• Bulletin of the Korean Chemical Society
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• 제35권7호
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• pp.2081-2085
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• 2014

Second-order rate constants ($k_N$) have been measured spectrophotometrically for the reactions of phenyl 2- pyridyl carbonate (6) with a series of cyclic secondary amines in MeCN at $25.0{\pm}0.1^{\circ}C$. The Br${\o}$nsted-type plot for the reaction of 6 is linear with ${\beta}_{nuc}$ = 0.54, which is typical for reactions reported previously to proceed through a concerted mechanism. Substrate 6 is over $10^3$ times more reactive than 2-pyridyl benzoate (5), although the reactions of 6 and 5 proceed through the same mechanism. A combination of steric hindrance, inductive effect and resonance contribution is responsible for the kinetic results. The reactions of 6 and 5 proceed through a cyclic transition state (TS) in which H-bonding interactions increase the nucleofugality of the leaving group (i.e., 2-pyridiniumoxide). The enhanced nucleofugality forces the reactions of 6 and 5 to proceed through a concerted mechanism. In contrast, the corresponding reaction of 4-nitrophenyl 2-pyridyl carbonate (7) proceeds through a stepwise mechanism with quantitative liberation of 4-nitrophenoxide ion as the leaving group, indicating that replacement of the 4-nitrophenoxy group in 7 by the PhO group in 6 changes the reaction mechanism (i.e., from a stepwise mechanism to a concerted pathway) as well as the leaving group (i.e., from 4-nitrophenoxide to 2-pyridiniumoxide). The strong electron-withdrawing ability of the 4-nitrophenoxy group in 7 inhibits formation of a H-bonded cyclic TS. The presence or absence of a H-bonded cyclic TS governs the reaction mechanism (i.e., a concerted or stepwise mechanism) as well as the leaving group (i.e., 2-pyridiniumoxide or 4-nitrophenoxide).

• 대한방사선기술학회지:방사선기술과학
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• 제32권4호
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• pp.393-399
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• 2009

본 연구에서는 전리함을 이용하여 엑스선 촬영실 내에서 공간산란선량을 측정하고 산란선의 발생원과 조사 조건에 대한 산란율 의존성을 조사하였다. 아크릴 팬톰의 산란선 발생 인자를 조사하기 위해 관전압(40~140 kV)과 조사면($10{\times}10\;cm^2$, $20{\times}20\;cm^2$, $35{\times}35\;cm^2$)에 대한 산란율 변화를 측정하였다. 조사면이 $35{\times}35\;cm^2$일 때 측방산란율은 3.11~4.5%로 측정되었다. 촬영실 내에서 팬톰, 콜리메이터, 엑스선관, 벽면에서 발생하는 산란선량의 영향을 측정하였는데 전체 관전압에 대해 팬톰의 산란선 발생률은 95.4% 이상이었으며 콜리메이터, 엑스선관, 벽면의 산란선 발생률은 각각 2.6%, 1.3%, 0.7% 이하로 나타났다. 관전압 100 kV, 40 mAs 조사 조건에서 촬영실 내 팬톰으로부터 1 m 거리에서 측정한 공간선량은 최대 2 mR 정도로 나타나 조사조건의 최적화 등의 산란선 경감조치가 필요할 것으로 생각된다.

• 한국운동역학회지
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• 제17권4호
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• pp.27-36
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• 2007

The purpose of this study was to investigate the effect of the upper body in order to increase a propulsive force in the old's walking. The subjects were each 10 males, the latter term of the aged and former term of the aged. There were three walking speeds of slow(about 5km/h), medium(about 6km/h), and maximum speed(about 7km/h). The subjects walking 11m were filmed the 5m section (from 3m to 8m) by 2-video cameras using three dimensional cinematography. And we computed different mechanical quantities and especially computed the relative momentum in order to achieve this study's aim. In this study, we was able to acquire some knowledge. The step length and step frequency increased in proportion to the walking speed, and the faster walking speed, the shorter ratio of supporting time( both legs supporting time/one step length time). When it was one leg support phase, the torso was indicated to generate the momentum in order to produce the propulsive force of walking. The upper and lower body had a cooperative relation for walking such as keeping step rate with the arms to legs and maintaining the body balance. The opposition phase for upward-and-downward direction of the torso and arms in walking was functioned to prevent the increase rapidly toward vertical direction of the center of gravity. The arms had contributed to coordinate the tempo of legs and the posture maintenance of the upper body. And by absorbing the relative momentum from the upper torso with arms to the lower torso, it had the rhythmical movement on upward-and-downward direction reducing the vertical reaction force. On account of the relations of absorption and generation of the propulsive force and the production of vertical impulse in the lower torso when walking by maximum speed, it was showed that the function of lower torso was come up as important problem for the mechanical posture stability and propulsive force coordination.

• 한국산학기술학회논문지
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• 제7권5호
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• pp.930-934
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• 2006

홍제천 유역의 평창 배수분구를 대상으로 강우시 발생하수의 특성을 파악하기 위해 유량 및 수질 조사를 수행하였고, 강우유출수를 기저하수, 강우, 지붕유출수, 도로유출수, 관내 퇴적물 등 오염원별로 분석하여 기원별 초염기여도를 파악하였다. 강우시 발생초기의 오염물질의 농도는 초기세척현상에 의해 비강우시 농도의 3-10배 이상 높게 나타났으나, 강우 후반기에는 희석에 의해 비강우시 평균 농도 보다 오히려 낮은 농도를 보이는 것으로 나타났다. 오염부하의 오염원별 기여도 분석에서 관거 퇴적물에 의한 오염도가 전체 오염도에서 COD의 경우 54.6%를, SS은 73.3%를 차지하여, 가장 높은 기여도를 보여 관거 내 퇴적물의 준설과 세정을 통하여 상당량의 오염부하를 저감시킬 수 있는 것으로 나타났다.

• 한국물환경학회지
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• 제37권1호
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• pp.20-31
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• 2021

In this study, an analysis of the characteristics of organic matter and nitrogenous oxygen demand (NOD) of 17 sewage effluent and wastewater treatments was conducted. High CODMn and carbonaceous biological oxygen demand (CBOD) concentrations were observed in the livestock treatment plants (LTP), wastewater treatment plants(WTP), and night soil treatment plants (NTP), but the highest NOD concentration and contribution rates of NOD to BOD5 were found in sewage treatment plants (STP). There was no significant difference in the CBOD/CODMn ratio for each of the six pollution source groups, but the LTPs, WTPs, and NTPs all showed relatively high CODMn concentrations in their effluent samples, indicating that they are facilities which discharge large amounts of refractory organic matter. The seasonal change of NOD in all facilities' effluent was found to be larger than the seasonal change of CBOD, and data results also revealed an elevation of NOD and NH3-N concentration from December to February, when the water temperature was low. There was no significant difference in NH3-N concentration in relation to pollution source group (p=0.08, one-way ANOVA), but the STP, which had a high NOD contribution rate to BOD5 of 48%, showed a high correlation between BOD5 and NOD (r2=0.95, p<0.0001). These results suggest that the effect of NOD on BOD5 is an important factor to be considered when analyzing STP effluent.

• The Korean Journal of Pain
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• 제32권2호
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• pp.120-128
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• 2019

Background: We aimed to explore the American College of Rheumatology (ACR) 1990 and 2011 fibromyalgia (FM) classification criteria's items and the components of Fibromyalgia Impact Questionnaire (FIQ) to identify features best discriminating FM features. Finally, we developed a combined FM diagnostic (C-FM) model using the FM's key features. Methods: The means and frequency on tender points (TPs), ACR 2011 components and FIQ items were calculated in the FM and non-FM (osteoarthritis [OA] and non-OA) patients. Then, two-step multiple logistic regression analysis was performed to order these variables according to their maximal statistical contribution in predicting group membership. Partial correlations assessed their unique contribution, and two-group discriminant analysis provided a classification table. Using receiver operator characteristic analyses, we determined the sensitivity and specificity of the final model. Results: A total of 172 patients with FM, 75 with OA and 21 with periarthritis or regional pain syndromes were enrolled. Two steps multiple logistic regression analysis identified 8 key features of FM which accounted for 64.8% of variance associated with FM group membership: lateral epicondyle TP with variance percentages (36.9%), neck pain (14.5%), fatigue (4.7%), insomnia (3%), upper back pain (2.2%), shoulder pain (1.5%), gluteal TP (1.2%), and FIQ fatigue (0.9%). The C-FM model demonstrated a 91.4% correct classification rate, 91.9% for sensitivity and 91.7% for specificity. Conclusions: The C-FM model can accurately detect FM patients among other pain disorders. Re-inclusion of TPs along with saving of FM main symptoms in the C-FM model is a unique feature of this model.

• 한국콘텐츠학회논문지
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• 제19권9호
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• pp.212-220
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• 2019

본 연구는 정부의 금융지원 정책인 영상전문투자조합이 한국영화 제작자본 조달에 기여한 정도를 평가하였다. 영상전문투자조합 정책은 1999년 중소기업청과 2000년 영화진흥위원회의 출자로 시작되었고, 이후 한국영화 제작비뿐만 아니라 문화산업 분야의 창업 초기기업과 프로젝트의 중요한 자본조달 구조로 발전하였다. 하지만 한국 영화산업의 관점에서 영상전문투자조합의 정책성과를 평가할 수 있는 기초자료가 기관별, 시기별로 산개해 있어서 일관적인 지표를 산출하기 어려웠다. 이에 본 연구는 해당 기관들의 자료를 재구성하여 1999~2017년까지 공적 출자를 통해 결성된 영상전문투자조합의 신규 결성규모, 공공 출자비율, 한국영화 투자편수 및 투자금액, 공공 출자금 및 결성액 대비 투자승수, 청산조합 수익률 등의 지표를 산출하였다. 이를 통해 영상전문투자조합 정책이 한국 영화산업의 성장에 기여한 성과를 평가할 수 있는 기초적인 토대를 제공하고자 한다.

• 한국IT서비스학회지
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• 제19권6호
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• pp.131-144
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• 2020

As the blockchain technology attracts attention, interest in cryptocurrency that is received as a reward is also increasing. Currently, investments and transactions are continuing with the expectation and increasing value of cryptocurrency. Accordingly, prediction for cryptocurrency price has been attempted through artificial intelligence technology and social sentiment analysis. The purpose of this paper is to develop a deep learning ensemble model for predicting the price fluctuations and one-day lag price of cryptocurrency based on the design science research method. This paper intends to perform predictive modeling on Ethereum among cryptocurrencies to make predictions more efficiently and accurately than existing models. Therefore, it collects data for five years related to Ethereum price and performs pre-processing through customized functions. In the model development stage, four LSTM models, which are efficient for time series data processing, are utilized to build an ensemble model with the optimal combination of hyperparameters found in the experimental process. Then, based on the performance evaluation scale, the superiority of the model is evaluated through comparison with other deep learning models. The results of this paper have a practical contribution that can be used as a model that shows high performance and predictive rate for cryptocurrency price prediction and price fluctuations. Besides, it shows academic contribution in that it improves the quality of research by following scientific design research procedures that solve scientific problems and create and evaluate new and innovative products in the field of information systems.

• 한국환경보건학회지
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• 제48권2호
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• pp.123-129
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• 2022

Background: The Environmental Health Action Program was a national project carried out from 2012~2021. It was aimed at developing public technologies to protect people's health from various environmental hazards. Objectives: One of the final goals of the project was "creating health benefits worth more than 179.2 billion won by reducing the environmental burden of disease." This study aims to evaluate whether the program sufficiently achieved the planned benefits. Methods: In order to secure consistency in evaluation, we applied the same equation used in the goal-setting process. It is comprised of six parameters to estimate the benefit: 1. The amount of medical expenses for environmental diseases; 2. The attributable proportion of environmental risk factors' 3. The rate of reduction in medical expenses for environmental diseases; 4. R&D project contribution; 5. The proportion of successful policy reflection; and 6. The contributions of the project. The corresponding variables were estimated at the end of the project, and the health benefits of the project were recalculated using the newly estimated variables. Results: It was estimated that a total of 195 billion won in health benefits occurred or will occur from 2015 to 2026. The main contributors for achieving the target were an increase in medical expenses for environmental diseases, a high score in the R&D project contribution, and the proportion of successful policy reflection. Conclusions: Technically, the equation used in the project is about medical expenses for environmental diseases rather than about the environmental burden of disease. There are several benefits of using the environmental burden of disease in the evaluation of public health policies. In further studies, developing a policy evaluation framework using indicators such as population attributable fraction would be needed.

• 한국프랜차이즈경영연구
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• 제7권2호
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• pp.27-35
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• 2016

Purpose - The primary objective of this study is to investigate the impact of employee characteristics on employees' preference towards corporate pension products. This study can provide a guidance for maximization of benefits for employees and their affiliated corporation. Employee characteristics include average length of labour, wage system of annual salary, age, types of interest rates and size of corporation. Existing research generally concentrate on vitalizations of corporate pension product raising an imperfection, improvements, tax benefit analysis and legal consideration. Thus, this study intensively analyses the effect of employee attributes on firms' decision for corporate pension products, such as DB(defined benefit) and DC(defined contribution) type. Research design, data, and methodology - The data were collected using self-administrated questionnaire survey on corporate pension products from CEOs or HR directors 250 foreign-invested companies', purchasing pension plans in practice with domestic financial trustees (insurance companies, banks and security companies). Hypotheses testing was conducted using Logistic Regression analysis with SPSS/PC+ 21.0. Results - The findings of the study are as follows. Employees with the long length of labour are more likely to have DB plan; more likely to prefer DC plan with the dividend distribution product regarding the types of interest rate. SMEs(less than 100 employees) are more likely to select DC plan whereas high fluctuation in wage with annual salary has no impacts. In addition, the ages has no significant effect on the preference. Conclusions - This study has examined with the empirical testing that employees' variable attributes and qualities are one of the vital factors for corporation pension plan selection. Currently, majority employees are highly likely to join DB plan and Defined interest types. Corporation with less than 10 employees prefer IRP scheme while most of corporation are intended to join DC plan. In a very near future, corporation more than 300 employees will be required to purchase mandatory plan under national regulation. For maximization of employees' contentment to corporation pension insurance and for complementing the flaws of existing plans, the future studies shall also research in a perspective of employee benefit.