• Title/Summary/Keyword: Concentration of Solution

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Improvement of the Degreasing Performance of Surface Treating Steel Sheet by the Automatic Control of Alkaline Degreasing Process (알칼리탈지공정 자동화관리에 의한 표면처리용 강판의 탈지능 향상)

  • 박노범;박대수;박정렬;유민수
    • Journal of Surface Science and Engineering
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    • v.29 no.2
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    • pp.132-139
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    • 1996
  • Experiments on the automatic control of NaOH concentration and on the spraying condition of NaOH solution in the alkaline degreasing process of a continuous hot-dip galvanizing line have been carried out in order to improve degreasing performance of a galvanizing sheet steel using laboratory degreasing and galvanizing simulators. The concentration of NaOH for the good degreasing has been determined to be 6.0% and more and this concentration has been able to be automatically well controlled within $\pm$0.1% by employing a solution electrical conductivity meter under a flow injection analysis condition rather than by employing a sodium ion selective electrode in the degreasing simulator. Frequent blocking of the spraying nozzles of the solution has been reduced considerably by the set-up and periodical operation of an automatic valve system in the nozzle system. By applying this automatic valve system and by automatic controlling the NaOH concentration and other ordinary variables in the degreasing process, the degreasing performance has been increased from the conventional 76% to the new 85%.

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The Study on the Influence of the Concentration NaCl Solution on Corrosion Fatigue Behavior of T.M.C.P. Steel (T.M.C.P. 강의 부식피로거동에 미치는 염분의 영향에 관한 연구)

  • 이상호;한정섭
    • Journal of Ocean Engineering and Technology
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    • v.7 no.2
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    • pp.131-140
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    • 1993
  • To study the corrosion fatigue begavior of T.M.C.P. steel, the rotary bending fatigue test with the change of concentration of NaCl solution was carried out. Fatigue life in the corrosion environment is decreased markedly in comparision with that in the air. Fatigue limit in the air was about 225 MPa. In case of 3.5% NaCl solution fatigue life could be expressed as .sigma./sub f/=10,392 * (N/sub f/)/sup -o.2923 . According to the paris's rule, crack growth rates could be expressed as da/dN=2.62.*10/sup -7/ .DELTA. K/sup 1.09/(3.5% NaCl solution), da/dN=1.95 *10/sup -7 .DELTA. K/sup 1.05/(1% NaCl solution), da/dN=2.62 * 10/sup -7/.DELTA./sup 0.72/(0.01% NaCl solution) with da/dN expressed in mm/cycle and .DELTA.K in MPa.GAMMA.m. The crack growth rate in the corrosion environment was highest under 3.5% NaCl solution.

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Si Anisotropic Etching Characteristics of TMAH/IPA (TMAH/IPA의 실리콘 이방성 식각특성)

  • 정귀상;박진성;최영규
    • Electrical & Electronic Materials
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    • v.10 no.5
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    • pp.481-486
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    • 1997
  • This paper describes the anisotropic etching characteristics of Si in acqueous TMAH/IPA solutions. The etch rates of (100) oriented Si crystal planes decrease with increasing TMAH concentration and IPA concentration. Etchant concentration and etch temperature have a large effect on hillock density. Hillock density strongly increase with lower TMAH concentration and higher etch temperature. The etched (100) planes are covered by pyramidal-shaped hillocks below TMAH 15 wt.%, but very smooth surface is obtained TMAH 25 wt.%. The addition of IPA to TMAH solution leads to smoother surfaces of sidewalls etched planes. Undercutting ratio of pure TMAH solution is much higher than KOH. But, addition of IPA to TMAh the underrcutting ratio reduces by a factor of 3∼4. Therefore, acqueous TMAH/IPA solution is able to use as anisotropic etchant of Si because of full compability with IC fabrication process.

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Regulation of precursor solution concentration for In-Zn oxide thin film transistors

  • Chen, Yanping;He, Zhongyuan;Li, Yaogang;Zhang, Qinghong;Hou, Chengyi;Wang, Hongzhi
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1300-1305
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    • 2018
  • The tunable electronic performance of the solution-processed semiconductor metal oxide is of great significance for the printing electronics. In current work, transparent thin-film transistors (TFTs) with indium-zinc oxide (IZO) were fabricated as active layer by a simple eco-friendly aqueous route. The aqueous precursor solution is composed of water without any other organic additives and the IZO films are amorphous revealed by the X-ray diffraction (XRD). With systematic studies of atomic force microscopy (AFM), X-ray photoemission spectroscopy (XPS) and the semiconductor property characterizations, it was revealed that the electrical performance of the IZO TFTs is dependent on the concentration of precursor solution. As well, the optimum preparation process was obtained. The concentrations induced the regulation of the electronic performance was clearly demonstrated with a proposed mechanism. The results are expected to be beneficial for development of solution-processed metal oxide TFTs.

Effects of Glycerin and PEG 400 in Donor and Receptor Solutions upon Skin Permeation of Drug (In vitro 경피흡수 실험시 Donor와 Receptor용액중의 글리세린과 PEG 400이 약물의 경피투과도에 미치는 영향)

  • Cho, Ae-Ri
    • Journal of Pharmaceutical Investigation
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    • v.26 no.2
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    • pp.99-103
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    • 1996
  • Effects of glycerin and PEG 400 in donor and receptor solutions upon skin permeation of drug were investigated. Deoxycortisone was used as a model compound. In vitro skin permeation study with freshly excised hairless mouse skin was performed and the steady-state skin permeation rates of the drug were determined in different fractions of glycerin or PEG 400 in donor and receptor solutions. Glycerin in donor solution didn't show any effect on the skin permeation rate of deoxycortisone. However glycerin in receptor solution showed significant effect on the skin permeation rate of the drug. In glycerin, there's a critical concentration for balancing hydration and dehydration of skin. At low concentration, less than 20 %, glycerin showed the enhancement of the flux due to the hydration effect of skin. At high concentration, more than 30 %, glycerin retard the permeation rate which might be due to the dehydration effect on the dermis layer. Since dermis has more water content than the stratum corneum, the steady state skin permeation rates were more influenced when glycerin was in receptor solution than that of in donor solution. PEG 400 aqueous solutions doesn't affect the steady state permeation rate of deoxycortisone significantly.

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Study on Narrow Band Solution of the Radiative Transfer within a Cubical Enclosure by Nongray Gas Mixtures with Nonuniform Concentration Profiles (비균일 농도 분포를 갖는 비회색 혼합가스로 충만된 정육면체 내의 좁은 파장모델을 이용한 복사열전달 해석 연구)

  • Park, W.H.;Chun, S.H.;Kim, T.K.;Son, B.S.
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.371-376
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    • 2001
  • Radiative transfer by nongray gas mixtures with nonuniform concentration and temperature profiles were studied by using the statistical narrow-band model and ray-tracing method with the sufficiently accurate $T_{60}$ quadrature set. Transmittances through the nonhomogeneous gas mixtures were calculated by using the Curtis-Godson approximation. Three different cases with different temperature and concentration profiles were considered to obtain benchmark solutions for nongray gas mixtures with nonuniform concentration and temperature profiles. The solutions obtained from this study were verified and found to be very well matched with the previous solutions for uniform gas mixtures. The results presented in this paper can be used in developing various solution methods for radiative transfer by nongray gas mixtures.

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Effect of the Corrosive Solution Conditions and Scan Rate to the Electrochemical Corrosion on the AISI 304 Stainless Steel (부식액의 조건 및 주사 속도가 AISI 304 스테인리스강의 전기화학적 부식에 미치는 영향)

  • 나은영;백신영
    • Journal of Advanced Marine Engineering and Technology
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    • v.21 no.5
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    • pp.535-541
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    • 1997
  • The effect of concentration of each solution( HCI, $H_2SO_4$ and $HNO_3$), scan rate and polished surface condition on the corrosion of AISI 304 Stainless Steel were investigated, utilizing the Method ASTM G5 - 87. It can be concluded that: 1) For the same concentration(i.e. 1N) of each solution the corrosion rate is the highest in HCI and lowest in $HNO_3$. Also, the difference of values of $i_{cirt}$ generated for each solution is significant. 2) As the concentration of the solution $H_2SO_4$ is increased (O.5N, 1N, 2N) the values of $E_{cor}$ $i_{crit}$ and $i_{p}$ are increased. 3) In case of existence of SCN ion of O.OlN, the values of iCTIt and ip generated are approximately 100 times and 1.4 times higher respectively, than in the case of non - existence of $SCN^{-}$. However the existence of $SCN^{-}$ doesn't affect the value of $E_{cor}$ and $E_{p}$. 4) The values of $i_{crit}$ and $i_{p}$ are increased due to the increase of scan rate. But the values of $E_{cor}$ and $E_{p}$ do not depend on the scan rate. 5) The $i_{p}$ value depends greatly on oxygen in the solution, but the changes in values of $E_{cor}$ $i_{crit}$ and $E_{b}$ due to the oxygen are insignificant. 6) If a component is polished using #400, #600 and #800 wet polish paper, the effect of surface condition on variations of values of $i_{crit}$ and $i_{p}$ is slightly significant.

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Removal of Benzene in Solution by using the Bio-carrier with Dead Bacillus drentensis sp. and Polysulfone (Bacillus drentensis sp. 사균과 polysulfone으로 이루어진 미생물담체를 이용한 수용액 내 벤젠 제거)

  • Park, Sanghee;Lee, Minhee
    • Journal of Soil and Groundwater Environment
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    • v.18 no.1
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    • pp.46-56
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    • 2013
  • Laboratory scale experiments to remove benzene in solution by using the bio-carrier composed of dead biomass have been performed. The immobilized bio-carrier with dead Bacillus drentensis sp. and polysulfone was manufactured as the biosorbent. Batch sorption experiments were performed with bio-carriers having various quantities of biomass and then, their removal efficiencies and uptake capacities were calculated. From results of batch experiments, 98.0% of the initial benzene (1 mg/L) in 1 liter of solution was removed by using 40 g of immobilized bio-carrier containing 5% biomass within 1 hour and the biosorption reaction reached in equilibrium within 2 hours. Benzene removal efficiency slightly increased (99.0 to $99.4%{\pm}0.05$) as the temperature increased from 15 to $35^{\circ}C$, suggesting that the temperature rarely affects on the removal efficiency of the bio-carrier. The removal efficiency changed under the different initial benzene concentration in solution and benzene removal efficiency of the bio-carrier increased with the increase of the initial benzene concentration (0.001 to 10 mg/L). More than 99.0% of benzene was removed from solution when the initial benzene concentration ranged from 1 to 10 mg/L. From results of fitting process for batch experimental data to Langmuir and Freundlich isotherms, the removal isotherms of benzene were more well fitted to Freundlich model ($r^2$=0.9242) rather than Langmuir model ($r^2$=0.7453). From the column experiment, the benzene removal efficiency maintained over 99.0% until 420 pore volumes of benzene solution (initial benzene concentration: 1 mg/L) were injected in the column packed with bio-carriers, investigating that the immobilized carrier containing Bacillus drentensis sp. and polysulfone is the outstanding biosorbent to remove benzene in solution.

A Colorimetric Glucose Assay via Concentration Gradient Paper Chip (종이기반 농도 구배 형성 칩을 통한 포도당 발색 반응 검사)

  • Kim, Taehoon H.;Shin, Hyun Young;Lee, Yun-Il;Tae, Ki-Sik;Kim, Minseok S.
    • Journal of Biomedical Engineering Research
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    • v.38 no.6
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    • pp.302-307
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    • 2017
  • This paper presents a paper-based concentration gradient chip to analyze colorimetric glucose assay. The paper-based concentration gradient chip was fabricated through a wax patterning technique that can design the fluidic channel by selectively printing hydrophobic and hydrophilic areas. Afterwards, glucose and dilution solutions were loaded into the inlet of a concentration gradient chip and each solution was then mixed sequentially at mixing channel. Finally, concentration gradient was formed at each outlet of the chip. To measure the glucose concentration of the solution in outlets, we conducted colorimetric glucose assay with fixed concentration of glucose solution (0, 5, 10, 15 and 20 mM) and obtained normalized intensity. Subsequently, glucose concentrations of the outlets were calculated by substituting the normalized intensity to linear regression function based on the normalized intensity of fixed glucose concentration. Finally, the concentration gradient of glucose was formed on the chip with the result of colorimetric assay. The concentration gradient paper chip has the potential to accurately analyze unknown glucose concentration.

A study on the PEO films on Mg alloys in aqueous solution (마그네슘 합금의 PEO 피막 형성 연구)

  • Nam, Yun-Gyeong;Mun, Seong-Mo
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.11a
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    • pp.95-95
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    • 2012
  • In this study, the effect of $PO{_4}^{3-}$ ions on formation of PEO(Plasma Electrolytic Oxidation) films was investigated in aqueous solution. A minimum concentration of $PO{_4}^{3-}$ ions was necessary for the formation of PEO film on pure Mg and arcing voltage of pure Mg decreased with increasing $PO{_4}^{3-}$ ion concentration. Immersion test to evaluate the corrosion resistance of PEO-treated pure Mg and Mg alloys were conducted in 0.5M NaCl solution.

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