• Bulletin of the Korean Chemical Society
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• v.31 no.5
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• pp.1314-1318
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• 2010

The $[Ru(tpy)_2]Cl_2$ (tpy:2,2':6',2"-terpyridine) complex was synthesized and its structure was confirmed by $^1H$-NMR and elemental analysis. Its binding mode toward DNA was compared with the well-known $[Ru(bpy)_3]Cl_2$ (bpy:2,2-bipyridyl), using isotropic absorption, linear dichroism(LD) spectroscopy, and an energy minimization study. Compared to $[Ru(bpy)_3]^{2+}$, the $[Ru(tpy)_2]^{2+}$ complex exhibited very little change in its absorption pattern, especially in the MLCT band, upon binding to DNA. Furthermore, upon DNA binding, both Ru(II) complexes induced a decrease in the LD magnitude in the DNA absorption region. The $[Ru(tpy)_2]^{2+}$ complex produced a strong positive LD signal in the ligand absorption region, which is in contrast with the $[Ru(bpy)_3]^{2+}$ complex. Observed spectral properties led to the conclusion that the interaction between the ligands and DNA bases is negligible for the $[Ru(tpy)_2]^{2+}$ complex, although it formed an adduct with DNA. This conclusion implies that both complexes bind to the surface of DNA, most likely to negatively charged phosphate groups via a simple electrostatic interaction, thereby orienting to exhibit the LD signal. The energy minimization calculation also supported this conclusion.

• Steel and Composite Structures
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• v.25 no.1
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• pp.45-55
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• 2017

Stainless steel exhibits high ductility and strain hardening capacity in comparison with carbon steel widely used in constructions. To analyze the particular behaviour of stainless steel cover-plate joints, an experimental study was conducted. It showed large ductility and complex failure modes of the joints. A non-linear finite element model was developed to predict the main parameters influencing the behaviour of these joints. The results of this deterministic model allow us to built a meta-model by using the quadratic response surface method, in order to allow for efficient reliability analysis. This analysis is then applied to the assessment of design formulae in the currently used codes of practice. The reliability analysis has shown that the stainless steel joint design according to Eurocodes leads to much lower failure probabilities than the Eurocodes target reliability for carbon steel, which incites revising the resisting model evaluation and consequently reducing stainless steel joint costs. This approach can be used as a basis to evaluate a wide range of steel joints involving complex failure modes, particularly bearing failure.

• Wind and Structures
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• v.31 no.5
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• pp.403-418
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• 2020

To investigate the effects of central buckles on the dynamic behavior and flutter stability of long-span suspension bridges, four different connection options between the main cable and the girder near the mid-span position of the Aizhai Bridge were studied. Based on the flutter derivatives obtained from wind tunnel tests, formulations of self-excited forces in the time domain were obtained using a nonlinear least square fitting method and a time-domain flutter analysis was realized. Subsequently, the influences of the central buckles on the critical flutter velocity, flutter frequency, and three-dimensional flutter states of the bridge were investigated. The results show that the central buckles can significantly increase the frequency of the longitudinal floating mode of the bridge and have greater influence on the frequencies of the asymmetric lateral bending mode and asymmetric torsion mode than on that of the symmetric ones. As such, the central buckles have small impact on the critical flutter velocity due to that the flutter mode of the Aizhai Bridge was essentially the symmetric torsion mode coupled with the symmetric vertical mode. However, the central buckles have certain impact on the flutter mode and the three-dimensional flutter states of the bridge. In addition, it is found that the phenomenon of complex beat vibrations (called intermittent flutter phenomenon) appeared in the flutter state of the bridge when the structural damping is 0 or very low.

• The Korean Journal of Applied Statistics
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• v.22 no.3
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• pp.499-513
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• 2009

An economic signal in the real world usually reflects complex phenomena. One may have difficulty both extracting and interpreting information embedded in such a signal. A natural way to reduce complexity is to decompose the original signal into several simple components, and then analyze each component. Spectral analysis (Priestley, 1981) provides a tool to analyze such signals under the assumption that the time series is stationary. However when the signal is subject to non-stationary and nonlinear characteristics such as amplitude and frequency modulation along time scale, spectral analysis is not suitable. Huang et al. (1998b, 1999) proposed a data-adaptive decomposition method called empirical mode decomposition and then applied Hilbert spectral analysis to decomposed signals called intrinsic mode function. Huang et al. (1998b, 1999) named this two step procedure the Hilbert-Huang transform(HHT). Because of its robustness in the presence of nonlinearity and non-stationarity, HHT has been used in various fields. In this paper, we discuss the applications of the HHT and demonstrate its promising potential for non-stationary financial time series data provided through a Korean stock price index.

• Wind and Structures
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• v.14 no.4
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• pp.359-381
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• 2011

This paper deals with the flutter instability problem of flexible bridge decks in the framework of bimodal-coupled aeroelastic bridge system analysis. Based on the analysis of coefficients of the polynomials deduced from the singularity conditions of an integral wind-structure impedance matrix, a set of simplified formulations for calculating the critical wind velocity and coupled frequency are presented. Several case studies are discussed and comparisons with available approximated approaches are made and presented, along with a conventional complex eigenvalue analysis and numerical results. From the results, it is found that the formulas that are presented in this study are applicable to a variety of bridge cross sections that are not only prone to coupled-mode but also to single-mode-dominated flutter.

• Journal of the Korean Society for Precision Engineering
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• v.17 no.1
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• pp.83-92
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• 2000

Sound intensity method is well known as a visualization technique of sound field or sound propagation in noise control. Sound intensity or energy flux is a vector quantity which describes the amount and the direction of net flow of acoustic energy at a given position. Especially two dimensional sound intensity method is very useful in evaluating periodic characteristics and acoustic propagation mode of noise source. In this paper, we have studied the noise source Identification, acoustic sound field analysis, and characteristics of noise source of rotary compressor and scroll compressor for air conditioner using complex sound intensity method. Also we proposed a now method of time domain analysis which is used in evaluating of position of noise source in rotary and scroll compressor in this paper This paper presents the advantage, simplicity and economical efficiency of this method by analysing the characteristics of noise source with two dimensional complex sound intensity simultaneously.

• Bulletin of the Korean Chemical Society
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• v.31 no.2
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• pp.435-441
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• 2010

We report the preparation and characterization of a new and water soluble complex of palladium(II) with 1,10- phenanthroline and butyldithiocarbamate ligands. This compound has been studied through spectroscopic techniques, $^1H$ NMR, IR, electronic spectra and elemental analysis and conductivity measurements. The complex shows 50% cytotoxic concentration ($Ic_{50}$) value against chronic myelogenous leukemia cell line, K562, much lower than that of cisplatin. Thus the mode of binding of this complex to calf thymus DNA have been extensively investigated by isothermal titration UV-visible spectrophotometry, fluorescence, gel filteration and other methods. UV-visible studies show that the complex exhibits cooperative binding with DNA and remarkably denatures the DNA at extremely low concentration ($~13\;{\mu}M$). Fluorescence studies indicate that the complex intercalate into DNA. Gel filtration studies suggest that the binding of Pd(II) complex with DNA is strong enough that it does not readily break. In these interaction studies, several thermodynamic and binding parameters are also determined which may reflect the mechanism of action of this type of compound with DNA.

• Journal of the Korean Society of Safety
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• v.12 no.4
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• pp.27-38
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• 1997

The effect of geometry factors on the combined mode stress intensity factor behaviors of a slant crack in a non-uniform thickness material was analysed by 2-dimensional theoretical analysis. The analysis is based on the Laurent's series expansions of complex potentials where the complex coefficients of the series are determined from the compatibility and the equilibrium conditions of the thickness interface and the stress free conditions of the crack surface. In numerical calculations the perturbation technique is employed. The expressions for the crack tip stress intensity factor are given in the form of power series of dimensionless crack length $\lamda$, and the function of crack slant angle $\alpha$ and thickness ratio $\beta$. The results of numerical calculations for each problems are represented as the correction factors F($\lamda$, $\alpha$, $\beta$). The results clearly show the following characteristics : The correction factors of the combined mode stress intensity factors for a non-uniform thickness material can be defined in the form of F($\lamda$, $\alpha$, $\beta$). The stress intensity factor values for a given crack length are decreased with increase of thickness ratio $\beta$.

• Journal of KSNVE
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• v.10 no.5
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• pp.800-805
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• 2000

To determine the modal matrix and modal frequency of engine mount system, we most solve so-called eigen-value problem. However eigen-value problem of engine mount system with hydraulic mount can not be solved by general eigne-analysis algorithm because the properties of hydraulic mount vary with frequency. so in this paper the method for modal analysis of rigid body motions of an engine supported by hydraulic mount is proposed. Natural frequencies and mode shapes of this nonlinear system are obtained by using complex exponential method and Laplace transformation method. In time domain, impulse response functions are calculated by (two-sided) discrete inverse Fourier Transformation of forced frequency response functions achieved by Laplace transformation of the differential equation of motion. Considering the fact that frequency response functions synthesized by modal parameters form proposed method are in good agreement with original FRFs, it is proved that the proposed method is very efficient and useful for the analysis of eigne-value problem of hydraulic engine mount system.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.38 no.12
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• pp.1351-1358
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• 2014

This study numerically simulates brake squeal and validates it experimentally by using a lab-scaled brake dynamometer. The system frequencies of the disc brake are traced with respect to the brake pressure by using a modal test and FEM. Then, the squeal frequencies measured from the brake dynamometer are found to correspond to the brake system mode with the dominant displacement of the caliper and pad. Furthermore, a complex eigenvalue analysis conducted using the finite element model confirms that the caliper mode generating the rotational displacement of the pad becomes unstable owing to the negative friction-velocity slope.