• Journal of Electrochemical Science and Technology
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• v.15 no.2
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• pp.253-260
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• 2024

Proton exchange membrane water electrolysis (PEMWE) is an efficient method for utilizing renewable energy sources such as wind and solar powers to produce green hydrogen. For PEMWE powered by renewable energy sources, its durability is a crucial factor in its performance since irregular and fluctuating characteristics of renewable energy sources, especially for wind power, can deteriorate the stability of PEMWE. Triangular voltage cycle is well able to simulate fluctuating wind power, but its effect on the durability has not been investigated extensively. In this study, the performance degradation of the PEMWE cell operated with the triangular voltage cycling was investigated at different ramping rates. The measured current responses during the cycling gradually decreased for both ramping rates, and I-V curve measurements before and after the cycling confirmed the degradation of the performances of PEMWE. For both measurements, the degradation rate was larger for 300 mV s^-1 than 30 mV s^-1, and they were determined as 0.36 and 1.26 mV h^-1 (at the current density of 2 A cm^-2) at the ramping rates of 30 and 300 mV s^-1, respectively. The comparison with other studies on triangular voltage cycling also indicate that an increase in the ramping rate accelerates the deterioration of the PEMWE performance. X-ray photoelectron spectroscopy and transmission electron microscopy results showed that the Ir catalyst was oxidized and did not dissolve during the voltage cycling. This study suggests that the ramping rate of the triangular voltage cycling is an important factor for the evaluation of the durability of PEMWE cells.

• Journal of the Korean Electrochemical Society
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• v.15 no.1
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• pp.12-18
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• 2012

The prohibitively high cost of Pt catalyst might be the biggest barrier for the commercialization of proton exchange membrane fuel cells (PEMFC) of which wide application is expected. Worldwide research efforts for the development of alternative to Pt oxygen reduction reaction (ORR) catalyst are made recently. One of the important considerations in the catalyst development is durability issue as well as economic aspect. From this point of view, platinum group metals (PGM) except Pt can be a candidate for replacing Pt catalyst because the material properties and the catalytic activity of PGM are expected to be similar to Pt. In contrast to Ir, Rh and Os to which not so much attention has been paid as an ORR catalyst, Pd that is most similar to Pt in terms of material properties and catalytic activity and Ru that is in the form of chalcogenide have been studied intensively. Activity comparison between non-Pt and Pt oxygen reduction catalysts by half cell test using RDE (rotating disk electrode) or PEMFC MEA (membrane electrode assembly) operation indicates that Pd-based catalysts show the most similar activity to Pt. In this paper we analyze the composition of PGM ORR catalyst in literature to promote the development of non-Pt ORR catalyst.

• Korean Chemical Engineering Research
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• v.56 no.2
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• pp.151-155
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• 2018

Degree of membrane degradation in Proton Exchange Membrane Fuel Cells (PEMFC) is mainly evaluated by the hydrogen crossover current density. The hydrogen crossover current density is measured by linear sweep voltammetry (LSV), which differs from the DOE protocol and the NEDO protocol. In this study, two protocols were compared during PEMFC operation and accelerated stress test. In the LSV method by the DOE method, the scan rate change affects the hydrogen crossover current density, but the NEDO method does not affect the hydrogen crossover current density. In the course of 15,000 cycles of polymer membrane wet/dry cycle, the DOE method was sensitive to membrane degradation, but the NEDO method was less sensitive to membrane degradation than the DOE method.

• Smart Structures and Systems
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• v.15 no.4
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• pp.1019-1039
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• 2015

Shanghai Tower is a composite structure building with a height of 632 m. In order to verify the structural properties and behaviors in construction and operation, a structural health monitoring project was conducted by Tongji University. The monitoring system includes sensor system, data acquisition system and a monitoring software system. Focusing on the health monitoring in construction, this paper introduced the monitoring parameters in construction, the data acquisition strategy and an integration structural health monitoring (SHM) software. The integration software - Structural Monitoring/ Analysis/ Evaluation System (SMAE) is designed based on integration and modular design idea, which includes on-line data acquisition, finite elements and dynamic property analysis functions. With the integration and modular design idea, this SHM system can realize the data exchange and results comparison from on-site monitoring and FEM effectively. The analysis of the monitoring data collected during the process of construction shows that the system works stably, realize data acquirement and analysis effectively, and also provides measured basis for understanding the structural state of the construction. Meanwhile, references are provided for the future automates construction monitoring and implementation of high-rise building structures.

• Structural Engineering and Mechanics
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• v.68 no.4
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• pp.459-473
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• 2018

Temperature fields and temperature deformations induced by time-varying solar radiation, shadow, and heat exchange are of great importance for the ride safety and quality of the maglev system. Accurate evaluations of their effects on the dynamic performances are necessary to avoid unexpected loss of service performance. This paper presents a numerical approach to determine temperature effects on the maglev train/guideway interaction system. Heat flux density and heat transfer coefficient of different components of a 25 m simply supported concrete guideway on Shanghai High-speed Maglev Commercial Operation Line is calculated, and an appropriate section mesh is used to consider the time-varying shadow on guideway surfaces. Based on the heat-stress coupled technology, temperature distributions and deformation fields of the guideway are then computed via Finite Element method. Combining guideway irregularities and thermal deformations as the external excitations, a numerical maglev train/guideway interaction model is proposed to analyze the temperature effect. The responses comparison including and excluding temperature effect indicates that the temperature deformation plays an important role in amplifying the response of a running maglev, and the parameter analysis results suggest that climatic and environmental factors significantly affect the temperature effects on the coupled maglev system.

• Fashion & Textile Research Journal
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• v.10 no.3
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• pp.289-297
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• 2008

This paper was to examine the salesperson's service that the consumer demands in different types of fashion retailing formats including department store, discount store and outlet store. Data has been collected from June to August in 2005 in Pusan and Seoul on subject of 1000 adult over18 years old and 979 pieces were used to analyze. Data analysis was conducted by factor analysis, regression using the SPSS statistics package program. Services in common in 3 fashion retailing formats were "individual concerning", "kindness, courtesy/customer respect", "quick correspondence/convenience", and "product knowledge". Unique services that consumer demanded for the department store were professional and polite attitude; for the discount store, honesty and convenience for refund and exchange; for the outlet store, wide range of product selection. The results has shown that the part of salesperson's service dimensions influenced the consumer's purchase, repurchasing intention and the level of satisfaction. Therefore fashion marketers need to carefully implicate operation and service management depending on the retailing formats.

• Progress in Superconductivity and Cryogenics
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• v.23 no.1
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• pp.7-11
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• 2021

Cryogenic vessels are special equipment that requires periodic evaluation of their thermal insulation performance. At the current standard, the test is considered as the loss product or heat leakage of cryogenic vessel, which takes over 72 h to evaluate; consequently, a large amount of working medium is discharged to the environment in the process. However, hydrogen is flammable and explosive, and the discharged gas may be dangerous. If liquid hydrogen is replaced with liquid nitrogen before testing, the operation then becomes complicated, and the loss product or heat leakage cannot respond to the thermal insulation performance of cryogenic vessels for liquid hydrogen. Therefore, a novel method is proposed to evaluate the heat leakage of cryogenic vessels for liquid hydrogen in self-pressurization. In contrast to the current testing methods, the method proposed in this study does not require discharge or exchange of working medium in all test processes. The proposed method is based on one-dimensional heat transfer analysis of cryogenic vessels, which is verified by experiment. When this method is used to predict the heat leakage, the comparison with the experimental data of the standard method shows that the maximum error of heat leakage is less than 5.0%.

• The Transactions of the Korean Institute of Power Electronics
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• v.13 no.5
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• pp.344-351
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• 2008

The benefits of utilizing energy exchange between the main land and Cheju island in Korea make it interesting to establish new HVDC sea cable interconnections. A total power of 350 MW or more can then be exchanged through the HVDC links including the existing Cheju HVDC #1 interconnection. A feasibility study base on economical benefits has been carried out. Especially the comparison of economy benefit between thermal power plant, LNG power plant and HVDC system shows that HVDC system is the only solution in Cheju island. Also, this paper shows that additiona 1 HVDC system help to enhance the stability of power system.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.5
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• pp.1954-1962
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• 2012

Recently the increase in the exchange of goods between Europe and Asia caused by social and economic factors creates good opportunities for railways. At the same time, however, it becomes an enormous challenge for railway transport. There are different rail track gauges (i.e narrow/standard/broad gauge) on the continental transportation between Korea (TKR) and Eurasian (TCR/TSR). The existence of various track gauges is one of obstacles preventing the smooth flow of goods by rail. The transferring process system from one track gauge to another could vary with the types of cargo. Service operation of these systems has a decisive effect on working time and cost of storage and transshipment facilities at border crossings. In relation to the above-mentioned factors, it is important to examine the comparison between different methods of transferring goods in different track gauges. In this study, it was performed to evaluate the effectiveness of continental railway transportation systems through analysis scenarios and to suggest technical factors of them.

• Particle and aerosol research
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• v.9 no.2
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• pp.103-110
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• 2013

The electrostatic precipitator (ESP) has been used for degrading atmospheric pollutants. These devices induce the electrical forces to facilitate the removal of particulate pollutants. The ions travel from the high voltage electrode to the grounded electrode by Coulomb force induced by the electric field when a high voltage is applied between two electrodes. The ions collide with gas molecules and exchange momentum with each other thus inducing fluid motion, electrohydrodynamic (EHD) flow. In this study, for the simulation of electric field and EHD flow in ESPs, an open source EHD solver, "espFoam", has been developed using open source CFD toolbox, OpenFOAM(R) (Open Field Operation and Manipulation). The electric potential distribution and ionic space charge density distribution were obtained with the developed solver, and validated with experimental results in the literature. The comparison results showed good agreement. Turbulence model is also incorporated to simulate turbulent flow; hence the developed solver can analyze laminar and turbulent flow. In distributions of electric potential and space charge, the distributions become distorted and asymmetric as the flow velocity increases. The effect of electrical drift flow was investigated for different flow velocities and the secondary flow in a flow of low velocity is successfully predicted.