• 제목/요약/키워드: Conductivity Film

검색결과 906건 처리시간 0.033초

고분자전해필 연료전지 분리판용 316 스테인리스강의 전기전도도에 미치는 Nb, Ti 첨가 및 표면처리 효과 (Effects of Nb and Ti Addition and Surface Treatments on the Electrical Conductivity of 316 Stainless Steel as Bipolar Plates for PEMFC)

  • 이석현;김정헌;김민철;천동현;위당문
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2006년도 추계학술대회
    • /
    • pp.324-324
    • /
    • 2006
  • Nb and Ti were added to 316 stainless steel, and then heat-treatments and surface treatments were performed on the 316 stainless steel and the Nb- and Ti-added alloys. All samples indicated enhanced electrical conductivity after surface treatments, whereas they showed low electrical conductivity before surface treatments due to the existence of non-conductive passive film on the alloy surface. In particular, the Hb- and Ti-added alloys showed remarkable enhancement of electrical conductivity compared to the original alloy, 316 stainless steel. Surface characterization revealed that small carbide particles formed on the alloy surface after surface treatments, while the alloys indicated flat surface structure before surface treatments. $Cr_{23}C_6$ mainly formed on the 316 stainless steel, and NbC and TiC mainly formed on the Nb- and Ti-added alloys, respectively. We attribute the enhanced electrical conductivity after surface treatments to the formation of these carbide particles, possibly acting as a means of electro-conductive channel through the passive film. Furthermore, NbC and TiC are supposed to be more effective carbides than $Cr_{23}C_6$ as electro-conductive channels of stainless steel

  • PDF

Solvent Treatment for PEDOT:PSS Conductivity Enhancement

  • 황기환;정원석;남상훈;유정훈;주동훈;부진효
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
    • /
    • pp.333-333
    • /
    • 2013
  • The poor conductivity of poly (3,4-ethylene dioxythiophene): poly (styrenesulfonate) (PEDOT:PSS) film hinders to use for a flexible electrode in solar cells. In this report we demonstrate that the conductivity of PEDOT:PSS film can be enhanced by modifying structures in a mixture of PEDOT: PSS aqueous solution and various organic solvents such as polar protic (2-propanol, methanol, ethanol, formic acid) and aprotic solvents (acetone and acetonitrile). To comparatively study the structural effects on the resulted electrical properties, the films are spin-coated on glasses and ITO. At the same time, a contact angle goniometer is used for clarifying a mechanism of wettability of PEDOT (hydrophobic) and PSS (hydrophilic) on the observed conductivity. The structures and electrical properties are investigated by FE-SEM (Field Emission Scanning Electron Microscopy), AFM (Atomic Force Microscopy), and 4-point probe, respectively.

  • PDF

PEDOT:PSS 전극의 전도도향상에 의한 CNT/PVDF 복합막의 압전성능 개선 (Improvement of Piezoelectric Performance of the CNT/PVDF Composite Film by Enhancing Conductivity of the PEDOT:PSS Electrodes)

  • 임영택;이선우
    • 한국전기전자재료학회논문지
    • /
    • 제29권11호
    • /
    • pp.716-719
    • /
    • 2016
  • In this paper, we fabricated flexible CNT/PVDF (carbon nanotube / polyvinylidene fluoride) piezoelectric composite device with flexible poly(3,4-ethylenedioxythiophene) : polystyrene sulfonate (PEDOT:PSS) conducting polymer electrode using spray coating method. We tried to improve the piezoelectric performance from the CNT/PVDF composite film by enhancing electrical conductivity of the PEDOT:PSS electrodes. Electrical conductivity of the PEDOT:PSS electrode was enhanced by dipping it into the EG (ethylene glycol) solvent. Changes of chemical composition of the PEDOT:PSS electrode were analyzed with the dipping time by XPS (x-ray photoelectron spectroscopy) in terms of oxygen (O1s). Finally, Piezoelectric performances such as output voltage and current were measured with the dipping time. We found that enhanced electrical conductivity of the PEDOT:PSS electrodes resulted in improvement of the piezoelectric performance of the CNT/PVDF films.

알루미늄 스퍼터링 처리 의류소재의 스텔스 특성과 전자파 차단 및 전기적 특성에 관한 연구 - 밀도 변화를 중심으로 - (Stealth, electromagnetic interception, and electrical properties of aluminum sputtered clothing materials - Focusing on the density change -)

  • 한혜리
    • 복식문화연구
    • /
    • 제30권4호
    • /
    • pp.579-593
    • /
    • 2022
  • This study examines the surface characteristics, electrical conductivity, electromagnetic wave blocking characteristics, infrared (IR) transmittance, stealth function, thermal characteristics, and moisture characteristics of IR thermal imaging cameras. Nylon film (NFi), nylon fabric (NFa), and 5 types of nylon mesh were selected as the base materials for aluminum sputtering, and aluminum sputtering was performed to study IR thermal imaging, color difference, temperature change, and so on, and the relationship with infrared transmittance was assessed. The electrical conductivity was measured and the aluminum-sputtered nylon film demonstrated 25.6kΩ of surface resistance and high electrical conductivity. In addition, the electromagnetic wave shielding characteristics of the sputtering-treated nylon film samples were noticeably increased as a result of aluminum sputtering treatment as measured by the electromagnetic wave blocking characteristics. When NFi and NFa samples with single-sided sputtering were placed on the human body (sputtering layer faced the outside air) and imaged using IR thermographic cameras, the sputtering layer displayed a color similar to the surroundings, showing a stealth effect. Moreover, the tighter the sample density, the better the stealth function. According to the L, a, b measurements, when the sputtering layer of NFi and NFa samples faced the outside air, the value of a was generally high, thereby demonstrating a concealing effect, and the △E value was also high at 124.2 and 93.9, revealing a significant difference between the treated and untreated samples. This research may be applicable to various fields, such as the military wear, conductive sensors, electromagnetic wave shielding film, and others.

Octadecylviologen-TCNQ LB 막의 물리적 특성 (Physical Properties of the Langmuir-Blodgett Films Layered with Octadecylviologen-TCNQ)

  • 신동명;박제상;강도열
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1995년도 춘계학술대회 논문집
    • /
    • pp.77-80
    • /
    • 1995
  • Enhancing the electrical conductivity of the ultrathin organic films using Langmuir-Blodget technique is important step for the developement of molecular electronic device. The Octadecylviologen-TCNQ was synthesized with Octadecylviologen-Bromide an Lithium TCNQ Sine Octadecylviologen-TCNQ has two TCNQ snion radicals, the conductivity of LB film is expected to increase. The $\pi$-A isotherm showed that the limiting area was 150${\AA}$$\^$2/ molecule and the silid-like transition surface pressure was 25 mN/m. The electronic transition of the TNCNQ anion radical was observed at 400 nm. Intermolecular charge transfer absorption was observed at 600nm and 850~1050 nm which ay resulted from the TCNQ anion radical dimer formation. The electrical conductivity of the viologen -TCNQ LB film was 10$\^$-6/cm This values was 100 times higher than that of the quinolinium-TCNQ and pyridinium-TCNQ LB films.

  • PDF

자동차용 클러치 마찰재의 미끄럼마찰마모특성 해석(제2보 마찰특성) (Analysis of Sliding Friction and Wear Properties of Clutch Facing for Automobile (Part 2))

  • 이한영;김근영;허만대
    • Tribology and Lubricants
    • /
    • 제21권2호
    • /
    • pp.77-82
    • /
    • 2005
  • In previous paper, the wear properties of clutch facing materials with two different copper amounts against fly-wheel materials used in the clutch system were investigated by sliding wear tests at different applied loads and speeds. This paper have been aimed to evaluate the friction properties for clutch facing materials at the same test conditions as the previous paper. The experimental results indicated that the friction properties of clutch facing materials are influenced from the thermal conductivities of the clutch facing material and the counter material. The clutch facing material with the lower thermal conductivity and the fly-wheel material with the higher thermal conductivity showed the low and stable friction coefficient in the range of high sliding speed. This appears to be due to the formation of a film on the surface of the fly-wheel material.

LB법을 이용한 viologen-diTCNQ 박막의 광학적 및 전기적 특성 (Optical and Electrical Characteristics of viologen-diTCNQ thin film prepared by Langmuir-Blodgett Technique)

  • 이용수;신동명;김태완;강도열
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1997년도 춘계학술대회 논문집
    • /
    • pp.45-48
    • /
    • 1997
  • Enhancing the electrical conductivity of the ultrathin organic films is one of the important factors for the development of molecular electronic devices. The Langmuir-Blodgett(LB) technique has recently been attracted interest as the a method of deposition ultrathin films. We have fabricated N-docosyl-N'-methyl viologen-diTCNQ(DMVT) anion radical LB film and investigated the optical and electrical conductivity. We have measured UV/visible and FT-lR spectrum. In ESR spectrum, we confirmed that a half-amplitude linewidth is clearly dependent on both temperature and incident angle, which indicates conducting species change. The in-plane electrical conductivity of 21 layers is approximately 1.37$\times$10$^{-6}$ (S/cm).

  • PDF

이온전도성 Poly(ethylene oxide) 고분자 전해질의 전도도에 미치는 가소제 첨가 효과 (The Effects of Plasticizer Addition on the Conductivity of Polymer Electrolyte Based on Poly(ethylene oxide))

  • 문성인;진봉수;김종욱;윤문수;구할본
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1994년도 추계학술대회 논문집
    • /
    • pp.82-85
    • /
    • 1994
  • The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li secondary battery. This paper describes effects of plasticizer addition and temperature dependence of conductivity of these PEO electrolytes. Adding propylene carbonate and ethylene carbonate to PEO-LiClO$_4$electrolyte, its conductivity was higher than PEO-LiClO$_4$ itself. Steady state current method and AC impedance used for the determination of transference number in PEO electrolyte film. The transference number of PEO$\_$8/LiClO$_4$PC$\_$5/EC$\_$5/ polymer electrolyte film is 0.45 at 60$^{\circ}C$.

Ballistic Diffusive Approximation에 의한 Quantum Dot Superlattice의 나노열전달 해석 (Analysis of Nano-Scale Heat Conduction in the Quantum Dot Superlattice by Ballistic Diffusive Approximation)

  • 김원갑;정재동
    • 대한기계학회:학술대회논문집
    • /
    • 대한기계학회 2004년도 춘계학술대회
    • /
    • pp.1376-1381
    • /
    • 2004
  • Understanding the thermal conductivity and heat transfer processes in superlattice structures is critical for the development of thermoelectric materials and optoelectronic devices based on quantum structures. $Chen^{(1)}$ developed ballistic diffusive equation(BDE) for alternatives of the Boltzmann equation that can be applied to the complex geometrical situation. In this study, a simulation code based on BDE is developed and applied to the 1-dimensional transient heat conduction across a thin film and transient 2-dimensional heat conduction across the film with heater. The obtained results are compared to the results of the $Chen^{(1)}$ and Yang and $Chen^{(1)}$. Finally, steady 2-dimensional heat conduction in the quantum dot superlattice are solved to obtain the equivalent thermal conductivity of the lattice and also compared with the experimental data from $Borca-Tasciuc^{(2)}$.

  • PDF

정전기 방전에 의해 제조된 흑연박리 그래핀 첨가 폴리이미드 막의 열전도 향상 (Thermal Conductivity Enhancement of Polyimide Film Induced from Exfoliated Graphene Prepared by Electrostatic Discharge Method)

  • 임채훈;김경훈;안동해;이영석
    • 공업화학
    • /
    • 제32권2호
    • /
    • pp.143-148
    • /
    • 2021
  • 본 연구에서는 폴리이미드(polyimide; PI) 막(film)의 열전도도를 향상시켜 그 응용성을 확대하고자, 정전기 방전법을 이용하여 흑연봉으로부터 그래핀을 제조하고 제조된 그래핀을 첨가하여 폴리아믹산(polyamic acid; PAA) 전구체로부터 200 ㎛두께의 폴리이미드 기반 열전도 막을 제조하였다. 정전기 방전 기법으로 생산된 그래핀은 라만, XPS, TEM 등을 이용하여 물성을 평가하였다. 제조된 그래핀은 라만 스펙트럼 분석 결과 ID/IG 값이 0.138이며, XPS 분석 결과 C/O 비율이 24.91로 구조적, 표면화학적으로 우수한 물성을 나타내었다. 또한, 흑연 박리 그래핀의 첨가량에 따라 폴리이미드 막의 열전도도는 지수함수적으로 증가하였으며, 그래핀 함량을 40% 초과 시에는 폴리이미드 막을 제조할 수 없었다. 그래핀을 폴리아믹산 중량 대비40 wt% 첨가하여 제조된 폴리이미드 막의 열원반(hot disk) 열전도도는 51 W/mK를 나타내었으며, 순수한 폴리이미드 막의 열전도도(1.9 W/mK)보다 크게 향상되었다. 이 결과는 정전기 방전기법으로 제조된 박리 그래핀의 우수한 물성에 기인한 것으로 판단된다.