• Journal of Adhesion and Interface
• /
• v.23 no.4
• /
• pp.130-136
• /
• 2022

Recently, organic semiconductor based indoor photovoltaics have gained attention since they exhibit excellent photovoltaic performance than that of conventional Si-based photovoltaics. In this study, we synthesize the medium bandgap polymer of PTBT and optimize PTBT:PC₇₁BM blend films by introducing solvent additives. To this end, we select DIO and CN solvent additives and vary their contents from 0 to 3 vol%. As a result, we produce the highest power conversion efficiency of 11.31% under LED 1000 lx conditions with DIO (1.5 vol%) + CN (0.5 vol%)

• Journal of Electrochemical Science and Technology
• /
• v.14 no.1
• /
• pp.96-104
• /
• 2023

Synergistically increased oxygen evolution reaction (OER) of manganese oxide (MnO₂) catalyst is introduced with surface-modified halloysite nanotube (Fe₃O₄-HNTs) structure. The flake shaped MnO₂ catalyst is attached on the nanotube template (Fe₃O₄-HNTs) by series of wet chemical and hydrothermal method. The strong interaction between MnO₂ and Fe₃O₄-HNTs maximized active surface area and inter-connectivity for festinate charge transfer reaction for OER. The synergistical effect between Fe₃O₄ layer and MnO₂ catalyst enhance the Mn³⁺/Mn⁴⁺ ratio by partial replacement of Mn ions with Fe. The relatively increased Mn³⁺/Mn⁴⁺ ratio on MnO₂@FHNTs induced 𝜎^* orbital (e_g) occupation close to single electron, improving the OER performances. The MnO₂@FHNTs catalyst exhibited the reduced overpotential of 0.42 V (E vs. RHE) at 10 mA/cm² and Tafel slope of (99 mV/dec), compared with that of MnO₂ with unmodified HNTs (0.65 V, 219 mV/dec) and pristine MnO₂ (0.53 V, 205 mV/dec). The present study provides simple and innovative method to fabricate nano fiberized OER catalyst for a broad application of energy conversion and storage systems.

• Journal of the Korean Institute of Gas
• /
• v.27 no.1
• /
• pp.78-85
• /
• 2023

Fixed-bed reactor Computational Fluid Dynamics (CFD) simulation of methanol steam reforming reaction was performed using the intrinsic kinetic data of the copper-impregnated hydrotalcite catalyst. The activation energy of the copper hydrotalcite catalyst obtained from the previous study results was 97.4 kJ/mol, and the pre-exponential was 5.904 × 10¹⁰. Process simulation was performed using the calculated values and showed a similar tendency to the experimental results. And the conversion rate according to the change of the reaction temperature (200 - 450 ℃) and the molar ratio of methanol and water was observed using the intrinsic kinetic data. In addition, mass and heat transfer phenomena analysis of a commercial reactor (I.D. 0.05 - 0.1m, Length 1m) was predicted through axial 2D Symmetry simulation using the power law model of the above kinetic constants.

• Journal of Fashion Business
• /
• v.27 no.2
• /
• pp.124-139
• /
• 2023

The purpose of this study is to determine the aesthetic identity of modern eroticism fashion in which the energy of desire is maximized through the 'jouissance' and 'gaze' of the unconscious theory of Jacques Lacan. The research method derived aesthetic identity after examining jouissance and gaze deeply related to eroticism in Lacan's theory of the unconscious by analyzing data of domestic and foreign monographs and prior research. Case analysis was limited to 2000 S/S to 2022 F/W. Based on prior research, it was analyzed mainly on clothing with eroticism characteristics of 'exposure, close contact, see-through, the conversion of underclothes into outer garments'. Results of the study are as follows. First, eroticism, which can be linked to Lacan's type of 'jouissance' with multiple meanings as the generating point of eroticism, has manifested itself in voyeuristic eroticism, fatale eroticism, masochistic eroticism, surplus eroticism, and sacred eroticism. Second, as eyes of unconscious desire, visual expression characteristics of 'gaze' appeared as anamorphosis, trompe l'oeil, and dépaysement. The identity of eroticism derived from Lacan's jouissance and the perspective of the desire gaze was divided into voyeuristic desire to gaze, fatal desire to gaze, masochistic desire to gaze, surplus desire to gaze, and sacred desire to gaze. Results of this study will expand theoretical horizons of eroticist fashion with a new interpretation of eroticism by combining Lacan's desire as a repressed and alienated subject within the human unconscious with the art that expands it.

• Current Photovoltaic Research
• /
• v.10 no.1
• /
• pp.16-22
• /
• 2022

The long-term stability of PSCs against visual and UV light, moisture, electrical bias and high temperature is an important issue for commercialization. In particular, since the operation temperature of solar cell can rise above 85℃, a study on thermal stability is required. In this study, the cause of thermal-induced degradation of PSCs was investigated using the SCAPS-1D simulation tool. First, PSCs of TiO₂/CH₃NH₃PbI₃/Spiro-OMeTAD/Au structure were exposed to a constant temperature of 85℃ to observe changes in conversion efficiency and quantum efficiency. Because the EQE reduction above 500 nm was remarkable, we simulated PSCs performance as a function of lifetime, doping density of perovskite and spiro-OMeTAD. Consequently, the main cause of thermal-induced degradation is considered to be the change in the perovskite doping concentration and lifetime due to ion migration of perovskite.

• Journal of Digestive Cancer Reports
• /
• v.7 no.1
• /
• pp.26-30
• /
• 2019

Pancreatic cancer has a very poor prognosis. Complete surgical resection remains the only current curative treatment. Locally advanced pancreatic cancer (LAPC) is considered as unresectable because of involvement of celiac and/or mesenteric vessels. The treatment of LAPC is a challenge. Current guidelines suggest systemic therapy. However, the majority of patients will never experience conversion to surgical resection. Thus, in these patients, ablation is an alternative therapy for local control, which causes local destruction while ideally avoiding injury to surrounding healthy tissue. Irreversible electroporation (IRE) is an energy delivery system, effective in ablating tumors by inducing irreversible membrane destruction of cells. IRE demonstrated to be safe in previous studies. However, it is not free from complications, even serious. Here, we reported two cases of the IRE in LAPC patients.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.31 no.2
• /
• pp.45-52
• /
• 2023

As of 2020, 139,753 tons/day of livestock manure is generated. Most of the livestock manure is made of compost(75.3%) and Liquor(11.7%) and is spread on farmland. The compost and Liquor of these livestock manure are the main causes of water pollution. Therefore, it is necessary to convert livestock manure into energy. For this reason, hydrothermal carbonization technology was applied to evaluate the physical and chemical properties. Among livestock manure, cow manure was used. Through hydrothermal carbonization, it was confirmed that the HHV (Kcal/kg) of 3,101 kcal/kg of raw material rises to more than about 3,800 kcal/kg at 220℃ or higher. This result was judged to be influenced by carbonization through a clear trend of decrease in O/C and H/C ratios. As a result, the value of Bio-SRF was evaluated through hydrothermal carbonization of cow manure, and All other items except for chlorine showed satisfactory results.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.31 no.2
• /
• pp.53-61
• /
• 2023

Most of the sewage sludge is organic waste containing a large amount of organic substances decomposable by microorganisms by biological treatment. As for existing sewage sludge treatment methods, reduction and fuel conversion are being carried out using technologies such as drying, incineration, torrefaction, carbonization. However, the disadvantage of high energy consumption has been pointed out as latent heat of 539 kcal/kg is consumed based on drying. Therefore, in this study, we intend to produce solid fuel through hydrothermal carbonization(HTC), which is a thermochemical treatment. To evaluate the value of solid fuel, the characteristics of carbonization and fuel ratio were analyzed. As a result, as the hydrothermal carbonization reaction temperature increased, the lower heating value also increased by about 500 kcal/kg due to the increase in the degree of carbonization. H/C, O/C, ratio showed a decreasing trend from 1.78, 0.46 to 1.57, 0.32. When the ratio of ash to combustible content (fixed carbon + volatile) of dry sludge was 0.25 or more, it was derived that the degree of carbonization and calorific value did not increase even when hydrothermal carbonization was performed.

• Korean Journal of Materials Research
• /
• v.33 no.7
• /
• pp.265-272
• /
• 2023

In this study, the synthesis of nitrobenzene was carried out using sulfated silica catalyst. The study delved into H₂SO₄/SiO₂ as a solid acid catalyst and the effect of its weight variation, as well as the use of a microwave batch reactor in the synthesis of nitrobenzene. SiO₂ was prepared using the sol-gel method from TEOS precursor. The formed gel was then refluxed with methanol and calcined at a temperature of 600 ℃. SiO₂ with a 200-mesh size was impregnated with 98 % H₂SO₄ by mixing for 1 h. The resulting 33 % (w/w) H₂SO₄/SiO₂ catalyst was separated by centrifugation, dried, and calcined at 600 ℃. The catalyst was then used as a solid acid catalyst in the synthesis of nitrobenzene. The weights of catalyst used were 0.5; 1; and 1.5 grams. The synthesis of nitrobenzene was carried out with a 1:3 ratio of benzene to nitric acid in a microwave batch reactor at 60 ℃ for 5 h. The resulting nitrobenzene liquid was analyzed using GC-MS to determine the selectivity of the catalyst. Likewise, the use of a microwave batch reactor was found to be appropriate and successful for the synthesis of nitrobenzene. The thermal energy produced by the microwave batch reactor was efficient enough to be used for the nitration reaction. Reactivity and selectivity tests demonstrated that 1 g of H₂SO₄/SiO₂ could generate an average benzene conversion of 40.33 %.

• Journal of IKEEE
• /
• v.27 no.4
• /
• pp.477-485
• /
• 2023

In this paper, the effect of AC ripple on the lifetime of lithium-ion batteries is experimentally analyzed. Bidirectional power conversion system(PCS) is used to increase the efficiency of energy storage systems (ESS). When connected to the grid, a current ripple with a frequency twice the grid frequency is applied to the battery due to its structure. Therefore, to analyze the effect of AC ripple on Li-ion battery aging, cycle life test are performed by applying charge/discharge profiles of DC current and DC+AC current ripple specifications. Based on the experimental results, direct current internal resistance (DCIR), incremental capacitance (IC), and surface temperature were analyzed. As a result, it is confirmed that AC ripple does not directly affect degradation and that battery degradation slows down after a certain cycle. These results can serve as a guideline for optimizing filters to reduce ripple on the battery side in applications where AC ripple occurs.