reduction in the contents of free radicals and MDA. These findings indicated that supplementation with selenium, copper and magnesium elevated high fluoride bovine antioxidant enzymes, and decreased MDA and free radicals contents. But, the activities of supplementation selenium group did not increase until day 83. These results demonstrated that fluorosis was associated with lower serum Se and Cu levels than in the control, and it was therefore concluded that fluorosis is associated with decreased serum levels of these minerals. Long-term high fluoride intake under productive condition enhances oxidative stress in the blood, thereby disturbing the antioxidant defense of cattle. Increased oxidative stress could be one of the mediating factors in the pathogenesis of toxic manifestations of fluoride. It is benefical for high fluoride cattle supplemented with proper selenium, copper and magnesium to increase fluoride excretion and obtain the protective impact of the activity of oxidative enzymes, and to decrease lipid peroxidation and free radicals contents.

Protective Activity of the Mixtures of Pine Oil and Copper Hydroxide against Bacterial Spot and Anthracnose on Red Pepper (파인 오일과 수산화동 혼합물에 의한 고추 세균점무늬병과 탄저병의 방제 효과)

  • Soh, Jae-Woo;Han, Kyung-Sook;Lee, Seong-Chan;Lee, Jung-Sup;Park, Jong-Han
    • Research in Plant Disease
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    • v.20 no.3
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    • pp.211-215
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    • 2014
  • This research was performed to examine the protective activities of the mixtures of pine oil and copper hydroxide against bacterial spot and anthracnose on pepper plants. As for bacterial spot, the treatment of pine oil alone displayed high disease incidence (59.6%) and low protective effect (28.9%). In comparison, the treatments of mixtures and copper hydroxide alone showed protective activities of 66.8-76.1%. The mixture of pine oil and copper hydroxide (4:1) suppressed the most effectively bacterial spot on pepper. On the other hand, the mixture of pine oil and copper hydroxide (4:1) also showed the strongest protective effect against pepper anthracnose among the 4 treatments tested; its disease incidence and disease control value were 49.8% and 41.7%, respectively. The other treatments showed low protective activities with control values of 7.4-17.1%. These results suggested that the mixture of pine oil and copper hydroxide (4:1) can be used for the environmental-friendly disease control of bacterial spot and anthracnose on pepper.

Effect of the compacting additives on the Discharge Characteristics of the Negative Electrode for Ni-MH Battery (니켈-수소저장합금전지 음극의 방전특성에 미치는 성형첨가제의 영향)

  • Jung, Jae-Han;Lee, Han-Ho;Kim, Dong-Myung;Lee, Kee-Young;Lee, Jai-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.6 no.2
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    • pp.65-73
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    • 1995
  • Negative electrode was prepared by mixing $Ti_{0.7}Zr_{0.3}Cr_{0.3}Mn_{0.3}V_{0.6}Ni_{0.8}$ alloy powder with copper or nickel powder and pressing in the air. The cycled electrodes were analyzed with SEM, potentiostat and electrochemical impedance spectroscopy. It was found that the Cu-compacted electrode showed better low temperature dischargeability and higher rate capability than Ni-compacted electrode. From SEM analysis of the cycled electrode compacted with copper powder, it was observed that the surface of MH particles was covered with copper grains and whisker precipitated from electrolyte after dissolution during cell test. It is found that the improved electrode characteristics are attributed to the copper layer on MH particles deposited by dissolution and precipitation(DP) process.

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Optical and Magnetic Properties of Copper Doped Zinc Oxide Nanofilms

  • Zhao, Shifeng;Bai, Yulong;Chen, Jieyu;Bai, Alima;Gao, Wei
    • Journal of Magnetics
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    • v.19 no.1
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    • pp.68-71
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    • 2014
  • Copper doped Zinc Oxide nanofilms were prepared using a simple and low cost wet chemical method. The microstructures, phase structure, Raman shift and optical absorption spectrum as well as magnetization were investigated for the nanofilms. Room temperature ferromagnetism has been observed for the nanofilms. Structural analyses indicated that the films possess wurtzite structure and there are no segregated clusters of impurity phase appreciating. The results show that the ferromagnetism in Copper doped Zinc Oxide nanofilms is driven either by a carrier or defect-mediated mechanism. The present work provides an evidence for the origin of ferromagnetism on Copper doped Zinc Oxide nanofilms.

Electrochemical Impedance Study for Selective Dissolution of a Cu-Zn Alloy

  • Hoshi, Y.;Tabei, K.;Shitanda, I.;Itagaki, M.
    • Corrosion Science and Technology
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    • v.15 no.6
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    • pp.311-313
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    • 2016
  • The anodic dissolution behavior of copper and brass in an electrolyte solution of 0.5M NaCl containing 0.5 mM $NaHCO_3$ was investigated by electrochemical impedance spectroscopy. The Nyquist plots of the copper impedance described a small loop in the high-frequency range and a large locus in the low-frequency range. Additionally, the features of the impedance spectrum of the brass were similar to those of the copper. This indicates that the copper-enriched layer formed on the brass surface due to the selective dissolution of the zinc from the surface. In addition, the rest potential and the anodic polarization curve for each sample were measured in order to discuss the selective dissolution of the zinc from the brass surface.

Effect of Carnosine and Related Compounds on Glucose Oxidation and Protein Glycation In Vitro

  • Lee, Beom-Jun;Park, Jae-Hak;Lee, Yong-Soon;Cho, Myung-Haing;Kim, Young-Chul;Hendricks, Deloy G.
    • BMB Reports
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    • v.32 no.4
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    • pp.370-378
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    • 1999
  • The effects of carnosine and related compounds (CRC) including anserine, homocarnosine, histidine, and ${\beta}$-alanine, found in most mammalian tissues, were investigated on in vitro glucose oxidation and glycation of human serum albumin (HSA). Carnosin and anserine were more reactive with D-glucose than with L-lysine. In the presence of $10\;{\mu}M$ Cu (II), although carnosine and anserine at low concentrations effectively inhibited formation of ${\alpha}$-ketoaldehyde from D-glucose, they increased generation of $H_2O_2$ in a dose-dependent manner. Carnosine, homocarnosine, anserine, and histidine effectively inhibited hydroxylation of salicylate and deoxyribose degradation in the presence of glucose and $10\;{\mu}M$ Cu (II). In the presence of 25 mM D-glucose, copper and ascorbic acid stimulated carbonyl formation from HSA. Except for ${\beta}$-alanine, CRC effectively inhibited the copper-catalyzed carbonyl formation from HSA. The addition of 25 mM D-glucose and/or $10\;{\mu}M$ Cu (II) to low density lipoprotein (LDL) increased formation of conjugated dienes. CRC effectively inhibited the glucose and/or copper-catalyzed LDL oxidation. CRC also inhibited glycation of HSA as determined by hydroxymethyl furfural and lysine with free ${\varepsilon}$-amino group. These results suggest that CRC may play an important role in protecting against diabetic complications by reacting with sugars, chelating copper, and scavenging free radicals.

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Effects of the Young Branch of Prunus persica Methanol Extracts and Solvent Fractions on ROS, RNS and Oxidized Low-Density Lipoprotein (도지(桃枝) 메탄올 추출물과 용매별 분획물이 활성산소종, 활성질소종 및 저밀도 지단백의 산화에 미치는 효과)

  • Moon, Jin Young;Park, Ju Yeon
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.27 no.2
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    • pp.189-195
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    • 2013
  • This study was designed to analyze the effects of methanol extracts and solvent fractions of the young branch of Prunus persica on scavenging activity of ROS, RNS and inhibiting activity of oxidative modification in human LDL induced by copper ion or free radical generator. The scavenging capacities of the fractions on DPPH radical, superoxide radical, nitric oxide and peroxynitrite were exhibited the highest in ethylacetate fraction, followed by butanol fraction. In the copper-induced LDL oxidative modification system, the highest antioxidant activity was revealed in ethylacetate fraction, and butanol fraction exhibited a similar activity. However, solvent fractions of the young branch of Prunus persica showed a relatively low antioxidant activity in the AAPH-mediated LDL oxidation. In addition, ethylacetate and butanol fractions also inhibited the copper-mediated LDL oxidation in the REM assay, which was comparable to that of the positive controls, including EDTA, ascorbic acid and BHT. Futhermore, a content of total phenolics in these two fractions was higher than that of the other fractions. These results indicated that ethylacetate and butanol fractions of the young branch of Prunus persica were useful for the prevention of the free radical- or metal ion-induced oxidative damages.