• Title/Summary/Keyword: Concentration and Dispersion

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Synthesis and Characterization of Graphene Based Unsaturated Polyester Resin Composites

  • Swain, Sarojini
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.2
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    • pp.53-58
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    • 2013
  • Graphene-based polymer nanocomposites are very promising candidates for new high-performance materials that offer improved mechanical, barrier, thermal and electrical properties. Herein, an approach is presented to improve the mechanical, thermal and electrical properties of unsaturated polyester resin (UPR) by using graphene nano sheets (GNS). The extent of dispersion of GNS into the polymer matrix was also observed by using the scanning electron microscopy (SEM) which indicated homogeneous dispersion of GNS through the UPR matrix and strong interfacial adhesion between the GNS and UPR matrix were achieved in the UPR composite, which enhanced the mechanical properties. The tensile strength of the nanocomposites improved at a tune of 52% at a GNS concentration of 0.05%. Again the flexural strength also increased around 92% at a GNS concentration of 0.05%. Similarly the thermal properties and the electrical properties for the nanocomposites were also improved as evidenced from the differential scanning caloriemetry (DSC) and dielectric strength measurement.

Effects of Surfactant and Preplate Process on Electroless Copper Plating on Carbon Nano-fiber (탄소나노섬유 표면 구리 무전해 도금에 미치는 분산제와 도금 전처리의 영향)

  • Han, Jun-Hyun;Seok, Hyun-Kwang;Lee, Sang-Soo;Jee, Kwang-Koo
    • Journal of Powder Materials
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    • v.16 no.2
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    • pp.131-137
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    • 2009
  • This paper deals with the effects of the surfactant and preplate process (sensitization and activation) on electroless copper plating on carbon nano-fiber (CNF). Ultrasonic irradiation was applied both during dispersion of CNF and during electroless plating containing preplate process. The dispersion of CNF and flatness of the plated copper film were discussed based on the changes in surfactant concentration and preplate process time. It was clearly shown that high concentration of surfactant and long time of preplate process could promote the agglomeration of CNF and uneven copper plating on CNF.

A Numerical Study on Fuel Concentration Distribution in a FBC (유동층 연소로내 연료농도분포의 수치적 연구)

  • Lee, D.I;Park, S.H.;Shin, D.S.
    • Journal of the Korean Society of Combustion
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    • v.3 no.1
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    • pp.41-48
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    • 1998
  • A numerical study on combustion in a fluidized bed is based on three dimensional mixing and dispersion phenomena in the bed owing to the bubble growth in the vertical direction. As fluidizing velocities increase, bubble diameters increase, which activates the fuel dispersion in the bed. The combustion rates, however, reduce due to the decrease of gas exchange rates between bubble and emulsion phases. Fuel distributions in the bed are dependent on fluidizing velocities, equivalence ratios, fuel particle diameters, fuel feeding points, and the number of fuel feeders.

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Modeling approach in mapping groundwater vulnerability

  • Im Jeong-Won;Bae Gwang-Ok;Lee Gang-Geun;Seok Hui-Jun
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.304-307
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    • 2005
  • A numerical modelling method using a backward-in-time advection dispersion equation is introduced in assessing the vulnerability of groundwater to contaminants as an alternative to classical vulnerability mapping methods. The flux and resident concentration measurements are normalized by the total contaminants mass released to the system to provide the travel time probability density function and the location probability function. With the results one can predict the expected travel time of a contaminant from up stream location to a well and also the relative concentration of the contaminant at a well. More specific groundwater vulnerability can be mapped by these predicted measurements.

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Surface Chemical Properties of Surface Active Aminocyclitol Derivatives (계면활성(界面活性) 아미노싸이클리톨 유도체(誘導體)의 계면화학적(界面化學的) 성질(性質))

  • Sohn, Joo-Hwan;Lee, Chang-Sup
    • Journal of the Korean Applied Science and Technology
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    • v.4 no.1
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    • pp.45-52
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    • 1987
  • Surface chemical properties including surface tension, Ross-Miles foaming power, foam stabilities, emulsifying properties, emulsion stabilities, effectiveness of dispersion, dispersion stabilites of the quaternary ammonium salt type deoxyaminoimositol derivatives such as sixteen kinds of dimethylafkyl-deoxyscyllo-inosityl- dimethylalkyl-2-deoxy-2-myo-inosityl-, dimethylakyl-2-deoxy-2-epi-inosityl- and dimethylalkyl-4-deoxy-4-myo-inosityl ammonium chlorides are tested. And critical micelle concentration of these compounds are estimated from the curves of surface tension and concentration. The experimental results show that the members of this class of compounds have necessary surface active properties to make them effective surfactants.

Effect of associating polymer on the dispersion stability and rheology of suspensions

  • Otsubo, Yasufumi;Horigome, Misao
    • Korea-Australia Rheology Journal
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    • v.15 no.1
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    • pp.27-33
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    • 2003
  • Associating polymers are hydrophilic long-chain molecules to which a small amount of hydrophobic groups (hydrophobes) is incorporated. In aqueous solution, the association interactions result in the formation of three-dimensional network through flowerlike micelles at high concentrations. In colloidal suspensions, the associating polymers act as flocculated by bridging mechanism. The rheological properties of suspensions flocculated by associating polymers end-capped with hydrophobes are studied in relation to the bridging conformation. At low polymer concentrations, the polymer chains effectively form bridges between particles by multichain association. The suspensions are highly flocculated and show typical viscoelastic responses. When the polymer concentration is increased above the absorbance at saturation, the excess polymer chains remaining in the solution phase build up three-dimensional network by associating interactions. Since the presence of particles does not significantly influence the network structures in the medium, the relative viscosity, which gives a measure of the degree of flocculation is decreased with increasing polymer concentration. The bridging conformation and flocculation level vary strongly depending on the polymer concentrations.

Modeling and analysis of an LDPE autoclave reactor with axial dispersion

  • Park, Seung-Koo;Wi, Jeong-Ho;Rhee, Hyun-Ku
    • 제어로봇시스템학회:학술대회논문집
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    • 1991.10b
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    • pp.1693-1698
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    • 1991
  • An axial dispersion model is developed for the slim reactor employed in the LDPE autoclave process so that imperfect mixing caused by large L/D ratio (10-20) may be quantified by Peclet number. The model is then used to investigate the effect of mixing on the reactor performance represented by the monomer conversion, the reactor temperature, the molecular weight, and the polydispersity. In addition, the existence of steady state multiplicity is identified with the initiator feed concentration or the feed temperature as the bifurcation parameter. The effects of the initiator feed concentration and the feed temperature are also examined.

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Sensitivity Analysis of Parameters in a Depth Averaged Two-Dimensional Sediment Transport Model (수심적분 2차원 유사이동모형에 관계된 인자들의 민감도분석에 관한 연구)

  • Seo, Sang-Won;Yun, Byeong-Man
    • Journal of Korea Water Resources Association
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    • v.31 no.1
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    • pp.115-120
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    • 1998
  • In this paper, a depth-averaged two-dimensional transport model is introduced, and its error bound is presented as the results of sensitivity analysis. The results show that the calculated SS concentration is highly dependant on Manning roughness coefficient, mixing coefficient. fall velocity. and critical shear stress. On the other hand, water level and dispersion coefficient are proved to be less significant in the variation of SS concentration.

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Effects of Al Concentration on Structural and Optical Properties of Al-doped ZnO Thin Films

  • Kim, Min-Su;Yim, Kwang-Gug;Son, Jeong-Sik;Leem, Jae-Young
    • Bulletin of the Korean Chemical Society
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    • v.33 no.4
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    • pp.1235-1241
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    • 2012
  • Aluminium (Al)-doped zinc oxide (AZO) thin films with different Al concentrations were prepared by the solgel spin-coating method. Optical parameters such as the optical band gap, absorption coefficient, refractive index, dispersion parameter, and optical conductivity were studied in order to investigate the effects of the Al concentration on the optical properties of AZO thin films. The dispersion energy, single-oscillator energy, average oscillator wavelength, average oscillator strength, and refractive index at infinite wavelength of the AZO thin films were found to be affected by Al incorporation. The optical conductivity of the AZO thin films also increases with increasing photon energy.

Dispersion Polymerization of Acrylamide in Ethanol/water Media (에틸 알코올/물 혼합 용매에서 아크릴아미드의 분산 중합)

  • 이기창;이성은;송봉근
    • Polymer(Korea)
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    • v.27 no.4
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    • pp.358-363
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    • 2003
  • Dispersion polymerization of acrylamide was carried out in the media of ethyl alcohol/water mixtures using hydroxypropyl cellulose and ammonium persulfate as steric stabilizer and initiator, respectively. The effects of concentrations of initiator and steric stabilizer, amount of monomer, polymerization temperature, ethyl alcohol/water ratio, and purification of monomer and nitrogen purge on the particle size of the latices and molecular weight of the polymers were investigated. The average particle diameter increased with increasing concentration of initiator, water content in ethyl alcohol/water media, and polymerization temperature, but decreased with monomer and stabilizer concentrations. The viscosity average molecular weight increased with increasing concentrations of monomer, steric stabilizer, and water content in dispersion media, but decreased with initiator concentration and polymerization temperature. The PAM polymers prepared with the purified monomer and the nitrogen purging before the reaction showed the highest molecular weight. In this study, PAM latices of 0.5∼2.4 $\mu\textrm{m}$ with 20000∼335000 in M$\_$v/ were prepared and the resulting PAM latices were all dissolved in water instantly.