• Mass Spectrometry Letters
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• v.4 no.1
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• pp.18-20
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• 2013

Headspace solid phase micro-extraction gas chromatography/flame ionization detection (HS-SPME-GC/FID) method was compared with headspace gas chromatography/mass selective detection (HS-GC/MS). Organic solvent-spiked urine as well as urine samples from workspace was analyzed under optimal condition of each method. Detection limit of each compound by HS-SPME-GC/FID was $3.4-9.5{\mu}g/L$, which enabled trace analysis of organic solvents in urine. Linear range of each organic solvent was $10-400{\mu}g/L$, with fair correlation coefficient between 0.992 and 0.999. The detection sensitivity was 4 times better than HS-GC/MS in selected ion monitoring (SIM) mode. Accuracy and precision was confirmed using commercial reference material, with accuracy around 90% and precision less than 4.6% of coefficient of variance. Among 48 urine samples from workplace, toluene was detected from 45 samples in the range of $20-324{\mu}g/L$, but no other solvents were found. As a method for trace analysis, SPME HS GC/FID showed high sensitivity for biological monitoring of organic solvent in urine.

• Korean Chemical Engineering Research
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• v.51 no.1
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• pp.25-34
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• 2013

The paper reviews the state of art in the design of liquefaction processes for the production of liquified natural gas, and addresses key design aspects to be considered in the design and how these design issues are systematically reflected in industrial applications. Various design options to improve energy efficiency of refrigeration cycles are discussed, including cascaded or multi-level pure refrigeration cycles which are used for covering wide range of cooling temperature, as well as mixed refrigerant cycle which can maintain a simple structure. Heat integration technique has been used for graphically examining differences of commercial cycles discussed in this paper, while energy efficiency and economics of commercial liquefaction processes has been summarized. Discussion also has been made about how to select the most appropriate set of drivers for compressors used in the liquefaction plant.

• Journal of the Korean Institute of Gas
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• v.22 no.2
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• pp.21-28
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• 2018

In recent years, payability of shale gas production has worsened due to oil and gas price declines resulting from sharply increasing shale gas production. Reliable economic evaluation in shale gas development has become important. In this study, Monte Carlo simulation of probabilistic analysis technique was applied to analyze the economic feasibility considering the uncertainty involved in shale gas development. For this, the range of major variables is set and a random number is generated to derive the probability distribution of Net Present Value(NPV) and Internal Rate of Return(IRR). Consequently, we estimated the probability that the feasibility of the project is evaluated to be positive when developing shale gas in the study area. In addition, sensitivity analysis of major parameters affecting economic efficiency in shale gas development was carried out, and the effect of major variables in economic evaluation for commercial production was identified. In the future, this study could be used to make decision for shale gas production by presenting the range of variation of economic index and probability value.

• Korean Chemical Engineering Research
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• v.55 no.5
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• pp.698-703
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• 2017

Bubble flow characteristics in fluidized beds were analyzed by CPFD simulation. A fluidized bed, which had the size of $0.3m-ID{\times}2.4m-high$, was modeled by commercial CPFD $Barracuda^{(R)}$. Properties of bed material were $d_p=150{\mu}m$, ${\rho}_p=2,330kg/m^3$, and $U_{mf}=0.02m/s$. Gas was uniformly distributed and the range of superficial gas velocity was 0.07 to 0.16 m/s. Two other geometries were modeled. The first was a three-dimensional model, and the other was a two-dimensional model of $0.01m{\times}0.3m{\times}2.4m$. Bubble size and rising velocity were simulated by axial and radial position according to superficial gas velocity. In the case of three-dimensional model, simulated bubble rising velocity was different from correlations, because there was zigzag motion in bubble flow, and bubble detection was duplicated. To exclude zigzag motion of bubble flow, bubble rising velocity was simulated in the two-dimensional model and compared to the result from three-dimensional model.

• Journal of Environmental Science International
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• v.13 no.6
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• pp.551-560
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• 2004

The feasibility and efficiency of the hydrogen peroxide produced by an electrolysis cell reactor was investigated, From regulating voltages for the given reaction time, the concentration of the hydrogen peroxide was gradually increased with increasing voltages. Optimal voltage range was found to be 10～15 V. The concentration of hydrogen peroxide was much higher with oxygen gas than without oxygen gas in the cathodic chamber. But there was a little difference in the generating rate of hydrogen peroxide regardless of the presence of nitrogen gas. Under given conditions, the maximum value of ICE(Instantaneous Current Efficiency) was about 38%, and then current density was 74 $mA/\textrm{cm}^2.$ The specific energy consumption was $0.694[kWh/kg-H_2O_2].$ Since Esp (Specific Energy Consumption)was very little value, It did not demand high energy in this system. Using the hydrogen peroxide gained in the experiment, Fenton's reaction was conducted and the removal of nitrobenzene, 3-chlorophenol and dye wastewater was studied. This results were very similar to the Fenton's reaction by using commercial hydrogen peroxide.

• Korean journal of food and cookery science
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• v.22 no.3 s.93
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• pp.299-306
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• 2006

The numerous varieties of coffee beans contain a wide range prices and qualities. While the varieties of green coffee beans can generally be distinguished by their appearance, this visual criterion is impossible after the roasting process. Therefore, we need to develop a classification method or device. In this study, the potential of a new type of electronic nose, fast gas chromatography based on a surface acoustic wave sensor(SAW), was evaluated for the classification of origins and blended commercial brands in roasted coffee beans. Eight blended commercial brands and the origins of four similarly roasted ground coffee beans(with no significant difference of color) were rapidly(90 sec/sample) classified. The reproductive results were easily understandable over the aroma image pattern by $VaporPrint^{TM}$. In conclusion, GC-SAW electronic nose can be applied to the classification of origins and commercial brands in roasted ground coffee beans and to e evaluation of the similarities and differences of volatile pattern between samples.

• Transactions of the Korean hydrogen and new energy society
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• v.21 no.3
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• pp.193-200
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• 2010

Anode off-gas of high temperature fuel cell still contains combustible components such as hydrogen, carbon monoxide and hydrocarbon. In this study, a catalytic combustor has been applied to the high temperature fuel cell so that the combustion of anode-off gas can be boosted up. Since the performance of catalytic combustor directly depends on the combustion catalyst, this study is designed to perform the experimental investigation on the combustion characteristics of the three commercial catalysts with a different composition. Screening tests with three catalysts are preceded before the performance examination since it is necessary to determine the most suitable catalyst for design configuration of the catalytic combustor. The performance analysis shows that methane conversion rate strongly depends on gas hourly space velocity (GHSV) as well as inlet gas temperature. Additionally, the GSHV optimization results show that the optimum GHSV will be in the range between 18,000 $hr^{-1}$ and 36,000 $hr^{-1}$. It is also shown that the minimum inlet temperature of catalytic reaction of methane is from $100^{\circ}C$ to $150^{\circ}C$.

• 한국신재생에너지학회:학술대회논문집
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• 2006.06a
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• pp.523-526
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• 2006

The target of this work was the process development of demonstration plant to produce the high quailty alternative fuel oil by the pyrolysis of mixed plastic waste. In the first step of research, the bench-scale units of 70t/y and the pi lot plant of 360 t/v had been developed. Main research contents in this step were the process performance test of pilot plant ot 360ton/year and the development of demonstration plant of 3 000 t/y which was constructed at Korea R & D Company in Kimjae City. The process performance of pilot plant of 360 t/v showed components in PONA group appeared at between that of commercial gasoline and kerosene. On the other hand, HO product was mainly paraffin and olefin components and also appeared at upper temperature distribution range than commercial diesel. Gas product showed a high fraction of $C_3\;and\;C_4$ product like LPG composition, but also a high fraction of $CO_2$ and CO by probably a little leak of process.

• The Korean Journal of Petroleum Geology
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• v.11 no.1 s.12
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• pp.27-41
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• 2005

The hydrocarbon source rock potential of the Eocene units in the southern Oregon Coast Range was evaluated by using the Rock-Eval pyrolysis. Most Eocene units in southern Oregon Coast Range are thermally immature and contain lean, gas-prone Type III kerogen. However, some beds(coals) are sufficiently organic-rich to be sources of biogenic and thermogenic methane discovered in numerous seeps. The overall hydrocarbon source rock potential of the southern Oregon Coast Range is moderately low. Several requirements for commercial accumulations of hydrocarbon, however, probably exist locally within and adjacent areas. Three speculative petroleum systems are identified. The first includes the southern part of the Oregon Coast Range near the border with the Mesozoic Klamath Mountains and is related to a proposed subduction zone maturation mechanism along thrust faults. The second is centered in the northern part of the range and may be associated with basin-centered gas in an over-pressured zone. The third occurs near the eastern border of the range where maturation is related heating by sills and migration of hydrothermal fluids associated with mid-Tertiary volcanism in the Western cascade arc.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.3247-3252
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• 2007

Endwall losses contribute significantly to the overall losses in modern turbomachinery, especially when aerodynamic airfoil load and pressure ratio are increased. Hence, reducing the extend and intensity of the secondary flow structures helps to enhance overall efficiency. From the large range of viable approaches, a promising combination positioning and height of endwall contouring was chosen. The objective of this study is to document the three-dimensional flow in a turbine cascade in terms of streamwise vorticity, total pressure loss distribution and static pressure distribution on the endwall and blade surface and to propose an appropriate positioning and height of the endwall contouring which show best secondary, overall loss reduction among the simulated endwall. The flow through the gas turbine were numerically analyzed using three dimensional Navier-Stroke equations with a commercial CFD code ANSYS CFX-10. The result shows that the overall loss is reduced near the flat endwall rather than contoured endwall, and the case of contoured endwall installed at 30% from leading edge with height of 25% for span showed best performance.