• Journal of Environmental Science International
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• v.25 no.8
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• pp.1065-1076
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• 2016

This study analyzes the $PM_{10}$ characteristics (particulate matter with aerodynamic diameter less than $10{\mu}m$), concentration, and emissions in eight large South Korean cities (Seoul, Incheon, Daejeon, Daegu, Gwangju, Ulsan, Busan, Jeju). The annual median of $PM_{10}$ concentration showed a decline of $0.02{\sim}1.97{\mu}g/m^3$ in the regions, except for Incheon, which recorded an annual $0.02{\mu}g/m^3$ increase. The monthly distribution levels were high in spring, winter, fall, and the summer, but were lower in summer for all regions except for Ulsan. These differences are thought to be due to the dust in spring and the cleaning effect of precipitation in summer. The variation in concentrations during the day (diurnal variation) showed that $PM_{10}$ levels were very high during the rush hour and that this was most extreme in the cities (10.00 and 18.00-21.00). The total annual $PM_{10}$ emissions analysis suggested that there had been a general decrease, except for Jeju. On-road mobile (OM) sources, which contributed a large proportion of the particulates in most regions, decreased, but fugitive dust (FD) sources increased in the remaining regions, except for Daegu. The correlation analysis between $PM_{10}$ concentrations and emissions showed that FD could be used as a valid, positive predictor of $PM_{10}$ emissions in Seoul (74.5% (p<0.05)), Dajeon (47.2% (p<0.05)), and Busan (59.1% (p<0.01)). Furthermore, industrial combustion (IC) was also a significant predictor in Incheon (61.7% (p<0.01)), and on-road mobile (OC) sources were a valid predictor in Daegu (24.8% (p<0.05)).

• Journal of the Korean Institute of Gas
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• v.22 no.2
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• pp.78-83
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• 2018

The purpose of this paper is to study for failure examples of emission gas recirculation and air control and catalyzed particulate filter system in diesel engine vehicle. The first example, the researcher found the fact that the much engine oil came into the intake manifold causing diaphragm damage of EGR valve. The engine oil entered into combustion chamber of engine so that a car emit the polluted exhaust gas when driving. The second example, the researcher certified the sticking phenomenon of carbon and foreign substance with the throttle flap so that the exhaust fumes discharged exhaust port. The third example, the regeneration function don't activated to not detect the temperature of exhaust gas because of damage in the sensor. Thus, the researcher must meticulously manage his car not in order to take place the problem of environmental pollution.

• Analytical Science and Technology
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• v.27 no.2
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• pp.108-113
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• 2014

The harmful materials as volatile organic compounds (VOCS) that is easy for gas to be changed from liquid on ambient temperature, those should be controlled by Korea Chemicals Management Association. The VOCs samples should be collected directly in place so that those could be analyzed. Generally but it couldn't avoid to have the risk of analyst. Moreover, if there is the place limited to entrance, it is impossible to collect directly and measure. Owing to such problem, it tried to be solved by open path FT-IR spectrometer that could be studied on the combustion gases within long path and VOCs samples were tried to measure to large volume by remote and real time. Firstly, it was to investigate optimized measured length between the system and benzene sample of VOCs. As result, The optimized measured length was confirmed with 15 meter length and the qualitative analysis could be measured on seven VOC samples. The calibration curve as quantitative analysis of benzene samples could be worked. On the basis of the result, the system as remote monitor could show to have potentiality.

• Journal of the Korean Society of Propulsion Engineers
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• v.19 no.4
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• pp.52-60
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• 2015

Operation area of corps was expanded under military reformation, and extending range of 155 mm howitzer became important issue. New approach is needed to extend range to 80 kim. Ramjet engine is air breathing engine, and it can provide specific impulse several times more than solid rocket motor so that range is extended using same weight of propellant. If the ramjet engine is gun-launched system, it does not require any other booster because muzzle velocity is near Mach 3. Especially solid fuel ramjet (SFRJ) does not have any moving part so that it is favorable for gun-launching system which is under high stress during launching. In this paper, we design air intake, combustion chamber, and nozzle of 155 mm gun launched ramjet propelled artillery shell with inviscid flow assumption. We conduct parameter study to have range more than 80 km, and maximum high explosive volume.

• Transactions of the Korean Society of Mechanical Engineers
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• v.16 no.11
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• pp.2150-2158
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• 1992

This study was carried out to investigate the flow structure and mixing process of a cross mixing flow formed by two round jets with respect to the ratio of mass flow rate. This flow configuration is of great practical relevance in a variety of combustion systems, and the flow behaviour of a cross jet defends critically on the ratio of mass flow rate and the cross angle. The mass flow rate ratios of two different jets were controlled as 1.0, 0.8, 0.6, and 0.4, and the crossing angle of two round jets was fixed at 45 degree. The velocities issuing from jet nozzle with an exit diameter of 20mm were adjusted to 40m/s, 32m/s, 24m/s, and 16m/s, and the measurements have been conducted in the streamwise range of $1.1X_0$to $2.5X_0$ by an on-line measurement system consisted of a constant temperature type two channel hot-wire anemometry connected to a computer analyzing system. The original air flow was generated by a subsonic wind tunnel with reliable stabilities and uniform flows in the test section. For the analysis of the cross mixing flow structure in the downstream region after the cross point, the mean velocity profiles, the resultant velocity contours, and the three-dimensional profiles depending upon the mass flow rate ratio have been concentrately studied.

• Clean Technology
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• v.20 no.3
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• pp.212-217
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• 2014

In order to regenerate the sulfidated desulfurization sorbent, oxygen is used as the oxidant agent on the regeneration process. The small amount of oxygen un-reacted in regeneration process is flowed into direct sulfur recovery process. However, the reactivity for $SO_2$ reduction can be deteriorated with the un-reacted oxygen by various reasons. In this study, the deactivation effects of un-reacted oxygen contained in the off-gas of regeneration process flowed into direct sulfur recovery process of hot gas desulfurization system were investigated. Sn-Zr based catalysts were used as the catalyst for $SO_2$ reduction. The contents of $SO_2$ and $O_2$ contained in the regenerator off-gas used as the reactants were fixed to 5.0 vol% and 4.0 vol%, respectively. The catalytic activity tests with a Sn-Zr based catalyst were for $SO_2$ reduction performed at $300-450^{\circ}C$ and 1-20 atm. The un-reacted oxygen oxidized the elemental sulfur produced by $SO_2$ catalytic reduction and the conversion of $SO_2$ was reduced due to the production of $SO_2$. However, the temperature for the oxidation of elemental sulfur increased with increasing pressure in the catalytic reactor. Therefore, it was concluded that the decrease of reactivity at high pressure is occurred by catalytic deactivation, which is the re-oxidation of lattice oxygen vacancy in Sn-Zr based catalyst with the un-reacted oxygen on the catalysis by redox mechanism. Meanwhile the un-reacted oxygen oxidized CO supplied as the reducing agent and the temperature in the catalyst packed bed also increased due to the combustion of CO. It was concluded that the rapidly increasing temperature in the packed bed can induce the catalytic deactivation such as the sintering of active components.

• Applied Chemistry for Engineering
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• v.20 no.1
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• pp.62-66
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• 2009

Utilization and interest of unconventional fuel and process residue such as oil sand and its residue, oil sand coke, have been increased because of the continuous rise of fuel price and conventional fuel availability. In this study, the gasification of oil sand coke produced from coking process of oil sand was performed to utilize as an energy resource using lab-scale fixed bed gasification system. The combustion characteristics of oil sand bitumen and oil sand coke were investigated by using TGA and lab-scale gasification system was applied to reveal the characteristics of produced syngas composition with oxygen/fuel ratio, temperature and steam injection rate. Oil sand coke shows a high carbon content, heating value and sulfur content and low ash content and reactivity. In case of oil sand coke gasification, generally with increasing temperature, the amount of steam introduced and decreasing oxygen injection rate, $H_2$ content in product gas increased while the $CO_2$ content decreased. The calorific value of syngas shows about $2100kcal/Nm^3$ and this result indicates that the oil sand coke can be used as a resource of hydrogen and fuel.

• Journal of Energy Engineering
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• v.25 no.4
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• pp.13-29
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• 2016

In this study, we analyzed the causes of major faults in the biogas plant through the case of gas engine failure when cogenerating electricity and heat using biogas as a fuel in the actual sewage treatment plant and suggested countermeasures. Hydrogen sulfide in the biogas entering the biogas engine and water caused by intermittent malfunction of the water removal system caused intercooler corrosion in the biogas engine. In addition, the siloxane in the biogas forms a silicate compound with silicon dioxide, which causes scratches and wear of the piston surface and the inner wall of the cylinder liner. The substances attached to the combustion chamber and the exhaust system were analyzed to be combined with hydrogen sulfide and other impurities. It is believed that hydrogen sulfide was supplied to the desulfurization plant for a long period of time because of the high content of hydrogen sulfide (more than 50ppm) in the biogas and the hydrogen sulfide was introduced into the engine due to the decrease of the removal efficiency due to the breakthrough point of the activated carbon in the desulfurization plant. In addition, the hydrogen sulfide degrades the function of the activated carbon for siloxane removal of the adsorption column, which is considered to be caused by the introduction of unremoved siloxane waste into the engine, resulting in various types of engine failure. Therefore, hydrogen sulfide, siloxane, and water can be regarded as the main causes of the failure of the biogas engine. Among them, hydrogen sulfide reacts with other materials causing failure and can be regarded as a substance having a great influence on the pretreatment process. As a result, optimization of $H_2S$ removal method seems to be an essential measure for stable operation of the biogas engine.

• Journal of environmental and Sanitary engineering
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• v.7 no.2
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• pp.1-10
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• 1992

Since 1960's along with industrialization and urbanization, economic growth has been . achieved, however, at the same time, environmental condition has been seriously deteriorated. . Currently, volume of wastewater has been increasing at annual rate of 7% in sewage and 20% in industrial wastewater. However, the nation's sewage treatment serves only 33% of the municipal wastewater as of 1991. Major portion of air pollutants comes from combustion of oil and coal which comprise 81% of total energy use and emission gases from motor vehicles increasing at an accelerated rate. It is known that Korea generates the highest amount of waste per capta. Nevertheless, it is not sufficient to reduce the volume of waste by means of resources recovery and recycling. Recognizing the importance of global environmental problems such as ozone layer depletion, global warming and acid rain, international society has been making various efforts since the 1972 Stockholm conference. In particular, it is expected that the Rio conference which has adopted the Rio declaration and Agenda 21 will form a crucial turning point of the emerging new world order after the Cold War confrontation. To cope with such issues as domestic pollution and global environmental problems, the fundamental national policy aims at harmonizing "environmental protection and sustainable development". The Ministry of Environment has recently set up a mid-term comprehensive plan which includes annual targets for environmental protection. According to the government plan, gradual improvement of various environmental conditions and specific measures to achieve them is planned in time frame. Additional sewage treatment plants will be constructed in urban areas with the target to treat 65% of the nation's municipal sewage by 1996. Supply of clean fuels such as LNG will also be expanded starting from large cities as a cleaner substitute energy for coal and oil. In parallel with expansion of LNG, emphasis will be placed on installation of stack monitoring system. Due to the relatively limited land, government's basic policy for solid waste treatment is to develop large scale landfill facilities rather than small sized ones. Thirty three regional areas have been designated for the purpose of waste management. For each of these regions, big scale landfill site is going to be developed. To increase the rate of waste recycling the government is planning to reinforce separate collection system and to provide industries with economic incentives. As a part of meeting the changing situation on global environmental problems after UNCED, and accommodation regulatory measures stipulated in the global environmental conventions and protocols, national policy will try to alter industrial and economic structure so as to mitigate the increasing trends of energy consumption, by encouraging energy conservation and efficiency. In this regard, more attention will be given to the policy on the development of the cleaner technology. Ultimately, these policies and programs will contribute greatly to improving the current state of national public health.

• Transactions of the Korean Society of Automotive Engineers
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• v.22 no.2
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• pp.91-99
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• 2014

The common-rail injectors are the most critical component of the CRDI diesel engines that dominantly affect engine performances through high pressure injection with exact control. Thus, from now on the advanced combustion technologies for common-rail diesel injection engine require high performance fuel injectors. Accordingly, the previous studies on the numerical and experimental analysis of the diesel injector have focused on a optimum geometry to induce proper injection rate. In this study, computational predictions of performance of the diesel injector have been performed to evaluate internal flow characteristics for various needle lift and the spray pattern at the nozzle exit. To our knowledge, three-dimensional computational fluid dynamics (CFD) model of the internal flow passage of an entire injector duct including injection and return routes has never been studied. In this study, major design parameters concerning internal routes in the injector are optimized by using a CFD analysis and Response Surface Method (RSM). The computational prediction of the internal flow characteristics of the common-rail diesel injector was carried out by using STAR-CCM+7.06 code. In this work, computations were carried out under the assumption that the internal flow passage is a steady-state condition at the maximum needle lift. The design parameters are optimized by using the L16 orthogonal array and polynomial regression, local-approximation characteristics of RSM. Meanwhile, the optimum values are confirmed to be valid in 95% confidence and 5% significance level through analysis of variance (ANOVA). In addition, optimal design and prototype design were confirmed by calculating the injection quantities, resulting in the improvement of the injection performance by more than 54%.