• 한국화재소방학회논문지
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• 제28권5호
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• pp.52-57
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• 2014

구조용 강재는 고온 시 물질 내부의 구성 물질의 결합력 약화로 인하여 내력과 변형이 추가적으로 발생됨으로써, 구조적 성능이 저하되고, 국부 및 연속적 붕괴로 이어질 수 있다. 따라서 강재로 구성된 구조부재는 화재 시 열영향부를 최소화하기 위한 수단이 강구되는 내화설계가 요구된다. 건축용 내화강재(FR 490)는 용접 구조용 강재(SM 490)와 상온시 특성은 동일하나, 고온 시의 내력유지 성능이 우수한 강종으로써 이로 구성된 보부재의 고온 시 내력 평가 자료는 거의 없다. 따라서 본 연구에서는 FR 490강재로 구성된 보부재의 고온 시 거동을 고온 시 재료 특성과 이론적 방법을 통하여 해석적으로 평가하고, 이를 SM 490강재보와 비교함으로써 내화성능을 확인하고자 하였으며, 그 결과 FR 490강재보의 경우 SM 490강재보에 비해서 고온 시 내력유지 성능이 우수하였다.

• 한국건설순환자원학회논문집
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• 제3권2호
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• pp.122-131
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• 2015

본 논문에서는 국내 외 관련 문헌 자료 및 규정에 대한 고찰과, 20년 이상 된 수조 구조물 현장의 사례 조사를 통해 수밀 콘크리트와 침투방지재의 염소이온 투과에 대한 실험적 평가 등을 통하여 결론을 도출하고. 방수층 및 부식저항기술을 음용수조 구조물(상수조 등)의 각 시설물별 방수 방식에 대한 성능을 동시에 만족하여야 할 필요성을 정립하는 것이다. 이는 수조 구조물들이 방수 및 침투방지재가 확실히 필요하다는 사실을 확언 할 수 있고, 또한 여러 가지의 콘크리트 침식을 발생시키는 요소와 원인들에서부터 장기적인 내구성을 화보할 수 있다.

• 한국세라믹학회지
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• 제52권5호
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• pp.366-373
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• 2015

Sol-gel binder was prepared by hydrolysis and condensation reaction using boehmite sol and methyltrimethoxysilane as a function of aging-time. The coating slurry was composed of a plate-shape alumina in the sol-gel binder for the EPD process, in which particles dispersed in the slurry were deposited on the electrode under an electric field due to the surface charge. We studied the effects of three parameters: the content of boehmite, the aging time, and the applied voltage, on the physical, thermal, and electrical properties of the hybrid composite films by EPD. The amount of boehmite was 10 ~ 20 wt% and the aging time was 0.5 ~ 72, with a fixed amount of plate-shape alumina of 10 wt%. The condition of applied voltage was 5 ~ 30 V with a distance of 2 cm between the electrode during the EPD process. We confirmed that a structure of hybrid composite films of well-ordered plate alumina was deposited on the substrate when the film was prepared using a sol-gel binder composed of 15 wt% boehmite with 1 hr aging time and EPD at 10 V. The process shows a weight loss of 7% at $500^{\circ}C$ in TGA and a breakdown voltage of 8 kV at $87{\mu}m$.

• 한국건설순환자원학회논문집
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• 제8권2호
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• pp.175-182
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• 2020

철근 부식으로 인한 철근 콘크리트 구조물의 내구성능 저하를 방지하는 방법 중 하나인 에폭시 도막 철근의 사용이 증가하고 있으나, 에폭시 도막으로 인한 콘크리트와 철근의 부착성능 부족으로 정착길이 및 겹침이음길이를 증가시켜야하는 것이 문제가 된다. 이 논문은 에폭시 도막 철근의 부착성능을 개선하여 직접인발시험에서 확인한 기본정착길이의 감소 가능성을 실제 휨부재의 이음길이 산정에 반영할 수 있는지를 확인하기 위하여 수행한 실험연구를 정리한 것이다. 휨부재에서 일반철근과 에폭시 도막 철근의 겹침이음 특성을 비교하기 위하여 철근지름 및 겹침이음길이를 변수로 하여 36개의 시험체로 보-단부 실험을 통해 겹침 이음 성능평가를 하였다. 실험결과에 의하면 현행설계기준에 따라 이음길이에 보정계수 1.2를 사용한 에폭시 도막 철근 부착강도와 일반철근 부착강도를 비교한 결과 파괴 양상, 처짐특성 및 균열폭 등을 고려할 때 현행 설계기준에 따른 보정계수의 필요성을 확인하였다.

• Journal of Microbiology and Biotechnology
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• 제22권7호
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• pp.1015-1020
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• 2012

Antifungal cement mortar or microbiological calcium carbonate precipitation on cement surface has been investigated as functional concrete research. However, these research concepts have never been fused with each other. In this study, we introduced the antifungal calcite-forming bacteria (CFB) Bacillus aryabhattai KNUC205, isolated from an urban tunnel (Daegu, South Korea). The major fungal deteriogens in urban tunnel, Cladosporium sphaerospermum KNUC253, was used as a sensitive fungal strain. B. aryabhattai KNUC205 showed $CaCO_3$ precipitation on B4 medium. Cracked cement mortar pastes were made and neutralized by modified methods. Subsequently, the mixture of B. aryabhattai KNUC205, conidiospore of C. sphaerospermum KNUC253, and B4 agar was applied to cement cracks and incubated at $18^{\circ}C$ for 16 days. B. aryabhattai KNUC205 showed fungal growth inhibition against C. sphaerospermum. Furthermore, B. aryabhattai KNUC205 showed crack remediation ability and water permeability reduction of cement mortar pastes. Taken together, these results suggest that the $CaCO_3$ precipitation and antifungal properties of B. aryabhattai KNUC205 could be used as an effective sealing or coating material that can also prevent deteriorative fungal growth. This study is the first application and evaluation research that incorporates calcite formation with antifungal capabilities of microorganisms for an environment-friendly and more effective protection of cement materials. In this research, the conception of microbial construction materials was expanded.

• 한국표면공학회지
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• 제49권3호
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• pp.301-306
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• 2016

The effects of nanotexturing and post-etching on the reflection and quantum efficiency properties of diamond wire sawn (DWS) multicrystalline silicon (mc-Si) solar cell have been investigated. The chemical solutions, which are acidic etching solution (HF-$HNO_3$), metal assisted chemical etching (MAC etch) solutions ($AgNO_3$-HF-DI, HF-$H_2O_2$-DI) and post-etching solution (diluted KOH at $80^{\circ}C$), were used for micro- and nano-texturing at the surface of diamond wire sawn (DWS) mc-Si wafer. Experiments were performed with various post-etching time conditions in order to determine the optimized etching condition for solar cell. The reflectance of mc-Si wafer texturing with acidic etching solution showed a very high reflectance value of about 30% (w/o anti-reflection coating), which indicates the insufficient light absorption for solar cell. The formation of nano-texture on the surface of mc-Si contributed to the enhancement of light absorption. Also, post-etching time condition of 240 s was found adequate to the nano-texturing of mc-Si due to its high external quantum efficiency of about 30% at short wavelengths and high short circuit current density ($J_{sc}$) of $35.4mA/cm^2$.

• 한국산학기술학회논문지
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• 제7권6호
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• pp.1302-1307
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• 2006

본 연구는 고효율의 광촉매 제조와 그것의 환경적 응용에 관한 것이다. 가시광 영역에서도 $TiO_2$와 유사한 빛 흡수와 광분해속도를 갖는 나노 광촉매를 제조하였고, 낮은 온도에서도 활성 높은 rutile상이 형성하는 $TiO_2$ 광촉매를 제조하여 $SiO_2$위에 분산시켰다 또한, 광촉매에 적용 가능한 바인더와 안정한 $TiO_2$ 광촉매 졸을 제조하였다. 이와같은 물질들은 자외선/가시광선 분광광도계, X선 회절분석기, SEM, 광촉매활성 측정과 $TiO_2$ 코팅 표면의 물성으로 평가하였다. 이 결과들은 공기정화를 위하여 POF나 금속판을 이용하는 효율적인 광촉매 시스템에 적용 할 수 있다.

• 한국표면공학회지
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• 제38권3호
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• pp.106-111
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• 2005

Ternary Ti-B-C coatings were synthesized on WC-Co and Si wafers substrates by a PECVD technique using a gaseous mixture of $TiCl_4,\;BCl_3,\;CH_4,\;Ar,\;and\; H_2$. The effects of deposition variables such as substrate temperature, gas ratio, $R_x=[BCl_3/(CH_4+BCl_3)]$ on the microstructure and mechanical properties of Ti-B-C coatings were investigated. From our instrumental analyses, the synthesized Ti-B-C coatings was confirmed to be composites consisting of nanocrystallites TiC, quasi-amorphous TiB2, and amorphous carbon at low boron content, on the contrary, nanocrystallites $TiB_2$, quasi-amorphous TiC, and amorphous carbon at relatively high boron content. The microhardness of the Ti-B-C coatings increased from $\~23 GPa$ of TiC to $\~38 GPa$ of $Ti_{0.33}B_{0.55}C_{0.11}$ coatings with increasing the boron content. The $Ti_{0.33}B_{0.55}C_{0.11}$ coatings showed lower average friction coefficient of 0.45, in addition, it showed relatively better wear behavior compared to other binary coatings of $TiB_2$ and TiC. The microstruture and microhardness value of Ti-B-C coatings were largely depend on the deposition temperature.

• 한국표면공학회지
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• 제38권3호
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• pp.95-99
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• 2005

Quaternary Ti-Cr-Si-N coatings were synthesized onto steel substrates (SKD 11) using a hybrid method of arc ion plating (AIP) and sputtering techniques. For the Syntheses of Ti-Cr-Si-N coatings, the Ti-Cr-N coating process was performed substantially by a multi-cathodic AIP technique rising Cr and Ti targets, and Si was added by sputtering Si target during Ti-Cr-N deposition. In this work, comparative studies on microstructure and evaluation of mechanical properties between Ti-Cr-N and Ti-Cr-Si-N coatings were conducted. As the Si was incorporated into Ti-Cr-N coatings, the Ti-Cr-Si-N coatings showed largely increased hardness value of approximately 42 GPa than one of 28 GPa for Ti-Cr-N coatings. The average friction coefficient of Ti-Cr-N coatings largely decreased from 0.7 to 0.35 with increasing Si content up to 20 at. $\%$. In addition, wear behavior of Ti-Cr-N coatings against steel ball was much improved with Si addition due to the surface smoothening effect and tribe-chemical reaction.

• E2M - 전기 전자와 첨단 소재
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• 제10권2호
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• pp.134-140
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• 1997

PbTiO$_{3}$-PbZrO$_{3}$-Pb(Ni$_{1}$3/Nb $_{2}$3/O$_{3}$)(PZT-PNN) thin films were prepared from corresponding metal organics partially stabilized with diethanolamine by the sol-gel spin coating method. Each mol rates of PT:PZ:PNN solutions were #1(50:40:10), #2(50:30:20), #3(45:35:20) and #4(40:40:20), respectively. The spin-coated PZT-PNN films were sintered at the temperature from 500.deg. C to 600.deg. C for crystallization. The P-E hysteresis curve was drawn by Sawyer-Tower circuit with PZT-PNN film. The coercive field and the remanent polarization of #4(40:40:20 mol%) PZT-PNN film were 28.8 kV/cm and 18.3 .mu.C/cm$^{2}$, respectively. Their dielectric constants were shown between 128 and 1120, and became maximum value in MPB(40:40:20 mol%). The leakage currents of PZT-PNN films were about 9.4x 10$^{-8}$ A/cm$^{2}$, and the breakdown voltages were about 0.14 and 1.1 MV/cm. The Curie point of #3(45:35:20 mol%, sintered at 600.deg. C) film was 330.deg. C.