• Journal of The Korean Astronomical Society
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• v.31 no.2
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• pp.161-171
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• 1998

We have mapped about 1.5 square degree regions of Lynds 1299, a well isolated dark cloud in the Outer Galaxy (l = $122^{\circ}$, b = $-7^{\circ}$), in the J = 1- 0 transition of $^{12}CO$ and $^{13}CO$ with the 13.7 m radio telescope at Taeduk Radio Astronomy Observatory (TRAO). We found that there are two velocity components in the molecular emission, at $V_{LSR} = -52 km S^{-1}$ (Cloud A) and -8.8 km $s^{-1}$ (Cloud B), respectively. We have derived physical parameters of two molecular clouds and discussed three different mass estimate techniques. We found that there are large discrepancies between the virial and LTE mass estimates for both clouds. The large virial mass estimate reflects the fact that both are not gravitationally bound. We adopt the mass of $5.6 {\times}10^3 \;M{\bigodot}$ for Cloud A and $1.2{\times}10^3 \;M{\bigodot}$) for Cloud B using conversion factor. Cloud A is found to be associated with a localized star forming site, and its morphology is well matching with that of far-infrared (FIR) dust emission. It shows a clear ring structure with an obvious velocity gradient. We suggest that it may be a remnant cloud from a past episode of massive star formation. Cloud B is found to be unrelated to Cloud A (d = 800 pc) and has no specific velocity structure. The average dust color temperature of the uncontaminated portion of Cloud A is estimated to be 24$\~$27.4 K. The low dust temperature may imply that there is no additional internal heating source within the cloud. The heating of the cloud is probably dominated by the interstellar radiation field except the region directly associated with the new-born B5 star. Overall, the dust properties of Cloud A are similar to those of normal dark cloud even though it does have star forming activity.

• Journal of the Korean Applied Science and Technology
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• v.35 no.3
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• pp.757-767
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• 2018

In the propane dehydrogenation reaction proceeding at high temperature, the main cause of deactivation of the catalyst is coke deposition and sintering. In order to investigate the catalysts for reducing such inactivation, we have investigated the applicability of $MgAl_2O_4$ as a carrier for the catalytic dehydrogenation reaction. $MgAl_2O_4$ was prepared by Alcohthermal method at calcination temperature of 800, 900, $1000^{\circ}C$, and $Pt-Sn/MgAl_2O_4$ catalyst was prepared by supporting Pt and Sn by co-impregnation method. The reaction temperature was conducted at a high temperature of 650, $600^{\circ}C$ to confirm the thermal stability. As a result of the reaction experiment, it was confirmed that the conversion rate and yield of propane dehydrogenation reaction test were higher than that of the carrier-applied catalyst having a carrier calcination temperature of 900 and $1000^{\circ}C$, when the carrier-applied catalyst having a calcination temperature of $800^{\circ}C$ was used, It was found that the yield was higher than that of $Pt-Sn/{\theta}-Al_2O_3$ at $650^{\circ}C$. TGA, BET, XRD, CO-chemisorption, and SEM-EDS analyzes were performed for characterization. $MgAl_2O_4-800^{\circ}C$ was correlated with the relationship between good yield, Pt dispersion and low deactivation rate.

• Korean Chemical Engineering Research
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• v.50 no.2
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• pp.217-222
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• 2012

The synthesis of dimethyl carbonate(DMC) is a promising reaction for the use of naturally abundant carbon dioxide. DMC has gained considerable interest owing to its versatile chemical reactivity and unique properties such as high oxygen content, low toxicity, and excellent biodegradability. In this study, the synthesis of DMC through the transesterification of ethylene carbonate(EC) with methanol was investigated by using ionic liquid and metal oxide catalysts. The screening test of different catalysts revealed that choline hydroxide ([Choline][OH]) and 1-n-butyl-3-methyl imidazolium hydroxide([BMIm][OH]) had better catalytic performance than metal salts catalysts such as MgO, ZnO and CaO. The effects of reaction parameters such as reaction temperature, MeOH/EC mole ratio, and carbon dioxide pressure on the reactivity of [Choline][OH] catalyst were discussed. High temperature and high MeOH/EC mole ratio were favorable for high conversion of EC. However, the yield of DMC showed a maximum when carbon dioxide pressure was 1.34 MPa, and then it decreased for higher carbon dioxide pressure. Zinc chloride($ZnCl_2$) was used as co-catalyst with the ionic liquid catalyst. The mixed catalyst showed a synergy effect on the EC conversion and DMC yield probably due to the acid-base properties of the catalysts.

• Proceedings of the KSR Conference
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• 2010.06a
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• pp.739-744
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• 2010

As recent traffic policy focuses on reduction of congestion and environmental contamination, with a catch phrase, 'Green Traffic', Low Carbon Green Growth' and 'Sustainable Development', introducing the new eco-friendly transport means including railway has been emerging as critical issue. Included in the new transport means are BRT, Bimodal Tram and LRT, and this study was intended to evaluate and analyze Bimodal, among others, which generates less emission, noise and vibration thanks to hybrid type traction system employed by Bimodal Tram, which is considered a future-oriented system because of eco-friendly features and cost efficiency as well as punctuality and convenient accessibility to bus. Thus in this study, appropriateness of Bimodal Tram comparing to other system(BRT) was suggested, using conversion traffic from the road, traffic speed and CO2 emission at the metropolitan area and large provincial areas as the barometer in evaluation, and furthermore, the measures applicable to introduction strategy that will meet various functional aspects in urban area in the coming days were developed.

• Journal of the Korean Chemical Society
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• v.46 no.1
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• pp.57-63
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• 2002

The hydropurification reaction of CTA (crude terephthalic acid) was carried out with hydrogen over PdRu/CCM (carbon-carbonaceous composite material) catalyst in a batch reactor at high temperature. The first order kinetics of hydropurification is confirmed with the linear dependence of ln(4-CBA; 4-carboxybenzaldehyde) with reaction time. The reaction condition studied is thought to represent the hydropurification well because of the linear dependence of catalytic activity on the catalyst weight. The p-toluic acid (p-tol) in solid and liquid increases with the conversion of reaction or the decrease of 4-CBA. However, the benzoic acid (BA) concentration does not depend much on the conversion. The AT (alkali transmittance) does not depend on the 4-CBA when the concentration is higher than about 0.2% which shows the 4-CBA, in itself, does not cause the coloring effect. The AT of PTA depends inversely with the concentration of 4-CBA when the 4-CBA is less than about 0.15%. This may show the coloring materials are removed in parallel with the hydrogenation of 4-CBA. The (0.3%Pd-0.2%Ru)/CCM shows larger residual catalytic activity than a commercial catalyst, 0.5%Pd/C, after using in a commercial reactor even though the former has smaller fresh activity than the latter. The palladium and ruthenium in PdRu/CCM show the synergetic effect in activity when the ruthenium concentration is about $0.2{\sim}0.35$ wt%. It may be supposed that the PdRu/CCM catalyst can be a promising candidate to replace the commercial Pd/C catalyst.

• Korean Chemical Engineering Research
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• v.54 no.4
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• pp.501-509
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• 2016

The economic feasibility of a commercial indirect liquefaction process with the co-gasification process of petroleum coke which has been recognized as hazardous waste because of high sulfur content and bituminous coal and sub-bituminous coal mixtures was assessed. The 2,000 ton/day scale indirect liquefaction process including co-gasification, clean up, Fischer-Tropsch conversion and so on was assumed and used to analyze economical efficiencies with various conditions. Financial data from previous studies were modified and used and economical sensitivities with various mixture ratios were evaluated in this study. As a result, economic values of petroleum coke were superior than those of coals because of increasing sulfur sale. Also, mixtures with petroleum coke and bituminous coal was more favorable that those with petroleum coke and sub-bituminous coal due to lower moisture content. In case of sub-bituminous coal, the mixture ratio with petroleum coke had to be over 40wt% for the IRR of mixture to surpass 10%.

• Bulletin of the Korean Chemical Society
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• v.18 no.4
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• pp.402-405
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• 1997

Olefinic and cyclopropyl group substituted arenes (C6H5Y) react with [Cp*Ir(CH3COCH3)3]A2 (A=ClO4-, OTf-) to give η6-arene complexes, [Cp*Ir(η6-C6H5Y)]2+ (1a: Y=-CH=CH2 (a),-CH=CHCH3 (b),-C(CH3)=CH2 (c),-CH-CH2-CH2 (d)). Complex 1b-1d are readily converted into η3-allyl complexes, [Cp*(CH3CN)Ir(η3-CH(C6H5)CHCH2)]+ (2a) and [Cp*(CH3CN)Ir(η3-CH2(C6H5)CH2)]+ (2b), in the presence of Na2CO3 in CH3CN. The η6-styrene complex, 1a reacts with NaBH4 to give η5-cyclohexadienyl complex, [Cp*Ir(η5-C6H6-CH=CH2)]+ (3), while with H2 it gives η6-ethylbenzene complex [Cp*Ir(η6-C6H5CH2CH3)]2+ (4). Complex 1a and 1c react with HCl to give [Cp*Ir(η6-C6H5CH2CH2Cl)]2+ (5a) and [Cp*Ir(η6-C6H5CH(CH3)CH2Cl]2+ (5b), respectively.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.9
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• pp.1101-1105
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• 2014

Ocean Thermal Energy Conversion(OTEC) which uses the temperature difference between warm surface sea-water and cold deep sea-water to produce electric power is the promising technology. OTEC is able to be utilized as the $CO_2$ reducing technology by using the consistent temperature differential, while the system efficiency is very low. Thus, the design and development of a efficient turbine is essential to improve the system efficiency for OTEC. In this study, a 100kW-class radial inflow turbine using R32 was designed for OTEC and this turbine's performance was estimated by analysis of CFD. According as the simulation results, turbine's geometry was corrected. The radial inflow turbine satisfying the requirements is designed by the repeated attempts.

• Journal of Advanced Technology Convergence
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• v.2 no.3
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• pp.9-15
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• 2023

Recently, various public services are being performed based on information systems as the informatization business spreads. Public administration services based on these information systems provide internal and external services. In recent years, as the construction of cloud-based public services has been expanded, the advancement of information systems has attracted attention. In particular, as the dependence on information systems increases, the establishment of a response system to prevent dangerous situations such as interruption and paralysis of information systems in advance has become a hot topic not only in companies but also in public institutions. Therefore, in this paper, a disaster recovery system was designed and built to maximize the efficiency of system operation and shorten recovery time through service conversion automation of the disaster recovery system. The integrated DR server redundancy test, web server redundancy test, FC-IP redundancy test, and SAN switch redundancy test were performed respectively by applying the disaster recovery system designed and built according to the method proposed in the paper.

• Journal of Energy Engineering
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• v.19 no.3
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• pp.195-202
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• 2010

A third of primary energy is lost as a waste heat. To improve this inefficient use of energy, systems using chemical reaction have been suggested and studied. In this study, methanol decomposition/synthesis reaction as a chemical reaction was selected for long time heat storage and long distance heat transport system because of safe, cheap and gaseous product. The purpose of this study is to find the optimal conditions in the methanol decomposition and synthesis reactions for long distance heat transport. Several parameters such as reaction temperature, pressure, $H_2$/CO ratio, space velocity, catalyst particle size were tested to find the effects on the reaction rates for the methanol synthesis. And the reaction temperature, space velocity, catalyst particle size were tested to find the effects on the production concentration for the methanol decomposition.