• 한국분말재료학회지
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• 제27권3호
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• pp.193-197
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• 2020

Porous Cu-14 wt% Co with aligned pores is produced by a freeze drying and sintering process. Unidirectional freezing of camphene slurry with CuO-Co₃O₄ powders is conducted, and pores in the frozen specimens are generated by sublimation of the camphene crystals. The dried bodies are hydrogen-reduced at 500℃ and sintered at 800℃ for 1 h. The reduction behavior of the CuO-Co₃O₄ powder mixture is analyzed using a temperature-programmed reduction method in an Ar-10% H₂ atmosphere. The sintered bodies show large and aligned parallel pores in the camphene growth direction. In addition, small pores are distributed around the internal walls of the large pores. The size and fraction of the pores decrease as the amount of solid powder added to the slurry increases. The change in pore characteristics according to the amount of the mixed powder is interpreted to be due to the rearrangement and accumulation behavior of the solid particles in the freezing process of the slurry.

• 한국분말재료학회지
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• 제27권3호
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• pp.247-255
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• 2020

Recently, interest in technology for eco-friendly energy harvesting has been increasing. Polyvinylidene fluoride (PVDF) is one of the most fascinating materials that has been used in energy harvesting technology as well as micro-filters by utilizing an electrostatic effect. To enhance the performance of the electrostatic effect-based nanogenerator, most studies have focused on enlarging the contact surface area of the pair of materials with different triboelectric series. For this reason, one-dimensional nanofibers have been widely used recently. In order to realize practical energy-harvesting applications, PVDF nanofibers are modified by enlarging their contact surface area, modulating the microstructure of the surface, and maximizing the fraction of the ν-phase by incorporating additives or forming composites with inorganic nanoparticles. Among them, nanocomposite structures incorporating various nanoparticles have been widely investigated to increase the β-phase through strong hydrogen bonding or ion-dipole interactions with -CF₂/CH₂- of PVDF as well as to enhance the mechanical strength. In this study, we report the recent advances in the nanocomposite structure of PVDF nanofibers and inorganic nanopowders.

• Composites Research
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• 제26권3호
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• pp.160-164
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• 2013

In this study, the effect of phosphoric acid (PA) as a fiber spinning aid on the strength increase of polyacrylonitrile (PAN) nano-fibers by using modified mechano-electrospinning technologies has been analyzed. The medium carbonization temperature of $800^{\circ}C$ has been selected for the future economic production of these new materials. The concentration of PAN in dimethyl sulfoxide (DMSO) was fixed as 5 wt%. The weight fraction of PA was selected as being 2%, 4%, 6%, and 8% in comparison to PAN. These solutions have been used to make the nanofibers. The mechano-electrospinning apparatus installed in KRICT was made by our own design. By using this apparatus the continous and highly aligned precursor nano-fibers have been obtained. The bundle of 50 well aligned nano diameter continuous fibers with the diametr of 10 microns with 6 wt% phosphoric acid for addition showed maximum mechanical properties of 1.6 GPa as tensile strength and 300 GPa as Young's modulus. The weight of final product can be increased 19%, which can improve the economical benefits for the application of these new materials.

• 한국세라믹학회지
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• 제55권5호
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• pp.461-472
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• 2018

$Gd_2O_3:Eu/Bi$ nanoparticles were synthesized via spray pyrolysis and applied for the preparation of a luminescent pearl pigment as an anti-counterfeiting material. The luminescence properties were optimized by changing the $Eu^{3+}$ and $Bi^{3+}$ concentration. Ethylene glycol was used as an organic additive to prepare the $Gd_2O_3:Eu/Bi$ nanoparticles. The highest emission intensity was achieved when the total dopant content was 10.0 at.% and the mole fraction of Bi was 0.1. The concentration quenching was mainly due to dipole-dipole interactions between the same activators, and the critical distances were 9.0 and $19.6{\AA}$ for $Eu^{3+}$ and $Bi^{3+}$, respectively. The prepared $Gd_2O_3:Eu/Bi$ powder exhibited an average size of approximately 82.5 nm and a narrow size distribution. Finally, the $Gd_2O_3:Eu/Bi$ nanophosphor coated on the surface of the pearl pigment was confirmed to have good red emission under irradiation from a portable ultraviolet light-emitting diode lamp (365 nm).

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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• pp.60-60
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• 2008

We manufactured Liquid Crystal Polymer (LCP) and (1-x)$BaTiO_3-xSrTiO_3$(BST) ceramic composites and investigated dielectric properties to use as embedded capacitor in printed circuit boards and replace LTCC substrates. The dielectric properties of these composites are varied with volume fraction of BST and ratios of BT/ST. Dielectric constants are in the range of 3~28. In addition, we could get low TCC and High Q value that could not achieve in other ceramic-polymer composites. Especially, in composite with x=0.4 and 50vol% BST, the dieletric constant and Q-value are 27 and 300, respectively. And more TCC is -116~145ppm/$^{\circ}C$ in the temperature range of -55~$125^{\circ}C$. We think that this composites can be used high-Q substrate material like LTCC and embedded temperature compensation capacitor in printed circuit boards.

• Steel and Composite Structures
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• 제20권1호
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• pp.205-225
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• 2016

In this study the finite element method is utilized to predict the deflection and vibration characteristics of rectangular plates made of saturated porous functionally graded materials (PFGM) within the framework of the third order shear deformation plate theory. Material properties of PFGM plate are supposed to vary continuously along the thickness direction according to the power-law form and the porous plate is assumed of the form where pores are saturated with fluid. Various edge conditions of the plate are analyzed. The governing equations of motion are derived through energy method, using calculus of variations while the finite element model is derived based on the constitutive equation of the porous material. According to the numerical results, it is revealed that the proposed modeling and finite element approach can provide accurate deflection and frequency results of the PFGM plates as compared to the previously published results in literature. The detailed mathematical derivations are presented and numerical investigations are performed while the emphasis is placed on investigating the effect of the several parameters such as porosity volume fraction, material distribution profile, mode number and boundary conditions on the natural frequencies and deflection of the PFGM plates in detail. It is explicitly shown that the deflection and vibration behaviour of porous FGM plates are significantly influenced by these effects. Numerical results are presented to serve as benchmarks for future analyses of FGM plates with porosity phases.

• Steel and Composite Structures
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• 제22권3호
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• pp.691-712
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• 2016

In this editorial, buckling analytical investigation of the nanocomposite plate with square cut out reinforced by carbon nanotubes (CNTs) surrounded by Pasternak foundation is considered. The plate is presumed has square cut out in center and resting on Pasternak foundation. CNTs are used as amplifier in plate for diverse distribution, such as uniform distribution (UD) and three patterns of functionally graded (FG) distribution types of CNTs (FG-X, FG-A and FG-O). Moreover, the effective mechanical properties of nanocomposite plate are calculated from the rule of mixture. Domain decomposition method and orthogonal polynomials are applied in order to define the shape function of nanocomposite plate with square cut out. Finally, Rayleigh-Ritz energy method is used to obtain critical buckling load of system. A detailed parametric study is conducted to explicit the effects of the dimensions of plate, length of square cut out, different distribution of CNTs, elastic medium and volume fraction of CNTs. It is found from results that increase the dimensions of plate and length of square cut out have negative impact on buckling behavior of system but considering CNTs in plate has positive influence.

• Steel and Composite Structures
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• 제17권2호
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• pp.173-184
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• 2014

This study aimed to theoretical calculate the thermal residual stress in continuous SiC fiber reinforced titanium matrix composites. The analytical solution of residual stress field distribution was obtained by using coaxial cylinder model, and the numerical solution was obtained by using finite element model (FEM). Both of the above models were compared and the thermal residual stress was analyzed in the axial, hoop, radial direction. The results indicated that both the two models were feasible to theoretical calculate the thermal residual stress in continuous SiC fiber reinforced titanium matrix composites, because the deviations between the theoretical calculation results and the test results were less than 8%. In the titanium matrix composites, along with the increment of the SiC fiber volume fraction, the longitudinal property was improved, while the equivalent residual stress was not significantly changed, keeping the intensity around 600 MPa. There was a pronounced reduction of the radial residual stress in the titanium matrix composites when there was carbon coating on the surface of the SiC fiber, because carbon coating could effectively reduce the coefficient of thermal expansion mismatch between the fiber and the titanium matrix, meanwhile, the consumption of carbon coating could protect SiC fibers effectively, so as to ensure the high-performance of the composites. The support of design and optimization of composites was provided though theoretical calculation and analysis of residual stress.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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• pp.232-233
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• 2007

We manufactured Liquid Crystal Polymer (LCP) and (1-x)CaTiO3-xLaAlO3 (CT-LA) ceramic composites and investigated dielectric properties to use as embedded capacitor in printed circuit boards and replace LTCC substrate. The dielectric properties of these composites are varied with volume fraction of CT-LA and ratios of CT/LA. Dielectric constants are in the range of 3~15. In addition, we could get low TCC and High Q value that could not achieve in other ceramic-polymer composites. Especially, in composite with x=0.01 and 30 vol% CT-LA, the dieletric constant and Q-value are 10 and 200, respectively. And more TCC is $-28{\sim}300ppm/^{\circ}C$ in the temperature range of $-55{\sim}125^{\circ}C$. We think that this composites can be used high-Q substrate material like LTCC and embedded temperature compensation capacitor in printed circuit boards.

• Journal of the Korean Wood Science and Technology
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• 제45권2호
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• pp.182-194
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• 2017

The optimum alkali pretreatment parameters (reaction time, reaction temperature and potassium hydroxide concentration) for facilitate the conversion into fermentable sugar (glucose) from steam exploded (severity log Ro 2.45) barley husk were determined using Response Surface Methodology (RSM) based on a factorial Central Composite Design (CCD). The prediction of the response was carried out by a second-order polynomial model and regression analysis revealed that more than 88% of the variation can be explained by the models. The optimum conditions for maximum cellulose content were determined to be 201 min reaction time, $124^{\circ}C$ reaction temperature and 0.9% potassium hydroxide concentration. This data shows that the actual value obtained was similar to the predicted value calculated from the model. The pretreated barley husk using acid hydrolysis resulted in a glucose conversion of 94.6%. This research of steam explosion and alkali pretreatment was a promising method to improve cellulose-rich residue for lignocellulosic biomass.