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Mechanical Characteristics of Crystalline Carbon Nitride Films Grown by Reactive Sputtering (반응성 스퍼터링으로 성장된 결정성 질화탄소막의 기계적 특성)

  • 이성필;강종봉
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.2
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    • pp.147-152
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    • 2002
  • Carbon nitride thin films were deposited by reactive sputtering for the hard coating materials on Si wafer and tool steels. When the nitrogen content of carbon nitride film on tool steel is 33.4%, the mean hardness and elastic modulus are 49.34 GPa and 307.2 GPa respectively. The nitrided or carburised surface acts as the diffusion barrier which shows better adhesion of carbon nitride thin film on the steel surface. To prevent nitrogen diffusion from the film, steel substrate can be saturated by nitrogen forming a Fe$_3$N layer. The desirable structure at the surface after carburising is martensite, but sometimes, due to high carbon content an proeutectoid Fe$_3$C structure may form at the grain boundaries, leaving the overall surface brittle and may cause defects.

The Magnetic Characteristics of Co-Cr Thin Films Deposited by Facing Targets Sputtering (대향타겟식 스퍼터로 제작된 Co-Cr 박막의 자기적 특성)

  • Kim, K.H.;Son, I.H.;Kim, M.H.;Kim, J.H.;Nakagawa, S.;Naoe, M.
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1320-1322
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    • 1997
  • The distribution of coercivity in the thickness direction were investigated by using Kerr hysteresis loop tracer for the Co-Cr films deposited by Facing Targets Sputtering apparatus. It $H_{c{\bot}}(S)- H_{c{\bot}}(I)$ correlated strongly with ${\Delta}H_c$, which represents the degree of distribution of coercivity. Furthermore, the Cr content was varied in order to improve the coercivity of intial growth layer $H_{c{\bot}}(I)$ took a maximum value of 750 Oe and the distribution of coercivity became sharper at the Cr content of 25 at.%.

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The Preparation of Non-aqueous Supercapacitors with Lithium Transition-Metal Oxide/Activated Carbon Composite Positive Electrodes

  • Kim, Kyoung-Ho;Kim, Min-Soo;Yeu, Tae-Whan
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3183-3189
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    • 2010
  • In order to increase the specific capacitance and energy density of supercapacitors, non-aqueous supercapacitors were prepared using lithium transition-metal oxides and activated carbons as active materials. The electrochemical properties were analyzed in terms of the content of lithium transition-metal oxides. The results of cyclic voltammetry and AC-impedance analyses showed that the pseudocapacitance may stem from the synergistic contributions of capacitive and faradic effects; the former is due to the electric double layer which is prepared in the interface of activated carbon and organic electrolyte, and the latter is due to the intercalation of lithium ($Li^+$) ions. The specific capacitance and energy density of a supercapacitor improved as the lithium transition-metal oxides content increased, showing 60% increase compared to those of supercapacitor using a pure activated carbon positive electrode.

Insulation Coating for non-oriented Silicon Steel Sheerts (무방향성 전기강판의 절연피막 코팅재)

  • 조남웅;장세기
    • Journal of Surface Science and Engineering
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    • v.30 no.6
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    • pp.382-390
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    • 1997
  • Good appearance of insulation coating is required for non-oriented silicon steel sheets, The property is influenced by both the chemical composition of coating solution and the species of resin. The composition of inorganic-organic coating was studied to obtain good surface quality for non-oriented silicon steel. The greenish degree of coating surface depended on $Cr^{3+}$ content in the coating layer, which was satisfied when chromate content was more than 54.60 wt. %, in the coating solution. The homogeneous pattern and roughness of the coating surface depended on spreading property of the resin. Surface appearance of the coating could be improved by using resin with good spreading property at the chemical composition of chromate 59.00 wt.%.. resin 34.23wt.%, and etyhylene glycol 6.67 wt.% without colloidal sillica.

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Studies on the Germanium Components of Zingiberis Rhizoma (생강중 게르마늄 성분에 관한 연구)

  • 백남호;박만기;최승호;문동철
    • YAKHAK HOEJI
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    • v.25 no.4
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    • pp.193-197
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    • 1981
  • Germanium (Ge) content in Zingiberis Rhizoma was determined by flameless atomic absorption spectrometry with a graphite tube atomizer. The Ge content of the cortical layer was 65.mu.g/g, the central cylinder, $98\mu$g/g and the total, $87\mu$g/g. In the effect of the extraction of Ge by various solvents, polar solvent was more effective than the nonpolar one, Especially, water was the most effective solvent. The water extract of Zingiberis Rhizoma, separated by sephadex G-25 gel filtration, was fractionated into 2 peaks at 254nm. Both the peaks showed atomic absorptions of Ge. It may be concluded that the Ge components of Zingiberis Rbizoma exist as the form of an aqueous organic compounds or associated forms with proteins.

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Effects of Plasma Nitriding on the Surface Charcteristice Of Stainless Steels (스테인스강의 표면특성에 미치는 플라즈마질화의 영향)

  • 최한철;김관휴
    • Journal of Surface Science and Engineering
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    • v.30 no.2
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    • pp.144-154
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    • 1997
  • Effects of plasma nitriding on the surface charcteristice of stainless steel(SS) were investjgated by utilizing wear tester, micro-hardness tester and potentiostat. The surface and corrosion morphology of plasma nitrided SS were analyzed by utilizing optical microscopy, SEM, XRD and WDX. It was found that plasma nitriding at $550^{\circ}C$, compared with $380^{\circ}C$, prodiced a good wear resistance and hardness as nitriding time increased, whereas Mo addition showd that were resistance and hardness decreased. Intergranular corrosion(IGC) resistance improved significantly in the case of plasma nirtrided SS containing 4.05wt% Mo at $380^{\circ}C$ because that nitrogen and Mo ast syner gidically to form a protective layer on surface which is responsible for the aggresive SCN-ion. Plasma nitrided at $550^{\circ}C$ decreased IGC as Mo content increased. Pitting improved in the plasma nitirided SS at Mo content incresased owing to retard a nucleation and growth of chromium carbide or nitirde in grain boundary.

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An Effective WSSENet-Based Similarity Retrieval Method of Large Lung CT Image Databases

  • Zhuang, Yi;Chen, Shuai;Jiang, Nan;Hu, Hua
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.16 no.7
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    • pp.2359-2376
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    • 2022
  • With the exponential growth of medical image big data represented by high-resolution CT images(CTI), the high-resolution CTI data is of great importance for clinical research and diagnosis. The paper takes lung CTI as an example to study. Retrieving answer CTIs similar to the input one from the large-scale lung CTI database can effectively assist physicians to diagnose. Compared with the conventional content-based image retrieval(CBIR) methods, the CBIR for lung CTIs demands higher retrieval accuracy in both the contour shape and the internal details of the organ. In traditional supervised deep learning networks, the learning of the network relies on the labeling of CTIs which is a very time-consuming task. To address this issue, the paper proposes a Weakly Supervised Similarity Evaluation Network (WSSENet) for efficiently support similarity analysis of lung CTIs. We conducted extensive experiments to verify the effectiveness of the WSSENet based on which the CBIR is performed.

Dynamic/static stability characteristics of sandwich FG porous beams

  • Weijia Yu;Linyun Zhou
    • Steel and Composite Structures
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    • v.46 no.2
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    • pp.203-210
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    • 2023
  • In the present research, dynamic deflections of a sandwich beam having functionally graded (FG) porous core have been investigated assuming that the sandwich beam is exposed to a pulse load of blast type. The two layers of sandwich beam have been made of a polymeric matrix reinforced by graphene oxide powder (GOP). The micromechanical formulation of the layers has been done via Halpin-Tsai model. The solution method is chosen to be Ritz method which is an efficient method to solve the system of equations of beams modeled based on a higher-order theory. To derive the time history of sandwich beam under pulse load, Laplace method has been used. The porosity content of the core, the GOP content of the layers, thickness of the layer and also duration of the applied load have great influences of the responses of sandwich beam.

Properties of TiN Thin Films Deposited by ALD Using TDMAT Precursor in Low-Temperature Processes

  • Kyu-Min Park;Gyu-Jin Mun;Ji-Hun Cho;Si-Woo Lee;Gyeong-Jin Min;Sang-Jeen Hong
    • Journal of the Semiconductor & Display Technology
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    • v.23 no.3
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    • pp.14-20
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    • 2024
  • In this study, TiN thin films, used as electrode thin films, were deposited through the Thermal Atomic Layer Deposition method using TDMAT (Tetrakis(dimethylamido)titanium) as the precursor and NH3 as the reactant. After deposition at various temperatures, the thickness, crystal structure, surface roughness, impurity content, and resistivity of the films were compared. The results showed that the optimal process temperature was 200℃, forming TiO2 anatase and TiN(200) crystal structures. The surface roughness was the lowest, with Ra=0.393nm and Rq=0.502nm, and the impurity content was 27.5% O and 6.35% C, with the resistivity also recording its minimum value. Particularly, at a long pulsed time of 11 seconds, the impurity inclusion due to self-decomposition reactions was dominant, showing excellent properties at lower temperature.

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Immobilization of Burkholderia cepacia Lipase on Weak Base Styrene Resin Using Polyethyleneimine with Cross-linking (PEI(Polyethyleneimine)를 이용하여 음이온계 레진에 고정화된 Lipase AH 제조 및 효소적 Interesterification을 통한 반응 특성 연구)

  • Lee, Chi Woo;Lee, Ki Teak
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.43 no.7
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    • pp.1025-1035
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    • 2014
  • This study assessed the effect of immobilized lipase on weak base styrene resin using polyethyleneimine (PEI) with cross-linking. Two procedures were used in this study. The first one, "mono-layer" lipase immobilization, involves washing PEI after adsorption. The second procedure, "multi-layer" lipase immobilization, has no washing before the cross-linking step. Treverlite XS-100200 (weak base styrene resin) was immersed with PEI solution (2.2 mg/mL). Lipase AH (from Burkholderia cepacia) was adsorbed onto the support coated with PEI before cross-linking with glutaraldehyde. Structured lipid was synthesized by immobilized lipase-catalyzed interesterification using canola oil, palmitic ethyl ester (PEE), and stearic ethyl ester (StEE). Total fatty acid contents of triacylglycerol (TAG) in structured lipids were analyzed to investigate activity, properties, and reusability of immobilized lipases. Activities of immobilized lipases on the multi-layer and mono-layer increased at a high concentration (8 mg/mL) of lipase solution used for immobilization. The results show that immobilized lipase with the mono-layer method at pH 8.0 on resin had the highest total saturated fatty acid content (26.17 area%). Activity of immobilized lipase with the multi-layer method at pH 7.5 on support was lower than that of the mono-layer, but total saturated fatty acid content was 16.79 area% higher than that of lipase AH (15.01 area%).