• Title/Summary/Keyword: Concentration depth profile

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Sources and Distributions of Dissolved Organic Matter by Fluorescence Method in the Northeastern Pacific Ocean (북동태평양에서 형광 기법을 이용한 용존유기물의 기원 및 분포)

  • Son, Ju-Won;Son, Seung-Kyu;Ju, Se-Jong;Kim, Kyeong-Hong;Kim, Woong-Seo;Park, Yong-Chul
    • Ocean and Polar Research
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    • v.29 no.2
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    • pp.87-99
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    • 2007
  • This study was conducted to understand the source and behavior of organic matter using the fluorescent technique (excitation-emission matrix) as a part of environmental monitoring program in the Korea manganese nodule mining site in the Northeastern Pacific Ocean. Water samples were collected at $0^{\circ},\;6^{\circ}N$, and $10.5^{\circ}N$ along $131.5^{\circ}W$ in August 2005. The concentration of total organic carbon (TOC) ranged from 58.01 to $171.93\;{\mu}M-C$. The vertical distribution of TOC was characterized as higher in the surface layer and decreased with depth. At $6^{\circ}N$, depth-integrated (from surface to 200 m depth) TOC was $337.1\;gC/m^2$, which was 1.4 times higher value than other stations. The exponential decay curve fit of vertical profile of TOC indicated that 59% of organic carbon produced by primary production in the surface layer could be decomposed by bacteria in the water column. Dissolved organic matter is generally classified into two distinctive groups based on their fluorescence characteristics using three-dimensional excitation/emission (Ex/Em) fluorescence mapping technique. One is known as biomacromolecule (BM; protein-like substance; showing max. at Ex 280/Em 330), mainly originated from biological metabolism. The other is geomacromolecule (GM; humic-like substance; showing max. at Ex 330/Em 430), mainly originated from microbial degradation processes. The concentration of BM and GM was from 0.42 to 7.29 TU (tryptophan unit) and from 0.06 to 1.81 QSU (quinine sulfate unit), respectively. The vertical distribution of BM was similar to that of TOC as high in the surface and decreased with depth. However, the vertical distribution of GM showed the reverse pattern of that of BM. From these results, it appeared that BM occupied a major part of TOC and was rapidly consumed by bacteria in the surface layer. GM was mainly transformed from BM by microbial processes and was a dominant component of TOC in the deep-sea layer.

Distributions of 137Cs and 90Sr in the Soil of Uljin, South Korea (울진토양에서의 137Cs 및 90Sr 분포)

  • Song, JiYeon;Kim, Wan;Maeng, Seongjin;Lee, Sang Hoon
    • Journal of Radiation Protection and Research
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    • v.41 no.1
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    • pp.49-55
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    • 2016
  • Background: For the purpose of baseline data collection and enhancement of environmental monitoring the distribution studies of $^{137}Cs$ and $^{90}Sr$ in the soil of Uljin province was performed and the relation between surface soil activities and soil properties (pH, TOC and median of the surface soil) was analyzed. Materials and Methods: For 14 spots within 10 km from the NPP surface soil samples were collected and soils for depth profile were sampled for 3 spots in April 2011. Using ${\gamma}$-ray spectrometry with HPGe detector, the concentrations of $^{137}Cs$ were determined and the concentrations of $^{90}Sr$ were measured by counting ${\beta}$-activity of $^{90}Y$ (in equilibrium with $^{90}Sr$) in a gas flow proportional counter. Results and Discussion: The concentration ranges of $^{137}Cs$ and $^{90}Sr$ were $<0.479-39.6Bq{\cdot}(kg-dry)^{-1}$ (avg. $7.51Bq{\cdot}(kg-dry)^{-1}$) and $0.209-1.85Bq{\cdot}(kg-dry)^{-1}$ (avg. $0.74Bq{\cdot}(kg-dry)^{-1}$) which were similar to the reported values from other regions in Korea. The activity ratio of $^{137}Cs$ to $^{90}Sr$ in surface soils was around 9.67, which is much bigger than the initial value of 1.75 for worldwide fallouts because of faster downward movement of $^{90}Sr$ after fallout than that of $^{137}Cs$. For depth profile studies soils were collected down to 40 cm depth for the locations of Deokgu, Hujeong and Maehwa. The $^{137}Cs$ concentration distribution of the first two showed maximum values at top soils and decreased rapidly in exponential manner, while $^{90}Sr$ showed two local maximum values for soils near top and about 30 cm depth. Through linear fittings between the $^{137}Cs$ and $^{90}Sr$ concentrations of surface soil and pH, TOC and median of the surface soil, the only probable relationship obtained was between $^{137}Cs$ and TOC (determination coefficient $R^2=0.6$). Conclusion: The concentration ranges of $^{137}Cs$ and $^{90}Sr$ in Uljin were similar to the reported values from other regions in Korea. The only probable relationship obtained between activities and soil properties was between $^{137}Cs$ and TOC.

Optimization of Analytical Condition for Reliable and Accurate Measurement of Carbon Concentration in Carburized Steel by EPMA (EPMA를 이용한 침탄강의 정확하고 신뢰성 있는 탄소농도 측정을 위한 분석조건 최적화)

  • Gi-Hoon Kwon;Hyunjun Park;Byoungho Choi;Young-Kook Lee;Kyoungil Moon
    • Korean Journal of Materials Research
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    • v.33 no.3
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    • pp.106-114
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    • 2023
  • The carbon concentration in the carburized steels was measured by electron probe microanalysis (EPMA) for a range of soluted carbon content in austenite from 0.1 to 1.2 wt%. This study demonstrates the problems in carbon quantitative analysis using the existing calibration curve derived from pure iron (0.008 wt%C) and graphite (99.98 wt%C) as standard specimens. In order to derive an improved calibration curve, carbon homogenization treatment was performed to produce a uniform Kα intensity in selected standard samples (AISI 8620, AISI 4140, AISI 1065, AISI 52100 steel). The trend of detection intensity was identified according to the analysis condition, such as accelerating voltage (10, 15, 30 keV), and beam current (20, 50 nA). The appropriate analysis conditions (15 keV, 20 nA) were derived. When the carbon concentration depth profile of the carburized specimen was measured for a short carburizing time using the improved calibration curve, it proved to be a more reliable and accurate analysis method compared to the conventional analysis method.

Occurrence of butyltin compounds in marine environment of Gwangyang Bay, Korea

  • Park, Hee-Gu;Kim, Sang-Soo;Moon, Hyo-Bang;Gu, Bon-Kyu
    • Journal of Environmental Science International
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    • v.11 no.8
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    • pp.793-800
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    • 2002
  • Butyltin (BT) compounds were measured in seawater, sediment, sediment core, settling solids, and plankton from Gwangyang Bay in 2001, Tributyltin (TBT) was detected in seawater from 1 out of the 7 seawater sampling sites and in sediment from 18 out of the 35 sediment sampling sites. The highest concentration of TBT was found in the sediment from the site near Yeosu Harbor (53 ng Sn/g dry wt), acting as the point source for TBT The mean concentrations of TBT were in the order of plankton> settling solids> sediment. The degradation indexes ([DBT]+[MBT]/[TBT]) for the plankton were less than 1, indicating the possibility of recent inputs of TBT. The indexes for the sediment and settling solids ranged from 1.14 to 8.73. The composition of the BT compounds found in the settling solids was similar to that found in the sediment. The vertical profile of the total BT compounds in the sediment was characterized by an abrupt decline from the surface. However, no butyltin compounds appeared below a depth of 10 cm, corresponding to the 1980s. Accordingly, the current results demonstrated that the levels of all butyltin species in the environment of Gwangyang Bay were relatively lower than those in other polluted coastal areas. The vertical profile also suggested a fairly recent history for the down-core.

The Effects of Copper Source and Concentration on Lipid Metabolism in Growing and Finishing Angus Steers

  • Johnson, L.R.;Engle, T.E.
    • Asian-Australasian Journal of Animal Sciences
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    • v.16 no.8
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    • pp.1131-1136
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    • 2003
  • Forty-eight individually fed Angus steers (body weight $220kg{\pm}9.1$) were utilized to investigate the effects of copper (Cu) source and concentration on lipid metabolism and carcass quality. Steers were stratified by body weight and initial liver Cu concentration and randomly assigned to one of five groups. Groups were then randomly assigned to treatments. Treatments consisted of: 1) control (no supplemental Cu); 2) 10 mg Cu/kg DM from $CuSO_4$; 3) 10 mg Cu/kg DM from a Cu amino acid complex (Availa Cu) 4) 20 mg Cu/kg DM from $CuSO_4$; and 5) 20 mg Cu/kg DM from Availa Cu. Steers were fed a corn-alfalfa-based growing diet for 56 d. Steers were then switched to a high concentrate finishing diet for 145 d. On day 74 of the finishing phase subcutaneous adipose tissue biopsies were obtained from three steers/treatment to determine basal and stimulated lipolytic rates in vitro. Steers were then slaughtered after receiving the finishing diet for 145 d. Control steers tended (p<0.12) to have lower ceruloplasmin (Cp) activity than Cu supplemented steers. Steers receiving 20 mg Cu/kg DM from Availa Cu had higher (p<0.03) Cp activity than steers receiving 20 mg Cu/kg DM from $CuSO_4$. Plasma non-esterified fatty acids were similar across treatments. Steers receiving 10 mg Cu/kg DM from Availa Cu had higher (p<0.02) total plasma cholesterol concentrations relative to steers receiving 10 mg Cu/kg DM from $CuSO_4$. Steers receiving 20 mg Cu/kg DM from Availa Cu had lower (p<0.03) plasma triglyceride concentrations than steers supplemented with 20 mg Cu/kg DM from $CuSO_4$. Fatty acid profile of longissimus muscle was similar across treatments. Backfat depth tended (p<0.18) to be lower in Cu supplemented steers relative to controls. Steers supplemented with 20 mg Cu/kg DM from Availa Cu had heavier (p<0.03) hot carcass weights and a greater (p<0.02) dressing percentage than steers supplemented with 20 mg Cu/kg DM from $CuSO_4$. Furthermore, in vitro basal (p<0.06) and epinephrine stimulated (p<0.04) lipolytic rates of subcutaneous adipose tissue were higher in Cu supplemented steers relative to controls. The results of this study suggest that Cu supplementation has minimal effects on blood and lean tissue lipid profile. However, it appears that Cu may play a role in lipid metabolism in subcutaneous adipose tissue.

Evaluation of Chloride Extraction under Electrochemical Chloride Extraction (전기화학적 염화물 추출법에 따른 염소이온 제거 성능 평가)

  • Jiseok, Kim;Ki-Yong, Ann
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.553-557
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    • 2022
  • The present study evaluate the chloride extracion under electrochemical chloride extraction method. Chloride was penetrated into the concrete from external reservoir using a 4M NaCl solution, and an electrochemical chloride extraction method was applied after the curing period of 1 year. The current density was constantly kept 1000 mA/m2 for coulostatic application with the variation in potential difference. The duration of the ECE treatment was 2, 4, 8 weeks, respectively. The residual chloride concentration at all depths decreased, and the chloride concentration decreased as the application period increased. After the application period of 8 weeks, 62.9 to 77.6 % of chloride extracted in the total chloride profile, and 77.7 to 99.5 % of chloride extracted in the free chloride profile. In particular, the concentration of free chloride at a depth of 7 mm or more from the concrete surface was 0.01 % or less by cement. In addition, it was confirmed that the bound chloride could be extracted by the electrochemical chloride extraction.

Optimization of 1.2 kV 4H-SiC MOSFETs with Vertical Variation Doping Structure (Vertical Variation Doping 구조를 도입한 1.2 kV 4H-SiC MOSFET 최적화)

  • Ye-Jin Kim;Seung-Hyun Park;Tae-Hee Lee;Ji-Soo Choi;Se-Rim Park;Geon-Hee Lee;Jong-Min Oh;Weon Ho Shin;Sang-Mo Koo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.3
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    • pp.332-336
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    • 2024
  • High-energy bandgap material silicon carbide (SiC) is gaining attention as a next-generation power semiconductor material, and in particular, SiC-based MOSFETs are developed as representative power semiconductors to increase the breakdown voltage (BV) of conventional planar structures. However, as the size of SJ (Super Junction) MOSFET devices decreases and the depth of pillars increases, it becomes challenging to uniformly form the doping concentration of pillars. Therefore, a structure with different doping concentrations segmented within the pillar is being researched. Using Silvaco TCAD simulation, a SJ VVD (vertical variation doping profile) MOSFET with three different doping concentrations in the pillar was studied. Simulations were conducted for the width of the pillar and the doping concentration of N-epi, revealing that as the width of the pillar increases, the depletion region widens, leading to an increase in on-specific resistance (Ron,sp) and breakdown voltage (BV). Additionally, as the doping concentration of N-epi increases, the number of carriers increases, and the depletion region narrows, resulting in a decrease in Ron,sp and BV. The optimized SJ VVD MOSFET exhibits a very high figure of merit (BFOM) of 13,400 KW/cm2, indicating excellent performance characteristics and suggesting its potential as a next-generation highperformance power device suitable for practical applications.

Bacterial Community of Free-living and Aggregated Bacteria at Thawing Period in Lake Baikal (해빙기 바이칼호에서 부유세균과 Aggregates에 부착한 세균의 군집구조)

  • 홍선희;김옥선;전선옥;유재준;안태석
    • Korean Journal of Microbiology
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    • v.38 no.3
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    • pp.192-197
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    • 2002
  • Fluorescent in situ hybridization (FISH) with rRNA-targeted oligonucleotide probes was used to compare the community structures of free-living and aggregated bacteria at thawing period in Lake Baikal. Targeted groups were Eubacteria, $\alpha$-, $\beta$-, $\gamma$- proteobacteria groups, Cytophaga-Flavobacterium group and Planctomycetales. Total bacterial numbers of free-living bacteria were ranged from $0.2{\times}10^6\cells{\cdot}ml^-1$ to $3.2{\times}10^6\cells{\cdot}ml^-1$, which were decreasing with depth, while the aggregated bacterial numbers were dramatically increasing from $0.4{\times}10^4 to 3.3{\times}10^4 \cells{\cdot}ml^-1$ with depth. The ratios of EUB probe binding cells to DAPI counts were ranged from 52.3 to 74.1% in free-living bacteria, and from 39.6 to 66.7% in the aggregated bacteria, respectively. Community structures of the aggregated bacteria were very different from each free-living bacteria at every depth. At 25 m depth, where the chlorophyll a concentration was highest, both structures were quite different from those of surface layers, rendering the fact that the community structures might be affected by phytoplankton. The vertical profile of community structure of aggregated bacteria is particular. The proportion of $\beta$-proteobacteria group was increasing with depth and it was 51.8% at 100 m, but the dominant group was $\gamma$-pro-teobacteria group at 250 m. Taken together, the biodiversity and succession of aggregated bacteria are quite different from free-living bacteria.

Diffusion characterization of Doped Oxide and Nitride Film (도핑한 산화막 및 질화막의 확산특성)

  • 이종덕;김원찬
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.22 no.2
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    • pp.97-105
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    • 1985
  • Phosphorus and boron diffusion from doped PECVD oxide films into silicon have been studied. CVD PSG was also prepared to parallelly compare the diffusion characteristics of CVD PSG with that in PECVD PSG, The phosphorus diffusion experiments were performed in N2 and O2 ambient at the temperatures of 100$0^{\circ}C$, 105$0^{\circ}C$ and 110$0^{\circ}C$ The parameters of boron diffusion have been investigated from the doped film prepared by changing B2 H6 flow rate and deposition temperature. The diffusivities and diffusion profiles of the dopant into silicon were calculated by applying Barry's model using the measured parameters such as diffusion depth and surface concentration.

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A study on transparent conducting films for GaN-based light emitting diodes (GaN-LED용 투명전도막에 대한 연구)

  • Lee, Kang-Young;Kim, Won;Uhm, Hyun-Seok;Kim, Eun-Kyu;Kim, Myun-Sung;Park, Jin-Seok
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1270-1271
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    • 2008
  • Effects of thin ZnO/Mg interlayers on electrical and optical properties between p-GaN and ITO were characterized for its application to GaN-LEDs. The ZnO and Mg layers were deposited to have various thicknesses (1${\sim}$6nm for ZnO and 1${\sim}$2nm for Mg) by sputtering. After RTA process, the atomic migration between Mg and ZnO and the formation of Ga vacancy were observed from SIMS depth profile, resulting in the increase of hole concentration and the reduction of band bending at the surface region of p-GaN. The sample using ZnO(2nm)/Mg(2nm) interlayer produced the lowest contact resistance with SBH(Schottky barrier height) of 0.576 eV and the transmittance higher than 83% at a wavelength of 460nm when annealed at 500$^{\circ}C$ for 3min in air ambient.

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