• 한국세라믹학회지
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• 제47권1호
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• pp.86-91
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• 2010

Among various fuel cells, solid oxide fuel cells (SOFCs) offer the highest energy efficiency, when taking into account the thermal recycling of waste heat at high temperature. However, the highest efficiency and lowest pollution for a SOFC can be achieved through the sophisticated control of its constituent components such as electrodes, electrolytes, interconnects and sealing materials. The electrochemical conversion efficiency of a SOFC is particularly dependent upon the performance of its electrode materials. The electrode materials should meet highly stringent requirements to optimize cell performance. In particular, both mass and charge transport should easily occur simultaneously through the electrode structure. Matter transport or charge transport is critically related to the configuration and spatial disposition of the three constituent phases of a composite electrode, which are the ionic conducting phase, electronic conducting phase, and the pores. The current work places special emphasis on the quantification of this complex microstructure of composite electrodes. Digitized images are exploited in order to obtain the quantitative microstructural information, i.e., the size distributions and interconnectivities of each constituent component. This work reports regarding zirconia-based composite electrodes.

• Journal of Electrochemical Science and Technology
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• 제9권4호
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• pp.330-338
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• 2018

The adhesion strength as well as the electrochemical properties of $LiNi_{0.4}Mn_{0.4}Co_{0.2}O_2$ electrodes containing various conductive carbons (CC) such as fiber-like carbon, vapor-grown carbon fiber, carbon nanotubes, particle-like carbon, Super P, and Ketjen black is compared. The morphological properties is investigated using scanning electron microscope to reveal the interaction between the different CC and the active material. The surface and interfacial cutting analysis system is also used to measure the adhesion strength between the aluminum current collector and the composite film, and the adhesion strength between the active material and the CC of the electrodes. The results obtained from the measured adhesion strength points to the fact that the structure and the particle size of CC additives have tremendous influence on the binding property of the composite electrodes, and this in turn affects the electrochemical property of the configured electrodes.

• Structural Monitoring and Maintenance
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• 제4권1호
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• pp.69-84
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• 2017

Delamination is the most common failure mode in layered composite materials. The author have found that the electrical potential change (EPC) technique using response surfaces method is very effective in assessment delamination in basalt fiber reinforced polymer (FRP) laminate composite pipe by using electrical capacitance sensor (ECS). In the present study, the effect of the electrodes number on the method is investigated using FEM analyses for delamination location/size detection by ANSYS and MATLAB, which are combined to simulate sensor characteristic. Three cases of electrodes number are analyzed here are eight, twelve and sixteen electrodes, afterwards, the delamination is introduced into between the three layers [$0^{\circ}/90^{\circ}/0^{\circ}$]s laminates pipe, split into eight, twelve and sixteen scenarios for cases of eight, twelve and sixteen electrodes respectively. Response surfaces are adopted as a tool for solving inverse problems to estimate delamination location/size from the measured EPC of all segments between electrodes. As a result, it was revealed that the estimation performances of delamination location/size depends on the electrodes number. For ECS, the high number of electrodes is required to obtain high estimation performances of delamination location/size. The illustrated results are in excellent agreement with solutions available in the literature, thus validating the accuracy and reliability of the proposed technique.

• Smart Structures and Systems
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• 제22권4호
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• pp.369-382
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• 2018

Novel design of interdigitated electrodes capable of increasing the performance of piezoelectric transducers are proposed. The new electrodes' geometry improve the electromechanical coupling by offering an enhanced adaptation of the electric field to the interdigitated electrode configuration. The proposed analysis is based on finite element modeling and takes into account local polarization effect. It is shown that the proposed electrodes considerably increase the strain generation compared to flat electrode arrangement used for Macro Fiber Composite (MFC) and Active Fiber Composite (AFC) actuators. Also, electric field singularities are reduced allowing better reliability of the transducer against electric failure.

• Journal of Electrochemical Science and Technology
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• 제13권2호
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• pp.227-236
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• 2022

The microblade cutting method, so-called SAICAS, is widely used to quantify the adhesion of battery composite electrodes at different depths. However, as the electrode thickness or loading increases, the reliability of adhesion values measured by the conventional method is being called into question more frequently. Thus, herein, a few underestimated parameters, such as friction, deformation energy, side-area effect, and actual peeing area, are carefully revisited with ultrathick composite electrodes of 135 ㎛ (6 mAh cm^-2). Among them, the existence of side areas and the change in actual peeling area are found to have a significant influence on measured horizontal forces. Thus, especially for ultrahigh electrodes, we can devise a new SAICAS measurement standard: 1) the side-area should be precut and 2) the same actual peeling area must be secured for obtaining reliable adhesion at different depths. This guideline will practically help design more robust composite electrodes for high-energy-density batteries.

• 한국분말재료학회지
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• 제10권1호
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• pp.21-25
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• 2003

The Sn - graphite composites were prepared by chemical encapsulation method for anode materials in Li-ion batteries. EDS and XRD analysis confirmed the presence of Sn in the graphite structure. Cyclic voltammometry (CV) measurement shows extra reduction and oxidation peaks, which might to be related to the formations of $Li_xSn$ alloy compounds. Graphite-tin composite electrodes demonstrated higher Lithium storage capacities than graphite electrodes. Due to the nature of fine Sn particles on graphite surface, the graphite-tin composite electrodes have shown a good cycle properties.

• Composites Research
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• 제22권1호
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• pp.9-14
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• 2009

본 논문에서는 탄소섬유 복합재료의 균열의 위치 및 성장을 감지하기 위하여 브리지 회로 개념이 적용된 전기 전위법을 제안하였다. 중앙 관통 균열을 가진 복합재료 박판 시험편에 두 쌍의 전극을 생성하였으며, 브리지 회로 개념을 적용하여 한 쌍의 전극에 외부 전압을 인가하고 다른 한 쌍의 전극으로부터 출력 전압 변화를 관찰하였다. 실험과 유한요소해석을 통하여 전극의 크기와 간격, 균열의 위치와 크기 및 성장 방향의 영향을 고찰하였다. 검출 가능한 균열의 크기는 전극의 크기 보다는 전극의 간격에 의한 영향이 더 컸으며, 전극의 크기와 간격이 작을수록 균열의 검출 능력이 우수하였다. 또한, 균열 크기가 증가할 수록, 입력 전극과 가까울수록 출력 전압의 변화가 큼을 관찰할 수 있었다.

• Journal of Electrochemical Science and Technology
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• 제2권2호
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• pp.91-96
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• 2011

Polypyrrole (PPy)/multi-walled carbon nanotube (MWCNT)/conductive carbon (CC) composites are synthesized by the chemical oxidative polymerization method. The morphology analysis of the composite materials indicates uniform coating of PPy over MWCNTs and conductive carbon. The electrochemical performances of PPy/MWCNT/CC composites with different compositions are evaluated in order to optimize the composition of the composite electrode. Galvanostatic chargedischarge measurements and electrochemical impedance spectroscopy studies prove the excellent cycling stability of the PPy/MWCNT/CC composite electrodes.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.358-359
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• 2006

Ru-C nano-composite films were prepared by MOCVD, and their microstructures and their electrode properties for oxygen gas sensors were investigated. Deposited films contained Ru particles of 5-20 nm in diameter dispersed in amorphous C matrix. The AC conductivities associating to the interface charge transfer between Ru-C composite electrode and YSZ electrolyte were 100-1000 times higher than that of conventional paste-Pt electrodes. The emf values of the oxygen gas concentration cell constructed from the nano-composite electrodes and YSZ electrolyte showed the Nernstian theoretical values at low temperatures around 500 K. The response time of the concentration cell was 900 s at 500 K.

• 한국재료학회지
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• 제22권9호
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• pp.470-475
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• 2012

$La_{1-x}Sr_xMnO_3$(LSM,$0{\leq}x{\leq}0.5$) powders as the air electrode for solid oxide fuel cell were synthesized by a glycine-nitrate combustion process. The powders were then examined by X-ray diffraction(XRD) and scanning electron microscopy (SEM). The as-formed powders were composed of very fine ash particles linked together in chains. X-ray maps of the LSM powders milled for 1.5 h showed that the metallic elements are homogeneously distributed inside each grain and in the different grains. The powder XRD patterns of the LSM with x < 0.3 showed a rhombohedral phase; the phase changes to the cubic phase at higher compositions($x{\geq}0.3$) calcined in air at $1200^{\circ}C$ for 4 h. Also, the SEM micrographs showed that the average grain size decreases as Sr content increases. Composite air electrodes made of 50/50 vol% of the resulting LSM powders and yttria stabilized zirconia(YSZ) powders were prepared by colloidal deposition technique. The electrodes were studied by ac impedance spectroscopy in order to improve the performance of a solid oxide fuel cell(SOFC). Reproducible impedance spectra were confirmed using the improved cell, which consisted of LSM-YSZ/YSZ. The composite electrode of LSM and YSZ was found to yield a lower cathodic resistivity than that of the non-composite one. Also, the addition of YSZ to the $La_{1-x}Sr_xMnO_3$ ($0.1{\leq}x{\leq}0.2$) electrode led to a pronounced, large decrease in the cathodic resistivity of the LSM-YSZ composite electrodes.