• Journal of the Korean Ceramic Society
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• v.27 no.6
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• pp.755-762
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• 1990

The tungsten paste was printed on the surface of 92% alumina sheet which was made by type casting process. The printed tungsten was bonded on the Al2O3 by co-firing in reducing atmosphere. During the co-firing, the binder burn-out was easier in wet H2 atmosphere than in dry H2, which affected sintered density. In practically, the use of wet H2 above 100$0^{\circ}C$ was beneficial for density of alumina and bond strength. This phenomena occured more distinctly when atmosphere varied from dry H2 to wet H2 than varied dew point in wet H2. In wet H2, the improvement in bonding strength can be attributed to good glass migration into the metal layer due to inhibition of the tungsten particle growth, with increase of alumina density, at the temperatrue higher than 100$0^{\circ}C$.

• Korean Chemical Engineering Research
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• v.55 no.3
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• pp.436-442
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• 2017

Fischer-Tropsch synthesis is the technology of converting a syngas (CO+$H_2$) derived from such as coal, natural gas and biomass into a hydrocarbon using a catalyst. The catalyst used in the Fischer-Tropsch synthesis consists of active metal, promoter and support. The types of these components and composition affect the reaction activity and product selectivity. In this study, we manufactured an iron catalyst using ${\gamma}-Al_2O_3/SiO_2$ mixed support (100/0 wt%, 75/25 wt%, 50/50 wt%, 25/75 wt%, 0/100 wt%) by an impregnation method to investigate how the composition of ${\gamma}-Al_2O_3/SiO_2$ mixed support effects on the reaction activity and product selectivity. The physical properties of catalyst were analyzed by $N_2$ physical adsorption and X-Ray diffraction method. The Fischer-Tropsch synthesis was conducted at $300^{\circ}C$, 20bar in a fixed bed reactor for 60h. According to the results of the $N_2$ physical adsorption analysis, the BET surface area decreases as the composition of ${\gamma}-Al_2O_3$ decreases, and the pore volume and pore average diameter increase as the composition of ${\gamma}-Al_2O_3$ decreases except for the composition of ${\gamma}-Al_2O_3/SiO_2$ of 50/50 wt%. By the results of the X-Ray diffraction analysis, the particle size of ${\alpha}-Fe_2O_3$ decreases as the composition of ${\gamma}-Al_2O_3$ decreases. As a result of the Fischer-Tropsch synthesis, the CO conversion decreases as the composition of ${\gamma}-Al_2O_3$ decreases, and the selectivity of C1-C4 decreases until the composition of ${\gamma}-Al_2O_3$ was 25 wt%. In contrast, the selectivity of C5+ increases until the composition of ${\gamma}-Al_2O_3$ is 25 wt%.

• Applied Chemistry for Engineering
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• v.19 no.5
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• pp.466-470
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• 2008

The objective of this study is to convert methane into hydrogen using a nanoporous catalyst in the $CO_2$ containing syngas generated from the gasified waste. For the purpose, $Ni/Al_2O_3$ catalyst was prepared with the one-pot method. According to analyses of the catalyst, three dimensionally linked sponge shaped particles were created and the prepared nanoporous catalysts had larger surface area and smaller particle size and more uniform pores compared to the sphere shaped commercial catalyst. The catalyst for reforming reaction gave the highest $CH_4$ conversion of 91%, and $CO_2$ conversion of 92% when impregnated with 16 wt% of Ni at the reaction temperature of $750^{\circ}C$. At that time, the prepared catalyst remarkably improved the $CH_4$ and $CO_2$ conversion up to 20% compared to the commercial one.

• Journal of Power System Engineering
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• v.20 no.4
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• pp.69-74
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• 2016

Recently, in order to meet the stricter emission regulations, the proportion of after-treatments for vehicle and vessel is increasing gradually. The purpose of this study is to investigate the de-$CH_4$ characteristics of NGOC in front of proposed combined system according to additive catalyst and support ratio. In the case of Pd addition, the de-$CH_4$ performance of 2Pt-2Pd-3MgO/$Al_2O_3$ NGOC was improved by approximately 10 to 20% for the HC components. The de-$CH_4$ performance of 2Pt-2Pd-3Cr-3MgO/$Al_2O_3$ NGOC was higher compared to five kinds of NGOC catalysts, because Cr particle was smaller and dispersion of Pd was increased. The NGOC(Zeolite:$Al_2O_3$(80%:20%)｝catalyst according to support ratio, was improved performance at low temperature region on CO and NO conversion rate.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.6
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• pp.3102-3107
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• 2013

Inorganic pigments were prepared from $Al_2O_3$, CoO, $Cr_2O_3$, ZnO, $SrO_2$ and Kaolin. The pigment was prepared through the processes of mixing and crushing of the raw materials, sintering, milling and drying. The color of the pigments was changed from blue to green as $Cr_2O_3$ contents in the pigment increased. The color became brighter irrespective of the pigment composition as pigment particle size became smaller. Maximum sintering temperature was the most suitable at around $1,250^{\circ}C$. In the test of compatability between the pigment and glaze, the color became close to green as $Cr_2O_3$ contents in the pigment increased, and became close to blue as CoO contents increased.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.3
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• pp.112-118
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• 2018

In order to meet the strict emission regulations for internal combustion engines based on fossil fuel, the proportion of after-treatments for vehicles and vessels is gradually increasing. Diesel engines have high power, good fuel economy, and lower $CO_2$ emissions, and their market shares are increasing in commercial vehicles and passenger cars. However, NOx is generated in the localized high-temperature combustion regions, and particulate matter is formed in the zones of diffusion combustion. LNT and urea-SCR catalysts have been developed for after-treatment of the exhaust gas to reduce NOx in diesel vehicles. This study aims to improve the NOx reduction performance of Cu SCR catalyst, which is widely used in light, medium, and heavy-duty diesel engines. The de-NOx performance of $5Cu-2ZrO_2$/93Zeolyst(Si/Al=13.7) SCR catalyst was about 5-50% higher than that of $5Cu-2ZrO_2$/93Zeolite(Si/Al=2.9) at catalyst temperatures of $300^{\circ}C$ or higher. The zeolite had lower metal dispersion than zeolyst, and the reaction rate of the catalyst decreased as the average particle size increased. The $10Cu-2ZrO_2$/88Zeolyst catalyst loaded with 10wt% Cu had the highest NOx conversion rate of 40% at $200^{\circ}C$ and about 65% at $350^{\circ}C$. The ion exchange rate of Cu ions increased with that of Al, the crystalline compound of zeolite, and the de-NOx performance was improved by 20-40% compared to other catalysts.

• The Journal of Korean Academy of Prosthodontics
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• v.35 no.1
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• pp.144-164
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• 1997

The purpose of this study were to investigate the chemical composition, mean particle size, linear thermal expansion coefficient and metal-bonding strength of the regular opaque powder and core powder. In this study, 4 types of ceramic powders, namely Duceram Jacket Opaque powder, Duceram Opaque powder, Vita Hi-Ceram powder, Vita VMK Paint On-88 powder were used. Chemical composition was evaluated by EDS(Energy Dispersive X-ray Spectrophotometer, Oxford QX-2000, England), particle size was measured by MALVERN Instruments(MALVERN Instruments SB. OC., U.S.A.. ad linear thermal expansion coefficient was measured by dilatometer(Motoyama, Japan). Bond strength was measured by the Universal tsting machine(Istron Co., Ltd., U.S.A.). The Results were as follows : 1. Through recognition of the relative difference in chemical composition between the core powder and the regular opaque powder, the difference in the proportion of $Al_2O_3$ in each type of material is demonstrated ; Duceram Jaket Opaque powder : 30.16%, Duceram Opaque powder : 16.60%, Vita Hi-Ceram : 63.64%, Vita VMK Paint-On 88 : 16.16%. 2. There was no significant difference in the proportion of metal-bonding materials between the core powder and the regular opaque powder. 3. In the regular opaque powder, alkaline materials were incoporated in order to increase the coefficient of thermal expansion. 4. In the particle size analysis, there was no significant difference in mean particle size or in the particle size distribution between the core powder and the regular opaque powder. 5. In the thermal expansion test for temperature range of $25-600^{\circ}C$, the regular opaque powder had higher coefficient of thermal expansion than that of core powder. 6. In the 4 point flexural bending test, there was no statistically significant difference in the mean bond strength between the core powder and the opaque powder among the Duceram products.

• Journal of Ocean Engineering and Technology
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• v.27 no.4
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• pp.90-97
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• 2013

Oil booms are one of the most widely used types of equipment for the protection of coastal areas against oil spills. In some situations, however, there are several types of oil leaks from the oil boom. Important factors regarding these phenomena include the surrounding ocean environment, such as waves, the density and viscosity of oil, the length of the oil boom skirt, etc. To estimate the performance of the oil boom, it is necessary to predict the behavior of the spilled oil and oil boom. In the present study, the prediction of oil boom performance in waves was carried out using the Pusan-National-University-modified Moving Particle Semi-implicit (PNU-MPS) method, which is an improved version of the original MPS proposed by Koshizuka and Oka (1996). The governing equations, which consist of continuity and Navier-Stokes equations, are solved by Lagrangian moving particles, and all terms expressed by differential operators in the governing equations are replaced by the particle interaction models based on a kernel function. The simulation results were validated through a comparison with the results of Violeau et al. (2007)..

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.06a
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• pp.461-462
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• 2008

$BaMgAl_{10}O_{17}$:Mn, $Eu^{2+}$ green phosphors has been synthesized by the solid state reaction. Green phosphors of nano-size were manufactured in short time by shake method. which were easily manufactured respectively general method. Green phosphors of nano size were control additive, size of $ZrO_3$ ball, shake time and weight of ball in toluene. In result that green phosphors were obtained particle size of 140nm~150nm. The characteristics of fired samples were obtained by 365nm and 380nm excitation source under ultraviolet. In result that the highest PL intensity were observed in wavelength of 365nm.

• Resources Recycling
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• v.5 no.4
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• pp.32-41
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• 1996

The objective of this study was to investigate the facton affecting the property of CaCO, farmed from CaClz-Na,CO,-HiOsystem. The effcct of the concentmtlon of reaclants, impurity, the pH of reaction, the addition of sccd crystal, and injectingvelocity af reaclant solution an thc yield oI CaCO; polymorphs. parlide size and whiteness of CaCO, were investigated. Thcmqor resulls are ;o fallows; I The optimum concentratinn of reildilnts for forming vaterlte and aragonite is the range of 0.1-1.0 mol/l, when the yicld of vittcrite and araga~nles howed 7542% and XU-90%. respedively. 2. Among thc composition of impunticscontained h limestone, Fe' decrease the wh~tcness nf CaCO;. md Mg" increase the yield of aragonite. 3. The pHrange of vaterite and aragonite are formed with high yield is 8-11, and Calcite is famed in pH 6-8 with big particle size of 1over and in pH 11-13 with small particle size of I under. 4. The yicld of calcite and aragonite was increased by addingthc seed cryst.al nf itself.d cryst.al nf itself.