Globally, nuclear-decommissioning facilities have been increased in number, and thereby hundreds of thousands of wastes, such as concrete, soil, and metal, have been generated. For this reason, there have been numerous efforts and researches on the development of technology for volume reduction and recycling of solid radioactive wastes, and this study reviewed and examined thoroughly such previous studies. The waste concrete powder is rehydrated by other processes such as grinding and sintering, and the processes rendered aluminate (C3A), C4AF, C3S, and -C2S, which are the significant compounds controlling the hydration reaction of concrete and the compressive strength of the solidified matrix. The review of the previous studies confirmed that waste concretes could be used as recycling cement, but there remain problems with the decreasing strength of solidified matrix due to mingling with aggregates. There have been further efforts to improve the performance of recycling concrete via mixing with reactive agents using industrial by-products, such as blast furnace slag and fly ash. As a result, the compressive strength of the solidified matrix was proved to be enhanced. On the contrary, there have been few kinds of researches on manufacturing recycled concretes using soil wastes. Illite and zeolite in soil waste show the high adsorption capacity on radioactive nuclides, and they can be recycled as solidification agents. If the soil wastes are recycled as much as possible, the volume of wastes generated from the decommissioning of nuclear power plants (NPPs) is not only significantly reduced, but collateral benefits also are received because radioactive wastes are safely disposed of by solidification agents made from such soil wastes. Thus, it is required to study the production of non-sintered cement using clay minerals in soil wastes. This paper reviewed related domestic and foreign researches to consider the sustainable recycling of concrete waste from NPPs as recycling cement and utilizing clay minerals in soil waste to produce unsintered cement.
The structures of reinforced concrete have been extensively increased with rapid development of industrial society. Futhermore, these reinforced concretes are easy to expose to severe corrosive environments such as seawater, contaminated water, acid rain and seashore etc.. Thus, corrosion problem of steel bar embedded in concrete is very important in terms of safety and economical point of view. In this study, specimens having six different coating thickness (W/C:0.5) were prepared and immersed in flowing seawater for five years to evaluate the effect of coating thickness and immersion time on corrosion property. The polarization characteristics of these embedded steel bars were investigated using electrochemical methods such as corrosion potential, anodic polarization curve, and impedance. At the 20-day immersion, the corrosion potentials exhibited increasingly nobler values with coating thickness. However, after 5-yr. immersion their values were shifted in the negative direction, and the relationship between corrosion potential and coating thickness was not shown. Although 5-yr. immersion lowered corrosion potential, 5-yr. immersion did not increase corrosion rate. In addition, after 5-yr. immersion, the thinner cover thickness, corrosion current density was decreased with thinning coating thickness. It is due to the fact that ease incorporation of water, dissolved oxygen and chloride ion into a steel surface caused corrosion and hence, leaded to the formation of corrosion product. The corrosion product plays the role as a corrosion barrier and increases polarization resistance. The corrosion probability evaluated depending on corrosion potential may not be a good method for predicting corrosion probability. Hence, the parameters including cover thickness and passed aged years as well as corrosion potential is suggested to be considered for better assessment of corrosion probability of reinforced steel exposed to partially or fully in marine environment for long years.
Kim, Hyunwook;Phee, Young Gyu;Won, Jung Il;Ko, Won Kyung;Roh, Young Man;Shin, Chang Sub
Journal of Korean Society of Occupational and Environmental Hygiene
/
v.10
no.1
/
pp.104-114
/
2000
This study was carried out to estimate current status of dust concentrations in the factories producing non-metallic products in Korea. Data were gathered from the environmental monitoring reports by 40 workplace environmental monitoring institutes and the questionnaire designed for the study by the authors. A total of 1838 dust samples from 368 plants were obtained from the reports and were analyzed with no data modifications. But data on asbestos, rock wool, and welding fumes were excluded in this evaluation. The factories were classified into eight groups according to the standard industrial classification scheme in Korea. The results of this study were as follows; 1. The factories included were glass, non-refractory ceramic, refractory ceramic ware, structural non-refractory clay and ceramic, cement and lime, articles of concretes, and stone. Mean(geometric mean) concentrations of total dust samples ranged from $1.75(0.84)mg/m^3$ to $5.87(2.84)mg/m^3$. Statistically significantly higher dust concentrations were found in the cement and lime industries compared with other industries. 2. The non-compliance rates were 15.2% in glass and 20.6% in other non-metallic mineral products industries. Although all institutions surveyed utilized the identical sampling and classification scheme for dusts as specified in the current occupational exposure limits, wide discrepancies were found in collecting samples and classifying dusts. Further problems were discovered in classifying dusts. A dust sample collected could be classified into any of the three groups regardless of silica content. The results of this study showed that dust concentrations in the non-metallic products industries varied widely. Also discovered was classification errors of dust types among workplace monitoring institutes. These errors could adversely affect the results of exposure assessments and the true nature of dust hazards. Further, no institutions performed respirable dust sampling and analysis of crystalline silica. In order to correct these malpractices, current standards of occupational exposure limits should be revised and tight supervision by the Ministry of Labour be suggested.
KSCE Journal of Civil and Environmental Engineering Research
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v.31
no.4D
/
pp.577-584
/
2011
A series of field and laboratory permeability tests were performed to investigate the pore-clogging phenomenon of porous concrete used for pavement materials of a road. The field permeability tests were conducted for 37 study points in Jeju city, using the porous concretes with 13mm of maximum coarse aggregate ($G_{max}$). The results show that the service life of porous concrete is about 22 months when the permeability of the porous concrete is designed for 0.01 cm/sec. Some specimens were made with the purpose of recreating pore-clogging phenomenon. Tests were done for injected concentration of pore-clogging materials or size of maximum coarse aggregates ($G_{max}$). The test results demonstrated that relatively long in service life experienced with small amount of injected concentration of pore-clogging materials, whereas relatively short in service life experienced with a reduction in size of maximum coarse aggregates ($G_{max}$). In conclusion, the service life of porous concrete is in proportion to the concentration of pore-clogging material but it is in inverse proportion to the size of maximum coarse aggregate ($G_{max}$). Thus, the persisting period of porous concrete can be determined with respect to concentration of pore-clogging materials or size of maximum coarse aggregates ($G_{max}$).
Journal of the Korean Crystal Growth and Crystal Technology
/
v.18
no.5
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pp.211-216
/
2008
The artificial lightweight aggregate (ALA) was manufactured in a rotary kiln at $1125^{\circ}C$ using green body formed by pelletizing the batch powder composing of coal bottom ash (CBA) produced from power plant, clay and dredged soil (DS). The TCLP (Toxicity characteristic leaching procedure) results showed that the dissolution concentration of heavy metal ions of ALA fabricated in this study was below the limitation defined by the enforcement regulations of wastes management law in Korea. The ALA containing 60$\sim$70 wt% CBA had a bulk density of 1.45$\sim$1.49 and a water absorption of 17.2$\sim$18.5 %. The impact values for oven-dry state and saturated-surface dry state of ALA were 27.4$\pm$1.3 and 23.4$\pm$2.6 % respectively. The 28-days compressive strength of concrete made with various ALA was $22.7\sim27.8 N/mm^2$. The slump of concrete with ALA containing CBA 60 and 70 wt% were 7.9 and 14.3 cm respectively. The unit weight of concrete made with any ALA fabricated in this study was satisfied with the standard specifications of lightweight concrete for the civil engineering and construction presented by Korea as below $1.84 ton/m^3$.
Kim, Byeong-Jo;Song, Jin-Kyu;Song, Keum-Il;Oh, Myeong-Hyeon;Lee, Bang-Yeon
Journal of the Korea Concrete Institute
/
v.27
no.5
/
pp.511-519
/
2015
Methods such table flow, slump and outflow time have used to be as a main evaluation criteria regards to fluidity of concrete. Since those methods mentioned above have some inaccuracies which are up to its condition of test. Studies that evaluate fluidity applying the rheology has increased its portion in this field. Meanwhile, demands for AAS binder have been increased in accordance with its demand for this market, studies for rheology of AAS binder are little though. Therefore, this paper mainly deals a rheological peculiarity of AAS binder according to its condition of W/B ratio and alkali activators. The fluidity of AAS paste was evaluated with the index of table flow and outflow time. And shear stress following its shear rate was analyzed through rheological test. Rheological parameters were deduced through this rheological test of Bingham model and analyzed its interrelation with fluidity test. As the final outcome, it proposed the interrelation among table flow, yield stress, viscosity and outflow time. In basis of this study, we would like to suggest a reference for mixing AAS mortars and concretes.
Jo, Byung-Wan;Yoon, Kwang-Won;Park, Jung-Hoon;Kim, Heoun
Journal of the Korea Concrete Institute
/
v.22
no.3
/
pp.287-295
/
2010
In this study, ordinary Portland cement was used and the air void was minimized by using minute quartz as the filler. In addition, steel fibers were used to mitigate the brittle failure problem associated with high strength concrete. This study is in progress to make an Ultra-high strength powdered concrete (UHSPC) which has compressive strength over 300 MPa. To increase the strength of concrete, we have compared and analyzed the compressive strengths of the concretes with different mix proportions and curing conditions by selecting quartz sand, dolomite, bauxite, ferro silicon which have diameters less than 0.6 mm and can increase the bond strength of the transition zone. Ultra-high strength powdered concrete, which is different from conventional concrete, is highly influenced by the materials in the mix. In the study, the highest compressive strength of the powdered concrete was obtained when it is prepared with ferro silicon, followed in order by Bauxite, Dolomite, and Quartz sand. The amount of ferro silicon, when the highest strength was obtained, was 110%, of the weight of the cement. SEM analysis of the UHSPC showed that significant formation of C-S-H and Tobermorite due to high temperature and pressure curing. Production of Ultrahigh strength powdered concrete which has 28-day compressive strength upto 341MPa has been successfully achieved by the following factors; steel fiber reinforcement, fine particled aggregates, and the filling powder to minimize the void space, and the reactive materials.
In these days, construction activities have caused civil petitions associated with vibration-induced damages or nuisances. Therefore, it is strongly needed to develop a remedial technique to mitigate unfavorable effects. The objective of this experimental research is to investigate material and structural dynamic characteristics of vibration-controlled concretes which have been proportionally mixed with various vibration reducing material, such as latex, rubber powder, plastic resin, polystyrofoams and etc. Normal and high strength concrete specimens are also prepared for corresponding comparison. As part of the recycling research for obsolete rubber and plastic materials, 32 concrete cylinders and 10 concrete flexural beams have been made for material and structural dynamic properties, respectively. In accordance with the resonance test on concrete cylinders, it can be concluded that concrete with vibration-reducing material have relatively larger material damping ration than normal or high strength concrete. Styrofoam is determined to be very effective vibration-reducing mixtures. From the vibration test on 10 concrete flexural beams, meamwhile, of importance observations was that material damping ratio is very smaller than structural damping ratio of corresponding specimen. But further vibration test on more flexural beams should be strongly needed by varying support conditions.
This paper investigates the relationships between dynamic elastic modulus and static elastic modulus or compressive strength according to curing temperature, aging, and cement type. Based on this investigation, the new model of the relationships we proposed. Impact echo method estimates the resonant frequency of specimens and uniaxial compression test measures the static elastic modulus and compressive strength. Type I and V cement concretes, which have the water-cement ratios of 0.40 and 0.50, are cured under the isothermal curing temperatures of 10, 23, and 50$\^{C}$ Cement type and aging have no large influence on the relationship between dynamic and static elastic modulus, but the ratio of dynamic and static elastic modulus comes close to 1 as temperature increases. Initial chord elastic modulus which is calculated at lower strain level of stress-strain curve, has the similar value to dynamic elastic modulus. The relationship between dynamic elastic modulus and compressive strength has the same tendency as the relationship between dynamic and static elastic modulus according to cement type, temperature and aging. The proposcd relationship equations between dynamic elastic modulus and static elastic modulus or compressive strength properly estimates the variation of relationships according to cement type md temperature.
A review is presented of experimental studies on the strength performance of concrete exposed at short-term and rapid heating as in a fire and after cooling. Emphasis is placed on concretes with high original compressive strengths, that is, high-strength concrete(HSC). The compressive strength-temperature relationships from the reviewed test programs are distinguished by the test methods used in obtaining the data(unstressed, unstressed residual strength, and stressed tests) and by the aggregate types(normal or lightweight), The compressive strength properties of HSC vary differently with temperature than those of NSC. HSC have higher rates of strength loss than lower strength concrete in the temperature range of between 20$^{\circ}C$ to about 400$^{\circ}C$. These difference become less significant at temperatures above 400$^{\circ}C$ compressive strengths of HSC at 800$^{\circ}C$ decrease to about 30 % of the original room temperature strength. A comparison of lest results with current code provisions on the effects of elevated temperatures on concrete compressive strength and elastic modulus shows that the CEN Eurocodes and the CEB provisions are unconservative.
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