• Title/Summary/Keyword: Contaminant concentration

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Reliability Analysis to Contaminant Migration in Saturated Sandy Soils: Implementation and Verification (포화(飽和)된 사질토(砂質土) 내로의 오염물(汚染物) 이동에 관한 신뢰성(信賴性): 수행(遂行) 및 검증(檢證))

  • Jang, Yeon Soo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.12 no.2
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    • pp.217-227
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    • 1992
  • The first and second-order reliability method(FORM and SORM) is presented using one dimensional finite difference and two dimensional finite element transport models. FORM and SORM can be used without any restrictive assumptions about the properties of the media, and the sensitivity information obtained as part of these analyses is used to identify the parameters which have major influence on the estimate of probability. The reliability analysis of transport in a one-dimensional domain is used to test the robustness of the reliability code and to evaluate the accuracy of the reliability method. A continuous source 2-D example with a concentration threshold limit state function is used to evaluate the influence of the parameters in the location of interest on the reliability solution.

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The Analytical Derivation of the Fractal Advection-Diffusion Equation for Modeling Solute Transport in Rivers (하천 오염물질의 모의를 위한 프랙탈 이송확산방정식의 해석적 유도)

  • Kim, Sang-Dan;Song, Mee-Young
    • Journal of Korea Water Resources Association
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    • v.37 no.11
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    • pp.889-896
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    • 2004
  • The fractal advection-diffusion equation (ADE) is a generalization of the classical AdE in which the second-order derivative is replaced with a fractal order derivative. While the fractal ADE have been analyzed with a stochastic process In the Fourier and Laplace space so far, in this study a fractal ADE for describing solute transport in rivers is derived with a finite difference scheme in the real space. This derivation with a finite difference scheme gives the hint how the fractal derivative order and fractal diffusion coefficient can be estimated physically In contrast to the classical ADE, the fractal ADE is expected to be able to provide solutions that resemble the highly skewed and heavy-tailed time-concentration distribution curves of contaminant plumes observed in rivers.

Hexavalent Chromium Reduction by Bacteria from Tannery Effluent

  • Batool, Rida;Yrjala, Kim;Hasnain, Shahida
    • Journal of Microbiology and Biotechnology
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    • v.22 no.4
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    • pp.547-554
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    • 2012
  • Chromium is generated from several industrial processes. It occurs in different oxidation states, but Cr(III) and Cr(VI) are the most common ones. Cr(VI) is a toxic, soluble environmental contaminant. Some bacteria are able to reduce hexavalent chromium to the insoluble and less toxic Cr(III), and thus chromate bioremediation is of considerable interest. An indigenous chromium-reducing bacterial strain, Rb-2, isolated from a tannery water sample, was identified as Ochrobactrum intermedium, on the basis of 16S rRNA gene sequencing. The influence of factors like temperature of incubation, initial concentration of Cr, mobility of bacteria, and different carbon sources were studied to test the ability of the bacterium to reduce Cr(VI) under variable environmental conditions. The ability of the bacterial strain to reduce hexavalent chromium in artificial and industrial sewage water was evaluated. It was observed that the mechanism of resistance to metal was not due to the change in the permeability barrier of the cell membrane, and the enzyme activity was found to be inductive. Intracellular reduction of Cr(VI) was proven by reductase assay using cell-free extract. Scanning electron microscopy revealed chromium precipitates on bacterial cell surfaces, and transmission electron microscopy showed the outer as well as inner distribution of Cr(VI). This bacterial strain can be useful for Cr(VI) detoxification under a wide range of environmental conditions.

Numerical modeling of two-dimensional simulation of groundwater protection from lead using different sorbents in permeable barriers

  • Masood, Zehraa B.;Ali, Ziad Tark Abd
    • Environmental Engineering Research
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    • v.25 no.4
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    • pp.605-613
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    • 2020
  • This study is to investigate the possibility of using activated carbon prepared from Iraqi date-pits (ADP) which are produced from palm trees (Phoenix dactylifera L.) as low-cost reactive material in the permeable reactive barrier (PRB) for treating lead (Pb+2) from the contaminated groundwater, and then compare the results experimentally with other common reactive materials such as commercial activated carbon (CAC), zeolite pellets (ZP). Factors influencing sorption such as contact time, initial pH of the solution, sorbent dosage, agitation speed, and initial lead concentration has been studied. Two isotherm models were used for the description of sorption data (Langmuir and Freundlich). The maximum lead sorption capacities were measured for ADP, CAC, and ZP and were found to be 24.5, 12.125, and 4.45 mg/g, respectively. The kinetic data were analyzed using various kinetic models particularly pseudo-first-order, pseudo-second-order, and intraparticle diffusion. COMSOL Multiphysics 3.5a depend on finite element procedure was applied to formulate transmit of lead (Pb+2) in the two-dimensional numerical (2D) model under an equilibrium condition. The numerical solution shows that the contaminant plume is hindered by PRB.

대기압의 변화에 따른 휘발성 오염물질의 토양에서 대기로의 거동

  • Choi Ji-Won;Smith James A.;Hwang Gyeong-Yeop
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.114-116
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    • 2005
  • Natural attenuation has been actively studied and often selected as final clean-up process in remediation of contaminated ground-water and soil for the last decade. Accordingly, understanding of natural processes affecting the fate and transport of contaminants in the subsurface becomes important for a success of implementation of the natural remediation strategy, Contaminant advection and diffusion processes in the unsaturated zone are naturally related to environmental changes in the atmosphere. The atmospheric pressure changes affecting the transport of contaminants in the subsurface are investigated in this study. Moisture content, trichloroethylene (TCE) concentration, temperature, and pressure variations in the subsurface were measured for the July, August, November, and December 2001 at Picatinny Arsenal, New Jersey. These data were used for a one-phase flow and one-component transport model in simulating the soil-gas flow and accordingly the TCE transport in the subsurface in accordance with the atmosphere pressure variations at the surface. The soil-gas velocities during the sampling periods varied with a magnitude of $10^{-6}\;to\;10^{-7}\;m\;s^{-1}$ at land surface. The TCE advection fluxes at land surface were several orders of magnitude smaller than the TCE diffusion fluxes. A sensitivy analysis indicated that advection fluxes were more sensitive to changes in geo-environmental conditions compared to diffusion fluxes. Of all the parameters investigated in this study, moisture content has the most significant effect on TCE advection and diffusion fluxes.

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Characteristic of PVA-PMAA on the Fixation of Radioactively Contaminated Sand as a Result of a Nuclear Accident (PVA-PMAA에 의한 헥사고 오염모래의 고정화 특성)

  • Won, He-Jun;Ahn, Byung-Kil;Oh, Won-Jun
    • Nuclear Engineering and Technology
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    • v.27 no.1
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    • pp.18-24
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    • 1995
  • Characteristics of poly(vinyl alcohol)-poly(methacrylic acid) system (PVA.-PMAA system) for fixation of radioactive contaminant on sand were studied. Dissociation of carboxyl group in PMAA was found to be suppressed by PVA Permeability of sand layer treated with PVA-PMAA solution is directly proportional to the PMAA concentration when the [PMAA] is below 0.082 M and the empirical proportional constant (k) is -8.95$\times$10 ̄$^4$cm$^{5}$ /mole. The change of permeability can be explained by the formation of an intermacromolecular complex between PVA and PMAA The polymer bridge formed on a sand surface combines sand yams more firmly. The PVA-PMAA system is more effective than the PVA system for the fixation of deposited condensational radionuclides.

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On-line Identification of The Toxicological Substance in The Water System using Neural Network Technique (조류를 이용한 수계모니터링 시스템에서 뉴럴 네트워크에 의한 실시간 독성물질 판단)

  • Jung, Jonghyuk;Jung, Hakyu;Kwon, Wontae
    • Journal of Korean Society on Water Environment
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    • v.24 no.1
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    • pp.1-6
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    • 2008
  • Biological and chemical sensors are the two most frequently used sensors to monitor the water resource. Chemical sensor is very accurate to pick up the types and to measure the concentration of the chemical substance. Drawback is that it works for just one type of chemical substance. Therefore a lot of expensive monitoring system needs to be installed to determine the safeness of the water, which costs too much expense. Biological sensor, on the contrary, can judge the degree of pollution of the water with just one monitoring system. However, it is not easy to figure out the type of contaminant with a biological sensor. In this study, an endeavor is made to identify the toxicant in the water using the shape of the chlorophyll fluorescence induction curve (FIC) from a biological monitoring system. Wem-tox values are calculated from the amount of flourescence of contaminated and reference water. Curve fitting is executed to find the representative curve of the raw data of Wem-tox values. Then the curves are digitalized at the same interval to train the neural network model. Taguchi method is used to optimize the neural network model parameters. The optimized model shows a good capacity to figure out the toxicant from FIC.

A Study on the Concentration Variations of VOCs and Formaldehyde on the Type of Interior Materials of New Vehicles by Simulation Program (시뮬레이션 프로그램을 이용한 신규 차량의 인테리어 물질에 따른 VOC와 폼알데히드의 농도 변화에 관한 연구)

  • Yi, Young-Seop;Kim, In-Bum;Ko, Won-Kyoung
    • Journal of the Korean Society of Safety
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    • v.27 no.3
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    • pp.89-95
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    • 2012
  • The concentrations of Volatile Organic Compounds(VOCs) and Formaldehyde(HCHO) for interior materials of new vehicles are estimated and recognized by using the simulation program known as IAQx. The concentrations of contaminants are estimated and evaluated by the ventilation rates of new domestic vehicles and the required ventilation rates for new vehicles are estimated through the given contaminant data. This study is conducted to compare the ventilation rates for the contaminants between the discontinuously ventilated new vehicles and the continuously ventilated new vehicles using the simulation program. The equation of ventilation rate of new vehicles is acquired to be able to lower initial concentrations below the standard level under different conditions for both business and personal commuting.

Photocatalytic degradation of textile dye CI Basic Yellow 28 wastewater by Degussa P25 based TiO2

  • Konecoglu, Gulhan;Safak, Toygun;Kalpakli, Yasemen;Akgun, Mesut
    • Advances in environmental research
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    • v.4 no.1
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    • pp.25-38
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    • 2015
  • Wastewaters of textile industry cause high volume colour and harmful substance pollutions. Photocatalytic degradation is a method which gives opportunity of reduction of organic pollutants such as dye containing wastewaters. In this study, photocatalytic degradation of C.I. Basic Yellow 28 (BY28) as a model dye contaminant was carried out using Degussa P25 in a photocatalytic reactor. The experiments were followed out at three different azo dye concentrations in a reactor equipped UV-A lamp (365 nm) as a light source. Azo dye removal efficiencies were examined with total organic carbon and UV-vis measurements. As a result of experiments, maximum degradation efficiency was obtained as 100% at BY28 concentration of $50mgL^{-1}$ for the reaction time of 2.5 h. The photodegradation of BY28 was described by a pseudo-first-order kinetic model modified with the langmuir-Hinshelwood mechanism. The adsorption equilibrium constant and the rate constant of the surface reaction were calculated as $K_{dye}=6.689{\cdot}10^{-2}L\;mg^{-1}$ and $k_c=0.599mg\;L^{-1}min^{-1}$, respectively.

A Strategies to Improve the Natural Ventilation Performance at Underground Parking Lot in Multi-Residential Buildings (공동주택 지하주차장의 자연환기성능 향상방안에 관한 연구)

  • Seo, Jung-Min;Lee, Joong-Hoon;Song, Jong-Eui;Jung, Jung-Hwa;Song, Doo-Sam
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.23 no.2
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    • pp.153-163
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    • 2011
  • Energy efficiency and indoor air quality have become main issue to develop healthy and sustainable building in these days. As an effort to reduce the energy consumption in multi-residential building, many attempts as like passive design strategies and renewable energy as well as active control method are tried. However, underground parking lot in multi-residential building seldom adopt the sustainable strategies and only mechanical system is installed as usual. Moreover, the mechanical system installed in underground parking lot is rarely operated due to the electric demand for operation after completion. In this study, as an energy efficient measure, natural ventilation system using stack effect as a driving force for underground parking lot will be proposed and the performance of the suggested system will be analyzed by simulation method.