• Title/Summary/Keyword: Combustion reactivity

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Preparation of β-SiAlON Powder by Combustion Reaction in the System of Si-Al-SiO2-NH4F(β-Si3N4) (Si-Al-SiO2-NH4F(β-Si3N4)계에서 연소반응에 의한 β-SiAlON분말의 제조)

  • Min, Hyun-Hong;Shin, Chang-Yun;Won, Chang-Whan
    • Journal of the Korean Ceramic Society
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    • v.43 no.10 s.293
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    • pp.595-600
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    • 2006
  • The preparation of $\beta$-SiAlON powder by SHS in the system of $Si-Al-SiO_2-NH_4F(\beta-Si_3N_4)$ was investigated in this study. In the preparation of SiAlON powder, the effect of gas pressure, compositions such as Si, $NH_4F$, \beta-Si_3N_4$ and additive in mixture on the reactivity were investigated. At 50 atm of the initial inert gas pressure in reactor, the optimum composition for the preparation of pure $\beta$-SiAlON was $3Si+Al+2SiO_2+NH_4F$. The $\beta$-SiAlON powder synthesized in this condition was a single phase $\beta$-SiAlON with a rod like morphology.

Effects of Stoichiometry on Properties of NiAl Intermetallics coated on Carbon Steel through Combustion Synthesis (연소합성 코팅된 NiAl 금속간화합물의 화학양론이 미끄럼 마모특성에 미치는 영향)

  • Lee, Han-Young;Lee, Jae-Sung
    • Tribology and Lubricants
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    • v.36 no.3
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    • pp.124-132
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    • 2020
  • The effect of the stoichiometry on the sliding wear properties of NiAl coatings has been investigated. Three different powder mixtures with the compositions of Ni-50at%Al, Ni-54at%Al and Ni-42at%Al were diepressed respectively, and which were subsequently coated on mild steel through combustion synthesis in an induction heating system. Sliding wear behavior of the coatings was examined against an alloyed tool steel using a pin-on-disc type sliding wear test machine. As results, it could be seen that powder mixture(Ni-54at%Al) with displaying Al-rich deviations from the stoichiometry of NiAl(Ni-50at%Al) was promoted the most the synthetic reactivity. The microstructure of the coating layer with the compositions of Ni-54at%Al exhibits the porous NiAl single phase structure. However, the microstructure of the coating layer of the compositions of Ni-42at%Al exhibits the denser multi-phase structure containing several intermediate phases in addition to NiAl. Densification of the coating layer was enhanced by increasing the reacting temperature. On the other hand, the wear properties of the coating layers showed that the wear mode at speeds of around 1 m/s was severe wear, regardless of the stoichiometry and reacting temperature. However, wear properties of coating layer with the compositions of Ni-42at%Al were superior to those of coating layer with the compositions of Ni-54at%Al. This would be attributed by the fact that coating layer with the compositions of Ni-42at%Al develops little void and much intermediate phases with high strength.

Feasibility Study on the Use of CFBC Ash as Non-sintered Binder (순환유동층 보일러애시를 활용한 비소성 결합재로써의 활용 가능성 검토)

  • Kang, Yong Hak;Lim, Gwi Hwan;Kim, Sang Jun;Choi, Young Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.5
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    • pp.119-126
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    • 2018
  • Recently, the production of circulating fluidized bed combustion ash has been increased in thermal power plants. The addition of limestone for the desulfurizing effect of circulating fluidized bed boiler ash increases the content of CaO and $SO_3$ contained in ash, which is higher than the free fly ash in general fly ash. Unlike conventional fly ash, the circulating fluidized bed combustion ash has a high reactivity when it comes into contact with water due to its hydraulic properties and high free-CaO content. The aim of this study is to investigate the possibility of non-sintered binder by using self-cementing properties of circulating fluidized bed combustion ash. The mechanical and hydration characteristics were investigated according to the content of CFBC ash. In addition, the effects of gymsum type and content on the compressive strength and micro-structure of non-sintered binder pastes.

A Study on Combustion and Emission Characteristics of Diesel-DME Blended Fuels in D.I Compression-Ignition Engine (직접분사식 압축착화엔진에서 Diesel-DME 혼합연료의 연소 및 배기특성에 관한 연구)

  • Jeong, Jaehoon;Lim, Ocktaeck;Jeon, Jong Up;Lee, Sangwook;Pyo, Youngduck;Lee, Youngjae;Suh, Hocheol
    • Journal of Hydrogen and New Energy
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    • v.23 no.5
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    • pp.530-537
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    • 2012
  • This work experimentally investigates that Diesel-DME blended fuel influences combustion characteristics and emissions (NOx, CO, HC, smoke) in a single-cylinder DI diesel engine. Diesel is used as a main fuel and DME is blended for the use of its quick evaporating characteristics. Diesel and DME are blended by the method of weight ratio. Weight ratios for Diesel and DME are 95:5 and 90:10 respectively and the both ratios have been used altogether in blended fuel. The experiments are conducted in this study single cylinder engine is equipped with common rail and injection pressure is 700 bar at 1200 rpm. The amount of injected fuels is adjusted to obtain the fixed input calorie value as 972.2 J/cycle in order to compare with the fuel conditions. DME is compressed to 15 bar by using nitrogen gas thus it can be maintained the liquid phase. In this study, different system compared others paper is common rail system, also there is combustion and emission about compared DME and diesel fuel. It is expected to be utilized about blended fuel.

Experimental Investigation into the Combustion Characteristics on the Co-firing of Biomass with Coal as a Function of Particle Size and Blending Ratio (바이오매스(우드펠릿) 혼소율 및 입자크기에 따른 연소 특성에 관한 연구)

  • Sh, Lkhagvadorj;Kim, Sang-In;Lim, Ho;Lee, Byoung-Hwa;Kim, Seung-Mo;Jeon, Chung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.1
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    • pp.31-37
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    • 2016
  • Co-firing of biomass with coal is a promising combustion technology in a coal-fired power plant. However, it still requires verifications to apply co-firing in an actual boiler. In this study, data from the Thermogravimetric analyzer(TGA) and Drop tube furnace(DTF) were used to obtain the combustion characteristics of biomass when co-firing with coal. The combustion characteristics were verified using experimental results including reactivity from the TGA and Unburned carbon(UBC) data from the DTF. The experiment also analyzed with the variation of the biomass blending ratio and biomass particle size. It was determined that increasing the biomass blending ratio resulted in incomplete chemical reactions due to insufficient oxygen levels because of the rapid initial combustion characteristics of the biomass. Thus, the optimum blending condition of the biomass based on the results of this study was found to be 5 while oxygen enrichment reduced the increase of UBC that occurred during combustion of blended biomass and coal.

Effect of Boiler Operating Conditions on the Generation of Unburned Carbon in Anthracite Co-fired 500 MW Thermal Power Plant (무연탄 혼소 500 MW 석탄화력발전소에서 보일러 운전조건이 미연탄소 발생에 미치는 영향)

  • Nam, Jeong-Chul;Yoo, Ho-Seon
    • Plant Journal
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    • v.14 no.3
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    • pp.35-41
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    • 2018
  • Considering the recent government policy toward North Korea and situation of power facilities in North Korea, it will be necessary to prepare for the consumption of the anthracite coal from Korea in coal-fired power plants. In this study, the anthracite co-fired tests in 500 MW thermal power plants were conducted with varying the main operation conditions, such as anthracite injection position in the boiler, coal fineness and combustion air flow, to investigate the effects on the generation of unburned carbon. It was confirmed that the generation of unburned carbon was remarkably reduced when the anthracite coal was injected into the boiler low burner with a relatively long residence time in the main combustion region, and that the increase of the coal fineness proportional to the combustion reaction surface area also reduces the generation of unburned carbon. An increase in the combustion air flow, which increase the combustion reactivity, also contributes to the reduction of unburned carbon. It is possible to maintain the unburned carbon generation below 5 % of the ash recycling quality by controlling the above operating conditions for the given mixing rate of anthracite, and the priority of changing the operating conditions within the test range is the highest for anthracite coal injection position.

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Preparation of AlN Powder by Combustion Reaction in the System of Al-AlN-NH4Cl (Al-AlN-NH4Cl 계에서 연소반응에 의한 AlN 분말의 제조)

  • Min, Hyun-Hong;Won, Chang-Whan
    • Journal of the Korean Ceramic Society
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    • v.43 no.7 s.290
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    • pp.445-450
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    • 2006
  • The preparation of AlN powder by SHS in the system of $Al-AlN-NH_4Cl$ was investigated in this study. In the preparation of AlN powder, the effect of gas pressure and the composition such as Al, AlF, and additive in mixture on the reactivity were investigated. At 60 atm of the initial inert gas pressure in reactor, the optimum composition for the preparation of pure AlN was 35 wt%Al+5 wt% $NH_4Cl+60wt%$AlN. The AlN powder synthesized in this condition was a single phase AlN with a whisker morphology.

Development of Non-cement Material using Recycled Resources (유동층연소방식 석탄재를 활용한 무시멘트 결합재)

  • Mun, Kyoung-Ju;Lee, Min-Hi;Yoon, Seong-Jin
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.11a
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    • pp.156-157
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    • 2014
  • Inorganic binding material was made by recycled resource and its applicability as pile-filling material was examined. The result was that the material had same liquidity with the liquidity of OPC and high reactivity with site soil. According to dynamic/static loading tests by site test-construction, the inorganic binding material met both design bearing capacity and settlement. Since the inorganic binding material showed same or better performance than OPC, the utilization possibility of the inorganic binding material made of recycled resource as pile-filling material was verified.

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Reaction Parameters on the Reactivity in the Preparation of B4C by SHS (자전연소합성법에 의한 B4C분말의 제조에 있어 반응성에 대한 반응변수의 고찰)

  • Shin, Chang-Yun;Yun, Ki-Seok;Park, Yeong-Cheol;Hayk, Nersisyan;Won, Chang-Whan
    • Journal of the Korean Ceramic Society
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    • v.42 no.1
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    • pp.22-27
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    • 2005
  • The preparation of B4C by SHS in $B_{2}O_{3}-Mg-C$ system was investigated in this study. In the preparation of B4C, the effect on reactivity and reaction products of the initial pressure of inert gas in reactor, the content of Mg and C in mixture was investigated. The minimum initial pressure of inert gas in reactor for SHS reaction in this system was 25 atm, and as the pressure increased, the concentration of unreacted Mg decreased and combustion temperature increased. At the initial inert gas pressure in reactor of 25 atm, the optimum composition for the preparation of pure B4C was $2B_{2}O_{3}+6.3Mg +0.94C$. The B4C synthesized in this condition had an irregular shape and the particle size of $1\~3{\mu}m$.

Combustion Characteristics for Co-firing of Biomass (Walnut Shell) (바이오매스(호두껍질) 혼소에 대한 연소 특성에 관한 연구)

  • Kim, Jin-Ho;Lee, Byoung-Hwa;Sh, Lkhagvadorj;Kim, Sang-In;Jeon, Chung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.1
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    • pp.53-59
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    • 2015
  • Combustion characteristics for co-firing of biomass (Walnut Shell) as blending fuel in coal fired boiler have investigated using thermogravimetric analyser (TGA) and drop tube reactor (DTR). The results show that devolatilization and char combustion for WS occurs at lower temperature than those of existing coals and has lower activation energy value, which is resulting in higher reactivity. When the WS is blended with coal, TGA results show linear profiles depending on blending ratio for each fuel. However, DTR results exist the non-additive phenomena for blending of WS. As blending ratio of WS increase, the UBC decrease at BBR 5%, but the UBC rather increase from BBR 10% due to oxygen deficiency formed from rapid combustion of WS. This paper propose that fuel lean condition by oxygen rich lead to higher blending ratio of biomass by solving the oxygen deficiency condition.