• Title/Summary/Keyword: Concentration Characteristics

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Investigation on Electrochemical Characteristics of Battery Housing Material for Electric Vehicles in Solution Simulating an Acid Rain Environment with Chloride Concentrations (산성비 환경을 모사한 수용액에서 염화물 농도에 따른 전기자동차 배터리 하우징용 재료의 전기화학적 특성 연구)

  • Shin, Dong-Ho;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.21 no.2
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    • pp.147-157
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    • 2022
  • Electrochemical characteristics and damage behavior of 6061-T6 aluminum alloy used as a battery housing material for electric vehicles were investigated in solution simulating the acid rain environment with chloride concentrations. Potentiodynamic polarization test was performed to analyze electrochemical characteristics. Damage behavior was analyzed through Tafel analysis, measurement of damage area, weight loss, and surface observation. Results described that corrosion current density was increased rapidly when chloride concentration excceded 600 PPM, and it was increased about 7.7 times in the case of 1000 PPM compared with 0 PPM. Potentiodynamic polarization experiment revealed that corrosion damage area and mass loss of specimen increased with chloride concentrations. When chloride concentration was further increased, the corrosion damage area extended to the entire surface. To determine damage tendency of pitting corrosion according to chloride concentration, the ratio of damage depth to width was calculated. It was found that the damage tendency decreased with chloride concentrations. Thus, 6061-T6 aluminum alloy damage becomes larger in the width direction than in the depth direction when a small amount of chloride is contained in an acid rain environment.

Assessment and Correlation of Saline Soil Characteristics using Electrical Resistivity

  • Mustapha Maliki;Fatima Zohra Hadjadj;Nadia Laredj;Hanifi Missoum
    • Journal of Electrochemical Science and Technology
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    • v.14 no.3
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    • pp.205-214
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    • 2023
  • Soil salinity is becoming one of the most devastating environmental hazards over the years. Soil investigation involves fast, low cost and non disturbing methods to measure soil characteristics for both construction projects as well as for agricultural use. The electrical resistivity of saline soils is greatly governed by salt concentration and the presence of moisture in soil matrix. Experimental results of this investigation highlight that there is a significant relationship between the electrical resistivity of soil samples mixed with chloride solutions (NaCl, KCl, and MgCl2) at various concentrations, and soil physical properties. Correlations represented by quadratic functions were obtained between electrical resistivity and soil characteristics, namely, water content, degree of saturation and salt concentration. This research reveals that the obtained correlations between electrical resistivity, salt concentration, water content and degree of saturation are effective for predicting the characteristics of salt affected soils in practice, which constitute a governing element in the assessment of saline lands sustaining infrastructure.

The Effect of Sludge Settling Characteristics on Sludge-Water Interface Height Change Model (슬러지계면층 높이변화모델에서 슬러지 침전특성에 대한 영향)

  • Park, Suk Gyun;Kang, Seon-Hong
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.1
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    • pp.147-155
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    • 2006
  • For the further study of the solids flux theory, several researchers have proposed models to predict sludge settling velocity for each different concentration by using sludge indexes, SVI, SSVI and $SSVI_{3.5}$. It is difficult to apply the above models to predict sludge-water interface height in a batch column because sludge settling velocity changes while sludge settle down. While sludge settle down in a batch column, sludge concentration becomes high. The sludge concentration change is one of the most critical causes of the change of sludge settling velocity. Also, sludge concentration change causes of sludge index to change. SVI is more sensitive than SSVI or $SSVI_{3.5}$ to the change of sludge concentration. Each sludge has physical characteristics of its own which makes the settling velocity for each sludge different. The purpose of this study is to establish the correction factors that are able to compensate the errors derived from each different sludge settling characteristic by using sludge indexes, therefore the correction factors are applicable to the model for the change of sludge-water interface height.

An Experimental Study on the Effects of Concentration Gradient and Mean Velocity on the Liftoff Characteristics of the Triple Flame (농도구배와 평균속도가 삼지화염의 부상 특성에 미치는 영향에 관한 실험적 연구)

  • Seo, Jeong-Il;Kim, Nam-Il;Oh, Kwang-Chul;Shin, Hyun-Dong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.8
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    • pp.1061-1070
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    • 2003
  • A triple flame in a mixing layer was studied experimentally with concentration gradient and mean velocity by using a multi-slot burner, which can stabilize the lift-off flame. Flame stabilization condition, lift-off heights, and some other characteristics were examined for methane and propane flame within a range of very low concentration gradient. Pitot-tube and LDV(Laser Doppler Velocimetry) were used for velocity. Mass spectroscopy and Rayleigh scattering signal were used for concentration gradients. Thermo-couples and SiC TFP(Thin Filament Pyrometer) were used for temperature. It was found that minimum values of the lift-off heights exist at a certain concentration gradient for constant mean velocity and this means that the propagation velocity has a maximum value. The scales of flame to the burner nozzle and intensity variation of the diffusion flame were suspected as the cause.

A Study on the Mixing Characteristics in Complex Turbulent Flow by a Laser Induced Fluorescence Method (레이저 형광여기법(LIF)를 이용한 복잡 난류유동장의 혼합특성에 관한 연구)

  • Kim, Kyung-Chun;Jeong, Eun-Ho
    • Proceedings of the KSME Conference
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    • 2001.06e
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    • pp.542-547
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    • 2001
  • A non-intrusive Planar Laser-Induced Fluorescence(PLIF) technique was applied to study the turbulent mixing process in a Rushton turbine reactor. Instantaneous and ensemble averaged concentration fields are obtained by measuring the fluorescence intensity of Rhodamine B tracer excited by a thin Nd:Yag laser sheet illuminating the whole center plane of the stirred tank. The gray level images captured by a 14-bit cooled CCD camera can be transformed to the local concentration values using a calibration matrix. The dye injection point was selected at the tank wall with three quarter height (3/4H) from the tank bottom to observe the mixing characteristics in upper bulk flow region. There exist distinct two time scales: the rapid decay of mean concentration in each region after the dye infusion reflects the large scale mixing while the followed slow decay reveals the small scale mixing. The temporal change of concentration probability functions conjectures the two sequential processes in the batch type mixing. An inactive column of water existed above the impeller disk, in which the fluid rotates with the shaft but is isolated from the mean bulk flow.

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Variations of Air Quality in Kunsan, Taegu, and Pohang due to the Characteristics of Local Weather (국지 기상 특성에 따른 군산, 대구 및 포항의 대기질의 일변화)

  • 서기수;윤일희
    • Journal of Environmental Science International
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    • v.6 no.6
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    • pp.613-628
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    • 1997
  • Diurnal variations of air quality due to the characteristic features of local weather phenomena over Kunsan, Taegu, and Pohang are analyzed using various synoptic wand fields and the characteristics of local weather during the period of 1990 to 1992. The air pollutants analyzed are sulfur dioxide($SO2_$), nitrogen dioxide($NO_2$), and oxidants ($0_3$). The synoptic wind fields estimated at over the 850 hPa geopotential height are divided in terms of four wand directions and two wand speed categories for each season. The synoptic weather conditions are also classified Into two categories depending on the 850 hPa cloud amounts. The present study shows that the $SO_2$ concentration over Kunsan, and Taegu was maximum at the two or three hours after sunrise and second primary was three or flour hours after sunset. On the other hand, Its concentration over Kunsan was malnmum at 1900 LST or 2000 LST The $O_3$ concentration over the three cities shows Its mapdmum In the afternoon when the solar radiation is strong. The $NO_2$ concentration over Kansan shows in reverse proportion to the $O_3$ concentration over the Kunsan.

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A Study on the Mixing Characteristics in a Rushton Turbine Reactor by a Laser Induced Fluorescence Method (레이저 형광여기법(LIF)를 이용한 러쉬톤 터빈 교반기의 혼합특성에 관한 연구)

  • Jeong, Eun-Ho;Kim, Gyeong-Cheon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.8
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    • pp.1145-1152
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    • 2002
  • A non-intrusive Planar Laser-Induced Fluorescence(PLIF) technique was applied to study the turbulent mixing process in a Rushton turbine reactor. Instantaneous and ensemble averaged concentration fields was obtained by measuring the fluorescence intensity of Rhodamine B tracer excited by a thin Nd:Yag laser sheet illuminating the whole center plane of the stirred tank. The gray level images captured by a 14-bit cooled CCD camera could be transformed to the local concentration values using a calibration matrix. The dye injection point was selected at the tank wall with three quarter. height (3/4H) from the tank bottom to observe the mixing characteristics in upper bulk flow region. There exist distinct two time scales: the rapid decay of mean concentration after the dye infusion reflects the large scale turbulent mixing while the fellowed slow decay reveals the small scale molecular mixing. The temporal change of concentration variance field conjectures the two sequential processes for the batch type mixing. An inactive column of water is existed above the impeller disk, in which the fluid rotates with the shaft but is isolated from the mean bulk flow.

Variational Characteristics of Water Quality and Chlorophyll a Concentration in the Northern Kamak Bay. Southern Korea (가막만 북부해역의 해양환경과 식물플랑크톤 군집의 변동특성 2. 수질환경과 엽록소 a량의 변동특성)

  • 윤양호
    • Journal of Environmental Science International
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    • v.9 no.5
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    • pp.429-436
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    • 2000
  • In order to study on the variational characteristics of water quality and chlorolphyll a concentration the water samples were collected daily or three times a week during the period from April 1990 to November 1991 at Kukdong port located in the northern Kamak bay of Southern Korea I made an analysis on biological factor as chlorophyll a concentration as well as physico-chemical factors such as water temperature salinity sigma-t dissolved oxygen, nutrients (ammonia, nitrite, nitrate, phosphate, and silicate) N/P ratio and chemical oxygen demand. In Northern Kamak bay seasonal variations in physical factors such as water temperature salinity and sigma-t were very marked. On the other hand chemical factors such as nutrients concentration and COD were not so. Chemical factors, in particular silicate were influenced by input of freshwater. And the roles of silicate on the seasonal succession of phytoplankton species composition was very low. Phytoplankton biomass as measured by chlorophyll a concentration was very high all the year round and it was controlled by the combination of several factors especially of N/P ratio determined by dissolved inorganic nitrogen.

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Growth Characteristics of Acidithiobacillus thiooxidans in Different Sulfur Concentrations (황 농도에 따른 Acidithiobacillus thiooxidans의 생장 특성)

  • Lee, Eun-Young;Cho, Kyung-Suk;Ryu, Hee-Wook
    • Microbiology and Biotechnology Letters
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    • v.34 no.4
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    • pp.338-341
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    • 2006
  • The growth characteristics of sulfur-oxidizing bacteria, Acidithiobacillus thiooxidans AZ11, MET, and TAS were investigated in mineral salt media supplemented with elemental sulfur of 1$\sim$50 g $L^{-1}$. The sulfur oxidation rates of A. thiooxidans. MET and TAS increased highly with increasing sulfur concentration up to 10 g L$^{-1}$, but the rates increased slowly in sulfur concentration over 10 g L$^{-1}$. A. thiooxidans AZ11 showed the parallel increase of sulfur oxidation rate until sulfur concentration increased up to 40 g L$^{-1}$. The maximum sulfur oxidation rates (V$_{max}$) of AZl1, MET and TAS were 1.88, 1.38 and 0.43 g S L$^{-1}$ d$^{-1}$, respectively. The maximum specific growth rates (${\mu}_{max}$) of AZ11, MET, and TAS were 0.33 d$^{-1}$, 0.30 d$^{-1}$ and 0.45 d$^{-1}$, respectively. Although MET and TAS couldn't grow at sulfate concentration of 40 g L$^{-1}$, AZ11 could grow in the presence of 58 g L$^{-1}$ sulfate, the final oxidation product of elemental sulfur.

A Study on the Distribution Characteristics of Sulfur Compounds in Ambient air using Continuous Monitoring Method in Incheon Area

  • Seo, Seok-Jun;Lim, Yong-Jae;Hong, You-deok;Park, Geon-Young
    • Journal of Integrative Natural Science
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    • v.8 no.2
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    • pp.128-134
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    • 2015
  • This paper focuses on the applicability of a continuous monitoring method on trace sulfur compounds in the ambient air by TD and GC/PFPD. The target compounds for monitoring include H2S(hydrogen sulfide), Methyl mercaptan, Dimethyl Sulfide, and Dimethyl disulfide. The result of QA/QC on monitoring instruments satisfies all the standards of Odor Measurement and Analysis Method, showing that the reproductivity of the compounds by concentration is within 10%, linearity is above 0.98 of a correlation efficient, method detection limit is 0.16 ppb by MM standard, and recovery rate is over 70%. Monitoring was conducted for two years from March 2006 to February 2008. As a result of the monitoring, the average concentration of H2S was 0.08 ppb, with the maximum concentration at 16.15 ppb. The result indicates that it is reasonable to do continuous monitoring as there appears a spontaneous event of high concentration by the condition of the site during monitoring odor-causing substances. Therefore, it is suggested that the continuous monitoring method used in this paper is appropriate to identify the characteristics of sudden occurrence and concentration variations of sulfur compounds.