• Title/Summary/Keyword: Conductivity technique

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Control of scale formation using high voltage impulse (고전압 임펄스에 의한 스케일 제어)

  • Yang, Seon-Hee;Chang, In-Soung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.3
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    • pp.2301-2307
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    • 2015
  • The aim of this study was to evaluate the feasibility of application of the high voltage impulse (HVI) technique to the control of scale formation by calcium carbonate, which is pointed out as an important issue in industrial water treatment. The HVI system consisted of the power supply, high voltage generator, capacitors, switch and impulse generator was designed and made in laboratory scale, which can make 17kV impulse. HVI was introduced to the reactor that was filled with synthetic water containing $Ca^{2+}$ion. The concentration of calcium ion decreased only 3.0% after 5 minutes of contact time. However, it decreased up to 13.7% after 60 minutes of HVI contact time. Temperature and pH increased but conductivity decreased due to precipitation of the calcium carbonate. Although the decrease in concentration of calcium ion was not sufficient, it was verified that the HVI technique could be applicable for the softening and desalting processes.

Alternative Sintering Technology of Printed Nanoparticles for Roll-to-Roll Process (롤투롤 인쇄공정 적용을 위한 차세대 나노입자 소결 기술)

  • Lee, Eun Kyung;Eun, Kyoungtae;Ahn, Young Seok;Kim, Yong Taek;Chon, Min-Woo;Choa, Sung-Hoon
    • Journal of the Microelectronics and Packaging Society
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    • v.21 no.4
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    • pp.15-24
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    • 2014
  • Recently, a variety of printing technologies, including ink jet, gravure, and roll-to-roll (R2R) printing, has generated intensive interest in the application of flexible and wearable electronic devices. However, the actual use of printing technique is much limited because the sintering process of the printed nanoparticle inks remains as a huge practical drawback. In the fabrication of the conductive metal film, a post-sintering process is required to achieve high conductivity of the printed film. The conventional thermal sintering takes considerable sintering times, and requires high temperatures. For application to flexible devices, the sintering temperature should be as low as possible to minimize the damage of polymer substrate. Several alternative sintering methods were suggested, such as laser, halogen lamp, infrared, plasma, ohmic, microwave, and etc. Eventually, the new sintering technique should be applicable to large area, R2R, and polymer substrate as well as low cost. This article reviews progress in recent technologies for several sintering methods. The advantages and disadvantages of each technology will be reviewed. Several issues for the application in R2R process are discussed.

An Experimental Study of Nucleate Boiling Heat Transfer With EHD Technique in CFC-11 and HCFC-123 (Chiller용 냉매 CFC-11과 대체냉매 HCFC-123의 전기장을 사용한 핵비등 열전달 촉진에 관한 연구)

  • Kwak, T.H.;Kim, J.H.;Jung, D.S.;Kim, C.B.;Cha, T.W.;Han, C.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.6 no.4
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    • pp.365-379
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    • 1994
  • Pool boiling experiments were carried out to study the effect of electric field on nucleate boiling heat transfer. CFC-11 and its alternative HCFC-123 were used as working fluids. Boiling on both single tube and a bundle of five tubes was investigated. Heat flux varied from 5 to $25kW/m^2$ while the applied voltage changed from 0 to 1kV. The results showed that at low heat flux where boiling was not present or very weak, electric field-induced forced convection helped increase the heat transfer coefficients of CFC-11 and HCFC-123 significantly(4-15 times increase). However, at higher heat flux, nucleate boiling of CFC-11 which is a highly dielectric fluid, was not affected significantly by the application of electric field. In contrast to CFC-11, even at high heat flux, nucleate boiling of CFC-11 which has a relatively larger electric conductivity than CFC-11, was vigorously increased up to 2-4 times. The additional power required to apply the electric field was 1-2% of the total power consumption by the heater. The increase in overall heat transfer coefficient of evaporators with HCFC -123 was about 40%, suggesting a considerable reduction in evaporator size with EHD technique.

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Evaluation of Improvement of Detection Capability of Infrared Thermography Tests for Wall-Thinning Defects in Piping Components by Applying Lock-in Mode (적외선열화상 시험에서 위상잠금모드 적용에 따른 배관 감육결함 검출능력 개선 평가)

  • Kim, Jin Weon;Yun, Kyung Won
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.9
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    • pp.1175-1182
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    • 2013
  • The lock-in mode infrared thermography (IRT) technique has been developed to improve the detection capability of defects in materials with high thermal conductivity, and it has been shown to provide better detection capability than conventional active IRT. Therefore, to investigate the application of this technique to nuclear piping components, lock-in mode IRT tests were conducted on pipe specimens containing simulated wall-thinning defects. Phase images of the wall-thinning defects were obtained from the tests, and they were compared with thermal images obtained from conventional active IRT tests. It showed that the ability to size the detected wall-thinning defects in piping components was improved by using lock-in mode IRT. The improvement was especially apparent when detecting short and narrow defects and defects with slanted edges. However, the detection capability for shallow wall-thinning defects did not improve much when using lock-in mode IRT.

Measurement of Body Fat by Impedance Technique (임피던스 방법을 이용한 체지방 측정)

  • Kim, Deok-Won;Song, Chul-Gyu;Hwang, Soo-Kwan
    • Journal of Biomedical Engineering Research
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    • v.13 no.2
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    • pp.133-140
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    • 1992
  • Bioelectrical Impedance method for measuring human body composition is based upon the principle that the electrical conductivity of the fat-free mass (FFM) is far greater than that of the (at. Deter- mination o( impedance was nlade in 30 healthy and obese men aged $40.9{\pm}14.7$yr (mean${\pm}$SD) and 25 healthy and obese women aged $44.0{\pm}10.2$ yr. A commercial impedance body fat analyzer was used with a four electrode arrangement that introduced a painless constant current(ImA at 50 kHz) into the body. Linear relationships were found between impudence values and FFM(r=-0.786) and between weight and FFM(r=0.837). Signigicant increases in the correlation coefficients were ob served when the predicator Hta/z was regressed against FFM(r=0.912) where Ht Is height and Z Is impedance. A linear regression equation, FFM=0.586(Htf/z) +0.317(Weight) -1.674(r=0.977), was found. The correlation coefficient of % body fat between the impedance and infrared methods was 0.898. These data Indicate that the bioelectrical impedance technique is a reliable and valld approach for the estimation of human body composition. This method Is safe, noninvasivr, prouides rapld measure menu, requires little operator skill and subject cooperation, and Os portable. Finally measurement of percent body fat was made possible using both the regression equation and a developed impedance measuring device which measures impedance between wrist and ankle.

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Uncertainty Analysis of SWAT Model using Monte Carlo Technique and Ensemble Flow Simulations (몬테카를로 기법과 앙상블 유량모의 기법에 의한 SWAT 모형의 불확실성 분석)

  • Kim, Phil-Shik;Kim, Sun-Joo;Lee, Jae-Hyouk;Jee, Yong-Keun
    • Journal of The Korean Society of Agricultural Engineers
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    • v.51 no.4
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    • pp.57-66
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    • 2009
  • 수학적 모델은 수량과 수질의 예측을 위해 현장 조사의 대안으로 사용되어지며 이러한 모델의 사용과 실측에 불확실성이 존재하게 된다. 불확실성에 대한 많은 연구들이 진행되어 왔으나 시나리오에 의한 모델링 과정에서 발생하는 불확실성에 대한 연구는 미흡한 실정이다. 본 연구에서는 산림이 농경지와 목초지로의 변화에 따른 시나리오를 설계한 후 시나리오 적용에 따른 SWAT (Soil and Water Assessment Tool) 매개변수의 불확실성을 분석하고자 하였다. 몬테카를로 기법 (Monte Carlo simulation)을 이용하여 각 매개변수별 1,000개의 난수를 발생하였으며 앙상블 유량모의 기법을 이용하여 미국 Alabama주 카하바강 상류 (50,967ha)를 대상으로 각 난수별 100개의 유량을 통해 불확실성을 분석하였다. 분석 결과 산림지역이 농경지와 목초지로 변화 되었을 때 유출량이 증가하는 것으로 분석되었으며, 임야가 목초지 보다 농경지로 변화되었을 때 유출량은 더욱 증가하는 것으로 나타났다. 각 시나리오별 SWAT 매개변수의 불확실성은 AWC (Available water capacity), CN (Curve number), GWREVAP (groundwater re-evaporation coeffeicient), REVAPMN (minimum depth of water in shallow aquifer for re-evaporation to occur)순으로 크게 나타났으며, Ksat (Saturated hydraulic conductivity)와 ESCO(Soil evaporation compensation factor)는 유출량의 변화에 큰 영향을 미치지 못하는 것으로 분석되었다. 토지피복별 산림 면적이 클 경우 불확실성이 크게 나타나 산림이 목초지와 농경지로 변함에 따라 불확실성은 감소하는 것으로 나타났다.

Formation of Metal Electrode on Si3N4 Substrate by Electrochemical Technique (전기화학 공정을 이용한 질화규소 기판 상의 금속 전극 형성에 관한 연구)

  • Shin, Sung-Chul;Kim, Ji-Won;Kwon, Se-Hun;Lim, Jae-Hong
    • Journal of Surface Science and Engineering
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    • v.49 no.6
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    • pp.530-538
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    • 2016
  • There is a close relationship between the performance and the heat generation of the electronic device. Heat generation causes a significant degradation of the durability and/or efficiency of the device. It is necessary to have an effective method to release the generated heat. Based on demands of the printed circuit board (PCB) manufacturing, it is necessary to develop a robust and reliable plating technique for substrates with high thermal conductivity, such as alumina ($Al_2O_3$), aluminium nitride (AlN), and silicon nitride ($Si_3N_4$). In this study, the plating of metal layers on an insulating silicon nitride ($Si_3N_4$) ceramic substrate was developed. We formed a Pd-$TiO_2$ adhesion layer and used APTES(3-Aminopropyltriethoxysilane) to form OH groups on the surface and adhere the metal layer on the insulating $Si_3N_4$ substrate. We used an electroless Ni plating without sensitization/activation process, as Pd particles were nucleated on the $TiO_2$ layer. The electrical resistivity of Ni and Cu layers is $7.27{\times}10^{-5}$ and $1.32{\times}10^{-6}ohm-cm$ by 4 point prober, respectively. The adhesion strength is 2.506 N by scratch test.

Fabrication and Characterization of Alumina/Silver Nanocomposites

  • Cheon, Seung-Ho;Han, In-Sub;Woo, Sang-Kuk
    • Journal of the Korean Ceramic Society
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    • v.44 no.7
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    • pp.343-348
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    • 2007
  • Alumina/silver nanocomposites were fabricated using a soaking method through a sol-gel route to construct an intra-type nanostructure. The pulse electric-current sintering (PECS) technique was used to sinter the nanocomposites. Several specimens were annealed after sintering. The microstructure, mechanical properties, critical frontal process zone (FPZ) size, and thermo-mechanical properties of the nanocomposites were estimated. The relative densities of the specimens sintered at 1350 and $1450^{\circ}C$ were 95% and 99%, respectively. The maximum value of the three-point bending strength was found to be 780 MPa for the $2{\times}2{\times}10 mm$ specimen sintered at $1350^{\circ}C$. The fracture toughness of the specimen sintered at $1350^{\circ}C$ was measured to be $3.60 MPa{\cdot}m^{1/2}$ using the single-edge V-notched beam (SEVNB) technique. The fracture mode of the nanocomposites was transgranular, in contrast to the intergranular mode of monolithic alumina. The fracture morphology suggested that dislocations were generated around the silver nanoparticles dispersed within the alumina matrix. The specimens sintered at $1350^{\circ}C$ were annealed at $800^{\circ}C$ for 5 min, following which the maximum fracture strength became 810 MPa and the fracture toughness improved to $4.21 MPam^{1/2}$. The critical FPZ size was the largest for the specimen annealed at $800^{\circ}C$ for 5 min. Thermal conductivity of the alumina/silver nanocomposites sintered at $1350^{\circ}C$ was 38 W/mK at room temperature, which was higher than the value obtained with the law of mixture.

Hydrolysis Stability of Sulfonated Phthalic and Naphthalenic Polyimide with Ester Bond (에스테르기를 도입한 술폰화 프탈계 폴리이미드와 나프탈렌계 폴리이미드의 수화안정성에 관한 연구)

  • 이영무;이창현;손준용;박호범
    • Membrane Journal
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    • v.13 no.2
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    • pp.110-117
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    • 2003
  • Sulfonated polyimides had been utilized and studied widely as available materials in chloro-alkali electrolysis, cationic exchange resins, and so on. However, a slow decrease in performance during experiments had been reported, which could be attributed to a loss of ionic conductivity related to either a continuous dehydration or polymer degradation. One of main reasons to account for the degradation of sulfonated polymers is the hydrolysis leading to polymer chain scission and decrement of molecular weight. Therefore, the objective of our study was to investigate possible imide cycle and additional ester bond cleavage connected with $SO_3$H presence under hydrated condition. In order to confirm and obtain as clear information as possible about breakages of bonds via $^1H\; and \;^{13}C$ NMR and IR spectroscopic analyses, our study was performed by model compound. Consequently, model compounds with both phthalic and naphthalenic imide ring and ester bonds were synthesized to evaluate the hydrolysis stability of sulfonated polyimide. The experiments were performed for prepared model compounds before and after aging in deionized water at $80^{\circ}C$ and were terminated by lyophilization technique. The aging products were finally analyzed by NMR and IR spectroscopy.

Preparation and characterization of nanoflake composite multi core-shell SrFe12O19/Fe3O4/PEG/PPy

  • Hosseini, Seyed Hossein;Majidpour diz, Mohammad
    • Advances in materials Research
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    • v.1 no.2
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    • pp.161-168
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    • 2012
  • Nanoflake composite multi core-shell $SrFe_{12}O_{19}/Fe_3O_4$/PEG/Polypyrrole was synthesized by in situ polymerization method. In this paper, the fabrication of $SrFe_{12}O_{19}$ nanoflake is as first core by solgel method. Then fabricated a shell layer from magnetic nanoparticles of $Fe_3O_4$, which synthesized by coprecipitation technique, onto the $SrFe_{12}O_{19}$ nanoflake. Polyethylene glycol (PEG) as a polymer layer and as second shell was coated onto the before core-shell. Than core-shell $SrFe_{12}O_{19}/Fe_3O_4$/PEG was used as template for the preparation of $SrFe_{12}O_{19}/Fe_3O_4$/PEG/Polypyrrole composite. Final composite has a conductive property among $4.23{\times}10^{-2}Scm^{-1}$ and magnetic property about $M_s$=2.99 emu/g. Also final composite in soluble at organic solvent such as DMF and DMSO and has a flake structure. Conductivity and magnetic property respectively determine by four-probe instrument and vibrant sample magnetometer (VSM), morphology and article size determined by FE-SEM, TEM and XRD.