• Title/Summary/Keyword: Concentration Transition

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Temporal and Spatial Characteristics of Water Quality in a River-Reservoir (Paldang) (하천형 호수인 팔당호 수질의 시공간적 특성)

  • Kong, Dongsoo;Min, Jeong-Ki;Byeon, Myeongseop;Park, Hae Kyung;Cheon, Se-Uk
    • Journal of Korean Society on Water Environment
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    • v.34 no.5
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    • pp.470-486
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    • 2018
  • This study is to investigate the allochthonous load and water quality of a typical river-reservoir, Paldang during spring (March ~ May) of 17 years (2001 ~ 2017). Phosphorus loading from point sources seems to have been reduced by 74 % in the 2010s. As a result, trophic state of the Paldang reservoir, eutrophic during the 2000s, has returned to the lmesotrophic state. Along with decrease in phosphorus concentration, standing crops of algae (Chl.a) decreased, and concentration of biodegradable organic material decreased to the past level. Concentration of total suspended solids has decreased, and it is due to the decrease of phytoplankton standing crops since the mid-2000s. As transparency increased, it is estimated that euphotic area increased by 22 % and euphotic capacity expanded by 27 %. In the river/transition zone of Paldang, concentration of organic matter increases slightly due to algal growth, but concentration of all water quality items decreases in the lacustrine zone. Although algal growth rate revealed positive correlation with concentration of phosphorus, it was insignificant. Algal growth appeared to be dependent on renewal of phosphorus by flow, than either flow rate or phosphorus concentration. The empirical model including inflow phytoplankton concentration fit well with observed values, and indicates the Paldang reservoir is greatly influenced by allochthonous loads.

[Li]/[Nb]조성비 변화에 따른 iron-doped $LiNbO_3$ 결정의 특성분석

  • 한지웅;원종원;오근호
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1997.10a
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    • pp.111-115
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    • 1997
  • Iron-doped LiNbO$_3$ crystals were grown by floating zone(FZ) method with different [Li]/[Nb] ratio in order to investigate doping effects of transition metal impurity in LiNbO$_3$ crystal. The grown crystals were analyized edge in UV/VIS/IR spectrometry and EPMA(electron probe micro-analysis). The absorption edge in UV-VIS region and OH-absorption peak in IR region were investigated. The change of Fe concentration along the solidification direction was also investigated

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가교방법이 PVA 필름의 겔 특성에 미치는 영향

  • Gu, Gwang-Hoe;Jang, Jin-Ho
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2009.11a
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    • pp.15-16
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    • 2009
  • Poly(vinyl alcohol) was crosslinked by UV irradiation in the presence of water soluble photoinitiators. The crosslinking of PVA films with 1,2,3,4-Butanetetracarboxylic acid(BTCA) and sodium phosphinate monohydrate(SPM) was also achieved via thermal curing. Different factors in the crosslinking including thermal and radiation methods were studied. Gel fraction of PVA films increased with increasing photoinitiator concentration. The maximum gel fraction on the crosslinking method was reached about 81%. The glass transition and maximum decomposition temperature improved by both thermal and radiation crosslinking.

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Microscopic Interdiffusion in Multilayer Structure

  • Kim, Jai-Young
    • Journal of Magnetics
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    • v.2 no.2
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    • pp.58-66
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    • 1997
  • Recently, artificially modulated magnetic multilayer materials, for examples giant magnetoresistant magnetic head materials and magneto-optic recording materials in the wavelength of a blue laser beam, attract great attention in the electronics industry due to their unique properties derived from the modulated multilayer structure. Since the multilayer structure as well as amorphous structure, is non-equilibrium state in terms of free energy, an assessment of the thermal staibility in the multilayer structure is crucially importnat both for basic research and applications. In this review paper, effective microscopic interdiffusion process in the two dimensional multilayer structure will be described in terms of steep concentration gradient effect, strain effect and magnetic transition effect.

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Sodium Ion-Selective Membrane Electrode Based on Dibenzopyridino-18-Crown-6

  • Tavakkoli, Nahid
    • Bulletin of the Korean Chemical Society
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    • v.25 no.10
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    • pp.1474-1476
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    • 2004
  • A sodium ion- selective electrode based on dibenzopyridino-18-crown-6 as membrane carrier was successfully prepared. The electrode exhibits a Nernstian response for $Na^+$ ions within the concentration range of $1.0\;{\times}\;10^{-4}-1.0\;{\times}\;10^{-1}$ M. The response time of the sensor is 20 s. The sodium ion-selective electrode exhibited comparatively good selectivities with respect to alkali, alkaline earth and some transition metal ions.

The Qualitative Prediction for diffusion and transition of contaminants in the Clean Room by Numerical Flow Analysis (기류해석을 이용한 클린룸 내 오염물질의 확산경로 예측)

  • Jeong, Gi-Ho
    • Proceedings of the SAREK Conference
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    • 2007.11a
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    • pp.382-386
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    • 2007
  • In this study, the qualitative prediction and evaluation of clean room being utilized for mass production of electrronic components have been performed with the help of flow simulation. Compared to the experimental analysis based on measurements of the number of particles, concentration of contaminants and flow characteristics, the numerical analysis used in this study is much cost-effective.

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Nucleophilic Substitution Reactions of Thiophenyl Phenylacetate with Benzylamines in Acetonitrile

  • 오혁근;김선경;이익춘
    • Bulletin of the Korean Chemical Society
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    • v.20 no.9
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    • pp.1017-1020
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    • 1999
  • The aminolysis reactions of thiophenyl phenylacetates with benzylamines are investigated in acetonitrile at 55.0℃. Relatively large selectivity parameters, βx≒ 1.5, βz = -1.5~-1.8 and βxz = 0.92 together with the valid reactivity-selectivity principle are consistent with stepwise acyl transfer mechanism with rate limiting expulsion of the leaving group, thiophenolate anion, from the tetrahedral intermediate, T ± . The first order kinetics with respect to the benzylamine concentration and the realtively large secondary kinetic isotope effect (kH / kD = 1.2-1.7) involving deuterated benzylamine nucleophiles suggest a four center type transition state in which concurrent leaving group departure and proton transfer are involved.

Aminolysis of Aryl Thiol-2-furoates and Thiol-2-thiophenates in Acetonitrile

  • 오혁근;이준용;이익춘
    • Bulletin of the Korean Chemical Society
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    • v.19 no.11
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    • pp.1198-1202
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    • 1998
  • Aminolysis of aryl thiol-2-furoates and thiol-2-thiophenates with benzylainines are investigated in acetonitrile at 50.0 ℃. Relatively large selectivity parameters, ρx(βx), ρz(βx) and ρxz (> 0) together with the valid reactivity-selectivity principle are consistent with a stepwise acyl transfer mechanism with rate-limiting expulsion of the leaving group, thiophenolate anion, from the tetrahedral intermediate, T±. The first-order kinetics with respect to the benzylamine concentration and the relatively large secondary kinetic isotope effect involving deuterated benzylamine nucleophiles suggest a four-center type transition state in which concurrent leaving group departure and proton transfer are involved.

Transition of Domestic Construction Management Market Structure (국내 건설사업관리 시장의 구조적 변화 분석)

  • Yun, Ha-Jung;Kim, Ji-Sun;Lee, Yoon-Sun;Kim, Jae-Jun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.11a
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    • pp.277-278
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    • 2012
  • After the introduction of CM(construction management) for improving productability in construction industry, the CM market was shown to actively grow shape until 2007 but suddenly appears passive movement of the market after in 2008. However, on one hand, the CM corporations has increased, because the construction supervision market come to the CM market area by reduction their work place. Because of this, it was discussed that will intensify competition between companies in the CM market. Therefore, this paper want to analyze to status of the CM market structure for studying about the CM industry status and change during last 3 years. As a result, by decreasing the Market concentration, the CM market competition rate did not too high with business despite that CM market downsize and has been increased the number of companies.

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Characteristics of Propagating Tribrachial Flames in Counterflow

  • Ko, Young-Sung;Chung, Tae-Man;Chung, Suk-Ho
    • Journal of Mechanical Science and Technology
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    • v.16 no.12
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    • pp.1710-1718
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    • 2002
  • The effect of fuel concentration gradient on the propagation characteristics of tribrachial (or triple) flames has been investigated experimentally in both two-dimensional and axisymmetric counterflows. The gradient at the stoichiometric location was controlled by the equivalence ratios at the two nozzles; one of which is maintained rich, while the other lean. Results show that the displacement speed of tribrachial flames in the two-dimensional counterflow decreases with fuel concentration gradient and has much larger speed than the maximum speed predicted previously in two-dimensional mixing layers. From an analogy with premixed flame propagation, this excessively large displacement speed can be attributed to the flame propagation with respect to burnt gas. Corresponding maximum speed in the limit of small mixture fraction gradient was estimated and the curvefit of the experimental data substantiates this limiting speed. As mixture fraction gradient approaches zero, a transition occurs, such that the propagation speed of tribrachial flame approaches stoichiometric laminar burning velocity with respect to burnt gas. Similar results have been obtained for tribrachial flames propagating in axisymmetric counterflow.