• 제목/요약/키워드: Coefficient of Bonding

검색결과 159건 처리시간 0.031초

무전해도금 및 방전 플라즈마 소결을 이용한 구리/흑연 복합재료 제조 및 열물성 특성 평가 (Thermophysical Properties of Copper/graphite Flake Composites by Electroless Plating and Spark Plasma Sintering)

  • 이재성;강지연;김슬기;정찬회;이동주
    • 한국분말재료학회지
    • /
    • 제27권1호
    • /
    • pp.25-30
    • /
    • 2020
  • Recently, the amount of heat generated in devices has been increasing due to the miniaturization and high performance of electronic devices. Cu-graphite composites are emerging as a heat sink material, but its capability is limited due to the weak interface bonding between the two materials. To overcome these problems, Cu nanoparticles were deposited on a graphite flake surface by electroless plating to increase the interfacial bonds between Cu and graphite, and then composite materials were consolidated by spark plasma sintering. The Cu content was varied from 20 wt.% to 60 wt.% to investigate the effect of the graphite fraction and microstructure on thermal conductivity of the Cu-graphite composites. The highest thermal conductivity of 692 W m-1K-1 was achieved for the composite with 40 wt.% Cu. The measured coefficients of thermal expansion of the composites ranged from 5.36 × 10-6 to 3.06 × 10-6K-1. We anticipate that the Cu-graphite composites have remarkable potential for heat dissipation applications in energy storage and electronics owing to their high thermal conductivity and low thermal expansion coefficient.

만성요통환자가 지각하는 가족기능과 우울의 관계 (The Relationship between Perceived Family Functioning and Depression in Patients with Chronic Low-Back Pain)

  • 손정태;박현숙
    • 기본간호학회지
    • /
    • 제7권2호
    • /
    • pp.316-331
    • /
    • 2000
  • This study was conducted using a descriptive correlational survey design to identify how patients with chronic low-back pain perceived family function and to examine the relationship between family function and depression. The participants of the study were 116 patients with chronic low-back pain patient who were having follow-up treatment in a local pain clinic, located in Daegu. A structured questionnaire was filled out participants themselves and the structured interview was given during January and February, 2000. The data collection instrument were FACE II-Korean version and Beck's Depression Inventory(1983). The data collected were analysed using mean, standard deviation(SD), t-test, F-test, Duncan test and Pearson correlation coefficient, done with SAS. The results are as follows; 1. The mean of the respondents' perceived family function was 3.47, with emotional bonding at 3.61, acceptability and sharing at 3.61, participation at 3.23, negotiation and satisfaction at 3.24 and responsibility and expectation at 3.76. 2. The mean of the respondents' perceived depression was $17.53{\pm}8.76$. 3. There was significantly negative correlation between family function and depression(r=-0.4817, p=.0001). 4. Research variables included demographic characteristics and showed that subjects who were aged 65 years or older showed significantly lower scores in patient's perceived family function than those who were aged 45 years or below(p=.0502). Perceived family function of females respondents were significantly lower than males(p=.0026). The illiterate showed significantly lower scores than other groups(p=.0001). Respondents with spouse and extended family tended to show significantly higher scores than those who were living with spouse only or by themselves alone(p=.0091). Those who had higher income showed significantly higher scores than in the lower income group(p=.0001). 5. For family function regarding pain characteristics, those who reported severe pain-related daily activity impediments showed significantly lower scores in family function than others with less pain(p=.0357).

  • PDF

의료용 폴리머 소재를 활용한 3D 프린팅 인공치아용 사면체 비정질 카본 코팅 기술 연구 (A Study on the Tetrahedral Amorphous Carbon (ta-C) Coating on Medical Polymer Materials for 3D Printing Artificial Teeth)

  • 장영준;김종국;신창희;유성미
    • Tribology and Lubricants
    • /
    • 제38권6호
    • /
    • pp.255-260
    • /
    • 2022
  • This research presents tetrahedral amorphous (ta-C) coating on the artificial tooth for improving the durability and functionality (esthtics, foreign body of tooth) by filtered cathodic vacuum arc (FCVA). A differentiated coating method is required for a ta-C coating on polymer owing to the low melting point of the polymer, inter-facial adhesion, low friction, and non-conductivity. Herein, ta-C coating is applied below 50℃, and the potential difference of the carbon plasma drawn to the substrate was controlled by applying a positive duct bias voltage without using a substrate bias voltage. Consequently, the ta-C coating with a thickness of 70nm using the duct bias condition of 20V with the highest plasma intensity satisfies the esthetics of the artificial tooth and had a 5B level of inter-facial adhesion. In addition, the composite hardness of ta-C/polymer is 380 MPa, and correlations with esthetics, sp3 bonding, and mechanical properties. The friction coefficient (CoF) of the ta-C coating in a water-lubricated environment is 0.07, showing a six-fold reduction in CoF compared with that of a polymer.

Donor-Acceptor 발색단과 디케토피롤로피롤(DPP) 유도체에 관한 연구 (The Study of Donor-Acceptor Chromophores and Diketopyrrolopyrrole(DPP) Analogues)

  • 김헌수;김승회;박수열
    • Tribology and Lubricants
    • /
    • 제32권5호
    • /
    • pp.141-146
    • /
    • 2016
  • The diketopyrrolopyrrole (DPP) pigment is a bicyclic 8-π-electron system containing two lactam units. Typical DPP derivative pigments have melting points of over 350°C and very low solubility in most solvents, and show absorption in the visible region with a molar extinction coefficient of 33,000 dm2mol−1 and strong photoluminescence with maxima in the range 500–600 nm. X-ray structure analyses of DPP show that the whole molecule is almost in one plane. The phenyl rings are twisted out of the heterocyclic plane and the intermolecular hydrogen bonding between neighboring lactam NH and carbonyl units influences the structure of the DPP pigment in the solid state. In this study, mono-N-alkylation and mono-N-arylation were undertaken for Pigment Red 264 or Pigment Orange 73 with alkyl halide and aryl halide, respectively, in the presence of sodium tert-butoxide as a base catalyst to improve the solubility of DPP pigments and their application as CO2 indicators. The synthetic yield was in the range 11–88%. The indicator dyes are highly soluble in organic solvents and shows pH-dependent absorption (λmax 501 and 572 nm for the protonated and deprotonated forms, respectively) and emission (λmax 524 and 605 nm for the protonated and deprotonated forms, respectively) spectra. The mono-N-alkylated and mono-N-arylated DPP pigment was identified by 1H-NMR (1H-Nuclear Magnetic Resonance Spectrometer), FT-IR (Fourier Transform Infrared Spectroscopy), and MS (Mass Spectrometry). According to the results of color and hue properties obtained by a color matching analyzer, the synthesized DPP pigment material can be used as a CO2 indicator.

청소년의 스마트폰 중독에 영향을 미치는 요인 (Factors Influencing Smartphone Addiction in Adolescents)

  • 이은지;김윤경;임수진
    • Child Health Nursing Research
    • /
    • 제23권4호
    • /
    • pp.525-533
    • /
    • 2017
  • Purpose: The purpose of this study was to verify the relationship among depression, school adjustment, parent-child bonding, parental control and smartphone addiction, and to identify factors which influence smartphone addiction in adolescents. Methods: A cross-sectional design was used, with a convenience sample of 183 middle school students from 3 middle schools. Data collection was conducted through self-report questionnaires from April to May, 2017. Data were analyzed using ${\chi}^2$ test, Fisher's exact test, t-test, one-way ANOVA, correlation coefficient analysis, and binary logistic regression with SPSS Ver. 21.0. Results: The mean score for smartphone addiction was 29.40. Of the adolescents, 21.3% were in the smartphone addiction risk group. Logistic regression analysis showed that gender (OR=7.09, 95% Cl: 2.57~19.52), school life (OR=0.86, 95% Cl: 0.79~0.93), smartphone usage time (OR=1.32, 95% Cl: 1.04~1.66), and parental control (OR=4.70, 95% Cl: 1.04~21.29) were effect factors for the smartphone addiction risk group. Conclusion: Findings indicate that school satisfaction was an important factor in adolescents' smartphone addiction. Control oriented parent management of adolescents' smartphone use did not reduce the risk of smartphone addiction and may have worsen the addiction. Future research is needed to improve understanding of how teachers and parents will manage their adolescents' use of smartphones.

유체의 정확한 온도 측정을 위하여 내부 센서를 집적한 마이크로채널 제작 (Fabrication of the Microchannel Integrated with the Inner Sensors for Accurate Measuring Fluid Temperature)

  • 박호준;임근배;손상영;송인섭;박정호
    • 대한전기학회논문지:전기물성ㆍ응용부문C
    • /
    • 제51권9호
    • /
    • pp.449-454
    • /
    • 2002
  • A rectangular straight microchannel, integrated with the resistance temperature detectors(RTDs) for temperature sensing and a micro-heater for generating the Temperature gradient along the channel, was fabricated. Its dimension is 57${\mu}{\textrm}{m}$(H)$\times$200${\mu}{\textrm}{m}$(W)$\times$48,050${\mu}{\textrm}{m}$(L), and RTDs were placed at the inner-channel wall. Si wafer was used as a substrate. For the fabrication of RTDs, 5300$\AA$ thick Pt/Ti layer was sputtered on a Pyrex glass wafer. Finally, the glass wafer was bonded with Si wafer by anodic bonding, so that the RTDs are located inside the microchannel. Temperature coefficient of resistance(TCR) values of the fabricated Pt-RTDs were 2800~2950ppm$^{\circ}C$ and the variation of TCR value In the range of O~10$0^{\circ}C$ was less than 0.3%. Therefore, it was proved that the fabricated Pt-RTDs without annealing were excellent as temperature sensors. The temperature distribution in the microchannel was investigated as a function of mass flow rate and heating power. The temperature increase rate diminished with decreasing the applied power and increasing the mass flow rate. It was confirmed from the comparison with the simulation results that the temperature measured inside the microchannel is more accurate than measuring the temperature measured at the outer wall. The proposed temperature sensing method and microchannel are expected to be useful in microfluidics researches.

초음파 수침법을 이용한 터빈베어링 Babbitt금속 박리 검사 기술 (Implementation of Ultrasonic Immersion Technique for Babbitt Metal Debonding in Turbine Bearing)

  • 정계조;박상기;조용상;박병철;길두송
    • 비파괴검사학회지
    • /
    • 제24권4호
    • /
    • pp.348-353
    • /
    • 2004
  • 이 연구는 터빈베어링의 신뢰성을 평가하기 위하여 초음파 C-Scan 방법을 적용한 기술이다. 수침법에 관한 연구는 실험실과 현장검사 적용에 광범위하게 사용되는 기술이다. 여기에서는 C-Scan 방법을 이용하여 베어링의 모재와 Babbitt 금속간 경계부의 상태를 평가하였다. 수침법 C-Scan 방법에 의한 초음파 영상은 베어링 경계부의 상태를 확인하는데 효과적인 방법으로 사용될 수 있었다. 초음파 영상의 분해능을 높이기 위하여 집속형 탐촉자를 사용하고, Babbitt 금속과 베어링 모재간의 접합경계면에서 발생하는 초음파 음압 반사율을 측정하여 결함의 검출과 면적을 추정할 수 있었다. 초음파 수침법은 베어링 접합부의 박리위치와 박리면적의 경계면을 결정하여 크기를 계산하는데 아주 유용하게 사용될 수 있는 기술이며, 이 연구에서 개발된 기술은 화력발전소에서 사용되고 있는 터빈베어링의 건전성을 확보하는데 적용되었다.

열확산처리 공정에 의한 순수 타이타늄의 표면특성 향상 연구 (Improvement of Surface Properties of CP-Titanium by Thermo-Chemical Treatment (TCT) Process)

  • 정현경;이동근;;이용태;허보영
    • 대한금속재료학회지
    • /
    • 제49권9호
    • /
    • pp.692-698
    • /
    • 2011
  • The thermo-chemical treatment (TCT) process was applied to achieve surface hardening of CP titanium. The following three different surface modification conditions were tested so that the best surface hardening process could be selected:(a) PVD, (b) TCT+PVD, and (c) TCT+Aging+PVD. These specimens were tested and analyzed in terms of surface roughness, wear, friction coefficient, and the gradient of hardening from the surface of the matrix. The three test conditions were all beneficial to improve the surface hardness of CP titanium. Moreover, the TCT treated specimens, that is, (b) and (c), showed significantly improved surface hardness and low friction coefficients through the thickness up to $100{\mu}m$. This is due to the functionally gradient hardened surface improvement by the diffused interstitial elements. The hardened surface also showed improvement in bonding between the PVD and TCT surface, and this leads to improvement in wear resistance. However, TCT after aging treatment did not show much improvement in surface properties compared to TCT only. For the best surface hardening on CP titanium, TCT+PVD has advantages in surface durability and economics.

과부하 방지용 마이크로머시닝 세라믹 박막형 압력센서의 제작과 그 특성 (Fabrication of a micromachined ceramic thin-film type pressure sensor for high overpressure tolerance and Its characteristics)

  • 김재민;정귀상
    • 센서학회지
    • /
    • 제12권5호
    • /
    • pp.199-204
    • /
    • 2003
  • 본 논문에서는 Ta-N 스트레인게이지를 이용한 극한 환경용 세라믹 박막형 압력센서의 제작 및 특성에 관하여 연구하였다. 압력감지부로 Ta-N 스트레인게이지를 사용하였으며, SDB(Si-wafer Direct Bonding)와 전기화학적 식각정지법을 이용하여 매몰 cavity를 가지는 저가격 고수율의 Si 박막 다이어프램을 제작하였다. 또한, 실리콘 박막 다이어프램상에 박막형 스트레인게이지를 형성하여 세라믹 박막형 압력센서를 제작하였다. 제작된 세라믹 박막형 압력 센서는 기존의 스트레인 게이지를 이용한 로드셀에 비해서 온도특성이 우수하고 재현성, 소형화, 집적화 및 저가격화가 가능하기 때문에 고온, 고압 등의 각한 환경에서도 사용이 가능할 것으로 기대된다.

알칼리금속이 흡착된 Si(111)$7\times7$ 계의 초기 산화 과정 연구 (Initial oxidation of the alkali metal-adsorbed Si(111) surface)

  • 황찬국;안기석;김정선;박래준;이득진;장현덕;박종윤;이순보
    • 한국진공학회지
    • /
    • 제6권2호
    • /
    • pp.159-164
    • /
    • 1997
  • X-선 광전자 분광법 (x-ray photoelectron spectroscopy: SPS)과 반사 고에너지 전 자 회절법(reflection high energy electron diffraction: RHEED)을 이용하여 상온과 고온(약 300~$500^{\circ}C$)에서 알칼리금속(AM)/Si(111)7$\times$7표면에 1 monolayer(ML)의 AM을 흡착시키면 Si(111)7$\times$7표면에 비해 산소의 초기 부착 계수(initial sticking coefficient)와 산소의 포화량 은 증가하지 않았다. Si(111)7$\times$7-AM표면에 산소의 주입량을 증가시키면서 측정한 O ls 스 펙트럼으로부터 AM이 흡착된 Si(111)7$\times$7표면에 흡착되는 산소원자는 Si-O, AM-O 두 종 류의 결합형태를 가지는 것으로 생각되며 이중에서 AM-O 결합의 산화과정상에서의 역할 에 대하여 논의하였다. 상온과는 달리 고온에서는, Si(111)3$\times$1-AM표면으로 구조가 변화하 면서 산소의 흡착이 급격히 떨어지는 것을 관측할 수 있었다. 이때 3$\times$1-AM표면을 형성시 키는 AM종류의 산화에 대한 의존성을 살펴보았다.

  • PDF