• Journal of Energy Engineering
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• v.23 no.4
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• pp.61-72
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• 2014

This paper analyzed transition pathways toward a low carbon society in Korea to meet global $2^{\circ}C$ climate target. Lower economic growth, industrial structure change, enhance of energy demand management, decarbonization of power sector, and replacement of low carbon fuel could reduce greenhouse gas (GHG) emission from fuel combustion in 2050 by 67% against in 2011, or by 74% against in BAU (Business-As-Usual). Lower economic growth contributes to 13% of cumulative emission reduction relative to BAU, industrial structure change 9%, enhance of energy demand management 72%, decarbonization of power sector 5% and replacement of low carbon fuel 1% respectively. Final energy consumption in 2050 needs to be reduced to 50% relative to 2011, or to 41% relative to BAU. Nuclear, coal and renewable energy represent 31%, 40%, 2% respectively among electricity generation in 2011, but 38%, 2%, 32% in 2050. CCS represents 23% of total generation in 2050. Emission intensity of electricity in 2050 was decreased to 19% relative to 2011, or to 24% relative to BAU. Primary energy in 2050 was decreased to 64% compared to 2011, or to 44% compared to BAU. Final energy consumption, primary energy supply and GHG emission from fuel combustion from 1990 to 2011 increased by 176%, 197%, 146%. Radical change from historical trend is required to transit toward a low carbon society by 2050. Appropriate economic growth, structural change to non-energy intensive industries, energy technology research, development and deployment (RD&D) in terms of enhancement of energy efficiency and low carbon energy supply technologies, and fuel change to electricity and renewable energy are key instruments.

• Clean Technology
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• v.27 no.4
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• pp.350-358
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• 2021

The results of this study shows that the combustor temperature ranged from 848.27 to 1,026.80 ℃, averaging about 976.61 ℃, and the NOx concentration increased as the temperature increased. The urea usage ranged from 291.00 to 693.00 kg d^-1, averaging about 542.34 kg d^-1, and the NOx concentration decreased as the urea usage increased. Residence time was about 3.38 to 9.17 s, averaging about 5.22 s, about 2.61 times larger than the 2 s of the design details. This is 1,086 kg h^-1, averaging about 55.71%, compared to the 1,950 kg h^-1 SRF input permission standard. The combustion chamber area is constant, but the residence time is shown to increase with the decrease of exhaust gas. The O₂/CO ratio was 847.05 to 14,877.34, averaging about 3,111.30, and the NOx concentration slightly increased as the O₂/CO ratio increased. As the combustor temperature and O₂/CO ratio increased, the combustion reaction with nitrogen in the air increased and the NOx concentration slightly increased. As the urea usage and residence time increased, the NOx concentration decreased slightly with an increase in reactivity with NOx. The NOx concentration at the stack ranged from 7.88 to 34.02 ppm with an average of 19.92 ppm, and was discharged within the 60 ppm emission limit value. The NOhx emission factor was 1.058 to 1.795 kg ton^-1, averaging about 1.450 kg ton^-1. This value was about 24.87% of the maximum emission factor of 5.830 kg ton^-1 of other solid fuels. Other synthetic resins and industrial wastes were 79.80% and 43.65% compared to 1.817 kg ton^-1 and 3.322 kg ton^-1, respectively. This value was similar to 1.400 kg ton^-1 of RDF in the NIER notice (2005-9), 10.98% compared to the maximum SRF of 13.210 kg ton^-1. Therefore, the NOx emission factor had a large deviation.

• Journal of the Korean Society of Marine Environment & Safety
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• v.18 no.6
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• pp.584-590
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• 2012

In this study, we have conducted a work on homogenizer development which is operated by high shearing force generated by stator and rotor inside it. To investigate the performance for homogenization and atomization of homogenizer, Bunker-C (IFO 380 cSt) was used as a fuel for experiment. Pre-treatment of bunker-C was carried out with homogenizer developed in this study. Oil purifier was used to investigate effect of oil sludge reduction after pre-treatment. Experimental result showed that the amount of sludge of fuel oil after pre-treatment with homogenizer has decreased by 13 %. To confirm combustion efficiency, Bunker-C which have pre-treatment with homogenizer and purified after are burned in boiler system. The result showed that CO concentration in exhaust gas was decreased. These results mean that if the homogenizer which is developed in this study for marine fuel oil is applied on real vessels, oil costs and operating costs can be reduced.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.252.2-252.2
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• 2010

Biomass is considered to be a major potential fuel and renewable resource for the future. In fact, there is high potential to produce the large amount of energy from biomass around the world. In this study, to obtain basic data for practical application of wood pellet and wood pellet boiler system as heating system in agriculture, agricultural biomass resources were surveyed, pellet was made of agricultural by-product such as stem of rape, oat and rice, ricehusk and sawdust and wood pellet boiler system with capacity of 116 kW was manufactured and installed in greenhouse of $38.5m{\times}32m$. High heating value, bulk density and ash content of pellet made of agricultural by-product and efficiency and heating performance of this system was estimated. Rice straw was the largest agricultural biomass in 2005 and the total amount of rice straw converted into energy of $131.71{\times}10^{11}$ kJ. And in 2005, total amount of forest' by-product converted into energy of $29,277.05{\times}10^{11}$ kJ. High heating values of pellets made of agricultural by-products of stem and seed of rape, stem of oat, rice straw and rice husk were 16,034, 16,026, 16,089, 15,650, 15,044 kJ/kg respectively. High heating values of pellets made of agricultural by-products were 83.6% compared to that of wood pellet. Average bulk density of pellets made of agricultural by-products of stem and seed of rape, stem of oat, rice straw and rice husk was 1,400 $kg/m^3$. Ash contents of the pellets were 6.6, 7.0, 6.2, 5.5, 33% respectively. Ash content of rice husk pellet was the largest compared to other kind of pellets. To increase efficiency of agricultural pellet boiler, the boiler adopted secondary heat exchanger. The agricultural pellet boiler designed and manufactured in this study had high efficiency of 84.2% compared to the conventional agricultural pellet boiler, when water flow rate, exhaust gas temperature and average combustion furnace temperature were 39L/min, $180^{\circ}C$, $680^{\circ}C$ respectively. And pellet supplying and pausing time were 13, 43 seconds respectively. In March of 2010, prices of wood pellet, agricultural tax free diesel, diesel, kerosene were 350 won/kg, 811 won/L, 1,422 won/L, 976 Won/L respectively. Also in terms of energy, prices per same heating value were 77.8, 90.1, 158, 108.4 Won/Mcal. Energy saving rate of wood pellet was 16, 50, 39% compared to agricultural tax free diesel, diesel and kerosene respectively.

• Fire Science and Engineering
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• v.33 no.6
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• pp.105-113
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• 2019

This study investigates the toxicity characteristics of two Non-Class 1E Cables (For security reasons, we refer to company A and company B) used in nuclear power plants according to the accelerated deterioration period. In accordance with NES 713 test equipment and standards, tests were carried out on non-aged cables and the cables subjected to 20- and 40-year-accelerated-deterioration; each of the cables was further classified into sheath and insulation. The test results showed that the toxicity indices of 20- and 40-year-accelerated-aged cables were higher than those for the non-aged cables, and 20-year-aged cables of both A and B companies showed the highest toxicity indices. This is attributed to the extensive emissions of carbon monoxide and halide gases such as hydrogen chloride and hydrogen bromide. Furthermore, to analyze the toxicity indices of sheath and insulation in detail, the US Department of Defense standard (MIL-DTL) was applied to determine whether the Toxicity index (T.I.) allowance was exceeded, and the results showed that the insulating materials emitted considerably more than the allowable limit.

• Journal of the Korean Applied Science and Technology
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• v.32 no.2
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• pp.348-361
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• 2015

To reduce the effects of greenhouse gas (GHG) emissions, the government has announced the special platform of technologies as parts of an effort to minimize global climate change, and the government distributed biodiesel since 2006 as the further efforts. Although there are some debates about some quality specifications and unbalanced of source (44% from palm oil), more than 400kton/year of biodiesel was produced in 2013. Moreover the amounts will be increased when the RFS is activated. To solve the unbalanced situation and to achieve the diversity of feeds, it is essential that many researches should be considered. Especially, free and bond glycerines are one of the important properties seriously affected to the combustion system in vehicle & cold properties. Previous method (KS M 2412) couldn't cover the biodiesel derived from lauric oil($C_{12:0}$) such as PKO (Palm Kernel Oil), Coconut oil because those compositions are lighter than other conventional biodiesel sources. In this study, we review the existed method and figure out the factors should improve to analysis the glycerine from PKO and Coconut oil biodiesel. Modifying the analysis conditions to enhance the resolution and change the internal standards to avoid the overlapped- peaks between Capric acid ME ($C_{10:0}$) and standard#1(1,2,4-butantriol). From this revised method, we could solve the restrictions of previous methods. And check the possibility of new method to analyze the glycerine in biodiesel regardless of sources.

• Applied Chemistry for Engineering
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• v.7 no.5
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• pp.999-1005
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• 1996

Pt catalyst on carbon black was prepared by colloidal method, ion exchanging method and methanol reducing method. The colloidal method has been used generally. At ion exchanging method, $H^+$ of functional group on carbon surface made by oxidation treatment was exchanged with Pt ion. At methanol reducing method, Pt was impregnated on carbon to reduce by methanol contained with surfactants. With TEM and XRD, Pt particle size impregnated on carbon by various methods was $30{\sim}50{\AA}$. Loading yield was about 100%, loading yield of ion exchanging method was 99.92% by DCP analysis and 99.87% by combustion method. Within 60 hour, current density of oxygen reduction was $460mA/cm^2$ at 0.7V(vs. RHE) at colloidal method. It was the better performance than catalyst prepared by ion exchanging, methanol reducing method. But, it was shown some decrease of performance for long operation time(after 100hour), catalyst prepared by methanol reducing method was shown stable performance.

• Journal of Korean Society for Atmospheric Environment
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• v.26 no.5
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• pp.507-516
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• 2010

Stationary combustion sources such as coal-fired power plants, waste incinerators, industrial manufacturing, etc. are recognized as major sources of mercury emissions. Due to rapid economic growth, zinc production in Korea has increased significantly during the last 30 years. Total zinc production in Korea exceeded 739,000 tons in 2008, and Korea is currently the third largest zinc producing country in the world. Previous studies have revealed that zinc smelting has become one of the largest single sectors of total mercury emissions in the World. However, studies on this sector are very limited, and a large gap in the knowledge regarding emissions from this sector needs to be bridged. In this paper, Hg emission measurements were performed to develop emission factors from zinc smelting process. Stack sampling and analysis were carried out utilizing the Ontario Hydro method and US EPA method 101A. Preliminary data showed that $Hg^0$ concentrations in the flue gas ranged from 4.56 to $9.90\;{\mu}g/m^3$ with an average of $6.40\;{\mu}g/m^3$, Hg(p) concentrations ranged from 0.03 to $0.09\;{\mu}g/m^3$ with an average of $0.04\;{\mu}g/m^3$, and RGM concentrations ranged from 0.23 to $1.17\;{\mu}g/m^3$ with an average of $6.40\;{\mu}g/m^3$. To date, emission factors of 7.5~8.0 g/ton for Europe, North America and Australia, and of 20 or 25 g/ton for Africa, Asia and South America are widely accepted by researchers. In this study, Hg emission factors were estimated using the data measured at the commercial facilities as emissions per ton of zinc product. Emission factors for mercury from zinc smelting pross ranged from 4.32 to 12.96 mg/ton with an average of 8.31 mg/ton. The emission factors that we obtained in this study are relatively low, considering Hg contents in the zinc ores and control technology in use. However, as these values are estimated by limited data of single measurement of each, the emission factor and total emission amount must be updated in future.

• Journal of Bio-Environment Control
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• v.11 no.3
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• pp.101-107
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• 2002

This study was carried out to improve the performance of heat recovery device attached to exhaust gas flue connected to combustion chamber of greenhouse heating system. Three different units were prepared far the comparison of heat recovery performance; A-type is exactly the same with the typical one fabricated for previous study of analyzing heat recovery performance in greenhouse heating system, other two types (B-type and C-type) modified from the control unit are different in the aspects of airflow direction (U-turn airflow) and pipe arrangement. The results are summarized as follows ; 1. In the case of Type-A, when considering the initial cost and current electricity fee required for system operation, it was expected that one or two years at most would be enough to return the whole cost invested. 2. Type-B and Type-C, basically different with Type-A in the aspect of airflow pattern, are not sensitive to the change of blower capacity with higher than 25m$^3$.min$^{-1}$ . Therefore, heat recovery performance was not improved so significantly with the increment of blower capacity. This was assumed to be that air flow resistance in high air capacity reduced the heat exchange rate as well. Never the less, compared with control unit, resultant heat recovery rate of Type-B and Type-C was improved by about 5％ and 13％, respectively 3. Desirable blower capacity of these heat recovery units experimented were expected to be about 25m$^3$.min$^{-1}$ , and at the proper blower capacity, U-turn airflow units showed better heat recovery performance than control unit. But, without regard to the type of heat recovery unit, it was recommended that comprehensive consideration of system's physical factors such as pipe arrangement density, unit pipe length and pipe thickness, etc., was required for the optimization of heat recovery system in the aspects of not only energy conservation but economic system design.

• Journal of the Korea Organic Resources Recycling Association
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• v.20 no.3
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• pp.27-33
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• 2012

According to the statistics of the Ministry of Environment, the emission of sewage sludge is increased by 7~9% yearly. In the future, it will be increased continuously because of extension of sewage disposal plants, high class treatment for removing nitrogen and phosphorus. Until now, we have depended on reclamation for lots of quantity and some part has been treated by ocean emission. But, direct reclamation of organic waste will be prohibited and even ocean emission will be prohibited now, so the treatment of sludge is put on emergency alert. Bio-gas can be produced by applying anaerobic digestion method for the recycling or refuse derived fuel can be conducted by applying carbonization method. However, the process is difficult, causes bad smell and makes it the second waste, so it cannot be practical method in fact. This study applied a fluidized bed combustor for sewage sludge treatment technologies that can actually take advantage of key technologies in order to verify its purpose is to demonstrate selected. If applying the fluidized bed combustor, it can be easily utilized as the replaced resource of energy(fuel) in the countries whose energy resources are insufficient, like our country. Especially, if applying only original strengths of the fluidized bed combustor sufficiently, the sewage sludge can be treated simply, eco-friendly, sanitarily and economically. Particularly, it is verified as the energy technology suitable for government's green growth policy.