• Title/Summary/Keyword: Compositions

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Search for new red phosphors under NUV/blue excitation - the stimulating future for solid state lighting

  • Vaidyanathan, Sivakumar;Jeon, Duk-Young
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1350-1352
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    • 2008
  • Research on down conversion phosphor materials is the key for the development of solid state lighting (SSL). Especially finding alternative red phosphor for white LEDs based on blue or NUV LEDs are important research task. Under this view, we have synthesized a series of $Eu^{3+}$ substituted $La_2W_{2-x}Mo_xO_9$ (x = 0 ~ 2, insteps of 0.1) red phosphor and characterized by X-ray diffraction (XRD) and photoluminescence. XRD results reveal a phase transition from triclinic to cubic structure for $x\;{\geq}\;0$. All the compositions show broad charge transfer band due to charge transfer from oxygen to tungsten/molybdenum and red emission due to $Eu^{3+}$ ions. Select compositions show high red emission intensity compared to the commercial red phosphor under NUV/blue ray excitation. Hence, this candidate can be possible red emitting phosphors for white LEDs.

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Composition and Stability Study on the IR Transmitting $ZrF_4$-Based Glasses (적외선투과성 $ZrF_4$-유리의 조성과 안정성에 관한 연구)

  • 정기호
    • Journal of the Korean Ceramic Society
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    • v.27 no.3
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    • pp.430-436
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    • 1990
  • Glasses of different compositions were synthesized by substituting each component of 56ZrF4-14BaF2-6LaF3-4AlF3-20NaF(ZBLAN) with HfH4, SrF2, GdF3, InF3 and LiF3, each of similar size and chemical property with the component being substituted, respectively. The heating rate used in the DSC runs was 10K/min. All ofthe glasses exhibit glass transition temperatures of 510$\pm$10K, while crystallization temperatures vary between 625 and 720K depending upon different glass compositions. For most glasses crystallization temperatures obtained while cooled are lower than those obtained while heated, but InF3 or SrF2 containing glasses showed opposite trend. HBLAN, ZHBLAN and ZHBLANLi glasses, which were made by substituting HfH4, LiF for ZrF4 and NaF of ZBLAN respectively, showed improvement in the glass stability.

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Possible Glass Systems for Non-Pb Dielectric Layers, Barrier Rib and Sealant in PDP

  • Kim, Hyung-Sun;Jung, Byung-Hae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.391-394
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    • 2003
  • It is inevitable that reconsideration of the use of lead oxides in the electronics industry be undertaken as long as detrimental effects to the environment remain. To solve this problem, many recent studies on Pb-free compositions for PDP (plasma display panel) dielectric layers and also sealing glass compositions have been made. The present study was conducted to investigate whether the alternative systems for leadfree low firing glasses, detailed below, are available for use in PDP materials. The results suggest that low-melting phosphate glasses would be suitable as an alternative material for the Pb-based dielectric layer, sealants and barrier ribs in PDP.

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The Potential Barrier Heights and the Carrier Densities of ZnO Varistors with Various Compositions

  • Cho, Sung-Gurl;Kwak, Min-Hwan;Lee, Sang-Ki;Kim, Hyung-Sik
    • The Korean Journal of Ceramics
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    • v.4 no.1
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    • pp.37-42
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    • 1998
  • The barrier heights and carrier densities of ZnO varistors with various compositions were estimated using C-V, J-V and $\rho$-T relations. The barrier heights obtained from C-V and J-V plots were 0.73~5.98 eV and 0.25~2.70 eV, respectively. The carrier densities estimated from C-V plots were ~$10^{18}cm^{-3}$. Acceptable values of the barrier heights and the carrier densities were obtained from $\rho$-1/T curves and the capacitances at zero bias; 0.6~0.8 eV for the barrier heights and ~$10^{17}cm^{-3}$ for carrier densities. Addition of cobalt increased the barrier height and the carrier density, while chromium slightly lowered both of them.

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Effect of Frit Compositions on Properties of Lead Free Conductor and Resistor Pastes (무연계 도체 및 저항체 페이스트의 특성에 미치는 프릿트 조성의 영향)

  • Kim, Bit-Na;Youm, Mi-Rea;Koo, Bon-Keup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.335-335
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    • 2010
  • $SiO_2$, $B_2O_3$, $Al_2O_3$, CaO, MgO, $Na_2O$, $ZrO_2$, $Bi_2O_3$를 이용하여 성질이 다른 두 종류의 무연계 프릿트를 제조하여 특성을 표준화 하였고, 이들 무연계 프릿트를 이용하여 Ag계 도체 및 $RuO_2$계 저항페이스트롤 제조하여 특성에 미치는 프릿트 조성의 영향을 연구하였다. $B_2O_3$를 첨가하여 퍼짐특성이 큰 프릿트의 경우 더 우수한 페이스트 특성을 나타내었다.

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Biological Characteristics of Benzimidazole-Resistant and-Senstive Isolates of Monilinia fructicola from Peach Fruits in Korea

  • Lim, Tae-Heon;Chang, Tae-Hyun;Byeongjin Cha
    • The Plant Pathology Journal
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    • v.15 no.6
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    • pp.340-344
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    • 1999
  • Fungicide-resistant isolates of Monilinia fructicola grew readily on media amended with 0.1, 1.0, 10, 100 and $1,000\mu\textrm{g}$ a.i./ml of carendazim, benomyl, or thiophanate-methyl. However, sensitive isolates did not grow on media amended even with $0.1\mu\textrm{g}$ a.i./ml of carbendazim, $1.0\mu\textrm{g}$ a.i./ml of benomyl or thiophanate-methyl. The fitness compositions including mycelial growth on fungicide-free medium, sporulation on fungicide-free medium and pear, and virulence on pear were not different between resistant and sensitive isolates. The resistant isolates persisted carbendazim resistance during multiple subdulturing and long term storage. The competitive ability of resistant isolates obtained from peach orchards in Korea was similar to those of sensitive isolates.

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Perspectives on EFL Teachers' Responding to Students' Writing at the Semantic Level

  • Chang, Kyung-Suk
    • English Language & Literature Teaching
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    • no.3
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    • pp.185-201
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    • 1997
  • This study explores perspectives on responding to EFL students' compositions at the semantic level. In the last three decades, there has been a shift from product-oriented approach to process-oriented one to teaching writing. The shift has led to the criticism of the traditional view on teacher response. The traditional view has been under attack for its overemphasis upon form and ineffectiveness on improving student writing skill. It is also noted that research into students' reactions to the traditional teacher response has been inconclusive. The process-oriented approach, on the other hand, draws its attention to meaning and the logical development of thought as well as linguistic matters. In this context, the present study discusses what EFL teachers need to take into account in providing the semantic-level feedback on students' compositions. Firstly, teacher response to student writing is on-going; teacher feedback involves teacher intervention in the drafting process, the revision process, and the presentation of product. Secondly, in the writing conferences, the teacher provides students an opportunity to talk about writing, assistance and advice on the content/meaning of the written text, helping them expand and clarify thinking about audience(reader) and purpose.

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Performance Analysis of a Heat Pump Using Refrigerant Mixtures (I) (혼합냉매를 사용한 열펌프의 성능해석 (I))

  • Won, S.P.;Kim, M.S.;Kim, T.S.;Ro, S.T.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.2 no.2
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    • pp.142-154
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    • 1990
  • A theoretical cycle analysis has been performed for a basic heat pump, charged with non-azeotropic refrigerant mixtures, R22/R114 and R13B1/R152a. At first, a procedure is introduced to calculate thermodynamic properties simply and correctly, and the advantages of using refrigerant mixtures are discussed through the cycle analysis. It is shown that by using refrigerant mixtures in the heat pump, several improvements can be made. In comparison with conventional pure refrigerants, the application of refrigerant mixtures results in high reliabilities caused by the extension of the application limit, energetic improvements, and a continuous capacity control. From generalizing various results, the optimum compositions in refrigerant mixtures are also determined. The 30%/70% and 40%/60% compositions are selected for R22/R114 and R13B1/R152a, respectively.

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Analysis of the Irradiated Nuclear Fuel Using the Heavy Atom and Neodynium Isotope Correlations with Burnup

  • Kim, Jung-Suk
    • Nuclear Engineering and Technology
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    • v.29 no.4
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    • pp.327-335
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    • 1997
  • The correlation of isotope composition of uranium, plutonium and neodymium with the burnup in M uranium dioxide fuel has been investigated experimentally. The total and fractional($^{235}$ U) burnup were determined by Nd-148 and, U and Pu mass spectrometric method respectively. The isotope compositions of these elements, after their separation from the fuel samples were measured by mass spectrometric. The content of the elements in the irradiated fuel ore determined by isotope dilution mass spectrometric method using $^{233}$ U, $^{242}$ Pu and $^{150}$ Nd as spikes. The content of plutonium in the irradiated fuel was expressed by the correlation with uranium isotopes. The correlations between isotope compositions themselves and the total and fractional burnup ore compared with those calculated from ORIGEN2 code.

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Trace Element and Mineral Chemistry of the Cretaceous Granites in the Southern Mungyeong Area (문경남부일대(聞慶南部一帶)에 분포(分布)하는 백악기(白堊紀) 화강암류(花崗岩類)의 미량원소(微量元素) 및 광물화학(鑛物化學))

  • Yun, Hyun Soo
    • Economic and Environmental Geology
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    • v.24 no.4
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    • pp.379-391
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    • 1991
  • The studied Cretaceous granties are widely distributed at the southern Mungyeong area in the southwestern part of Ogcheon Fold Belt. From the mineralogical and geochemical compositions, it is suggested that they show the characteristics of I-type and magnetite-series and formed under the conditions of high oxygen fugacity. The mineral chemistry of plagioclase, alkali feldspar and biotite in the granites by EMPA, was revealed as albite to oligoclase, microcline to microcline perthite and orthoclase perthite, and annite compositions, respectively. The granites have the distribution patterns of enriched LREE and depleted HREE, and show Eu negative anomalies suggesting mainly due to the feldspar fractionation in the residual magma. The geochemical data of Eu, EU/$^*Eu$, Sm and Gd suggest that the granites of the area have more abundant alkali feldspar crystallization than plagioclase. From the geochemical characteristics of Sr/Ba, La/Sm vs. Ce/Yb and other trace element evidences, the granites were the late stage products of differentiation and fractionated from a homogeneous parental granitic magma.

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