• Title/Summary/Keyword: Co-Evaporation

검색결과 496건 처리시간 0.031초

Se 증기압이 CIGS 박막 태양전지에 미치는 영향에 관한 연구 (Effects of Se flux on CIGS thin film solar cell)

  • 김대성;김재웅;김태성
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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    • pp.71.2-71.2
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    • 2010
  • CIS(CuInSe2)계 화합물 태양전지는 높은 광흡수계수와 열적 안정성으로 고효율의 태양전지 제조가 가능하여 화합물 태양전지용 광흡수층으로서 매우 이상적이다. 또한 In 일부를 Ga으로 치환하여 밴드갭을 조절할 수 있는 장점이 있다. 미국 NREL에서는 Co-evaporation 방법을 이용해 20%의 에너지 변환 효율을 달성하였다고 보고된바가 있다. 본 연구에서는 미국의 NREL과 같은 3 stage 방식을 이용하여 광흡수층을 제조하고자 한다. 본 실험에서는 Se 증기압을 각각 $200^{\circ}C$, $230^{\circ}C$, $240^{\circ}C$, $245^{\circ}C$로 달리 하며 실험을 실시하였다. 이때 1st stage의 시간은 15분으로 고정하였으며 기판온도는 약 $250^{\circ}C$로 고정 하였다. 2nd stage는 실시간 온도 감지 장치를 이용하여 Cu와 In+Ga의 조성비가 1:1이 되는 시간을 기준으로 Cu의 조성을 30%더 높게 조절하였으며 기판 온도는 약 $520^{\circ}C$로 고정 후 실험을 실시하였다. 3rd stage의 경우 Cu poor 조성으로 조절하기 위해 모든 조건을 10분으로 고정 후 실험을 실시하였다. 각각의 Se 증기압에 따른 물리적, 전기적 특성을 알아보기 위해 FE-SEM, EDS, XRD 분석을 실시하였다. 본 연구에서 기판은 Na이 첨가되어있는 soda-lime glass를 사용 하였으며 후면 전극으로 약60nm 두께의 Mo를 DC Sputtering 방법을 이용해 증착 하였다.

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Rosiglitazone약물을 함유한 PLGA 나노입자 제조 및 분석 (Preparation and Characterization of Rosiglitazone-loaded PLGA Nanoparticles)

  • 신고은;허강무;이용규
    • KSBB Journal
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    • 제23권5호
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    • pp.408-412
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    • 2008
  • 본 연구에서는 당뇨병치료제인 로시글리타존약물를 생분해성 PLGA 나노입자에 봉입시킴으로서 위장흡수율과 물에 대한 용해도를 증가시키기 위한 나노제제 개발에 기반을 두고 있다. 특히 제조조건에 따라 형태 및 크기가 조절가능한 나노입자를 제조하고자 하였고, 실험결과 Emulsion-evaporation방법을 사용하여 100-150 nm 크기의 고른 입자분포를 가진 나노입자를 제조하였다. 다양한 농도의 약물 존재하에서 나노입자를 제조함으로서 1%까지의 약물이 80% 이상의 봉입율로 제조될 수 있음을 확인하였다. 또한 나노입자의 크기는 PVA양을 조절하면서 크기분포를 제어하였다. 36시간 동안의 용출실험 결과 초기 약간의 Burst effect가 있었으나 36시간동안 일정하게 약물이 용출되어 나옴을 확인하였다. 앞으로의 연구를 통해, 고효율의 경구제제용 당뇨병치료제 운반체 개발에 중점을 둘 예정이다.

Combustion Synthesis of $LiMn_2$$O_4$with Citric Acid and the Effect of Post-heat Treatment

  • Han, Yi-Sup;Son, Jong-Tea;Kim, Ho-Gi;Jung, Hun-Teak
    • 한국세라믹학회지
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    • 제38권4호
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    • pp.307-307
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    • 2001
  • Combustion process with citrate was used to produce the LiMn$_2$O$_4$powder. Precursors are pre-ignited in open air followed by post-heating in the range from $600^{\circ}C$ to 80$0^{\circ}C$ for 4h. With varying the molar ratio (R) of ethylene glycol (EG) to citric acid (CA) from 0 to 4, the effect of EG content on powder characteristics is evaluated. Vacuum drying promote the auto-ignition at room temperature. With small addition of EG metal ion was selectively segregated with organic substances and undesired lithium evaporation occurred during post-heating. LiMn$_2$O$_4$phase which is produced by combustion reaction was decomposed back to Mn$_3$O$_4$because the reaction temperature was higher than 95$0^{\circ}C$. With increasing EG content, the homogeneity of LiMn$_2$O$_4$powder increased and specific surface area increased. And lithium evaporation during vacuum drying and/or ignition also increased.

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동시진공증발법을 이용한 고효율 CIGS 박막 태양전지 개발 (Development of High Efficiency CIGS Thin Film Solar Cells by co-evaporation process)

  • 윤재호;안세진;안병태;박희선;윤경훈
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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    • pp.23-23
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    • 2009
  • CIGS 박막 태양전지는 제조단가가 낮고 박막 태양전지 중에서 변환효율이 가장 높아 발전 가능성이 큰 태양전지로 인식되고 있다. 이미 일본, 독일, 미국을 비롯한 선진국에서는 30-50 MW 급의 양산 라인이 구축되고 있어 2010년 이후에는 본격적인 상용화가 진행될 것으로 보인다. CIGS 광흡수층은 진공증발, 셀렌화, 나노입자, 전기도금등 다양한 방식으로 제조가 가능한데 이 중에서도 동시진공증발공정은 고효율 CIGS 박막 태양전지 제조에 적합하다. 본 연구에서는 동시진공증발법을 이용하여 CIGS 박막을 증착하였으며 소다회유리/Mo/CIGS/CdS/i-ZnO/n-ZnO/Al/AR 구조의 태양전지를 제조하였다. 기판온도 모니터링을 통한 Cu 이차상 조절 기술을 이용하여 결정립이 매우 큰 CIGS 박막을 증착하였으며 Ga/(In+Ga) 조성비의 조절을 통하여 밴드갭 에너지를 최적화하였다. 또한 QCM 장치를 활용하여 용액 속에서 성장되는 CdS 박막의 두께와 특성을 조절하였다. 이러한 공정최적화를 통하여 개방전압 0.65 V, 단락전류밀도 38.8 $mA/cm^2$, 충실도 0.74 그리고 변환효율 18.8% 의 CIGS 박막 태양전지를 얻었다.

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단기통 디젤엔진에서 흡기온도변화에 따른 연소 및 배기특성 (Combustion and Exhaust Emission Characteristics by the Change of Intake Air Temperature in a Single Cylinder Diesel Engine)

  • 신달호;박수한
    • 한국자동차공학회논문집
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    • 제25권3호
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    • pp.336-343
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    • 2017
  • Intake air conditions, such as air temperature, pressure, and humidity, are very important parameters that influence engine performance including combustion and emissions characteristics. The purpose of this study is to investigate the effects of intake air temperature on combustion and exhaust emissions characteristics in a single cylinder diesel engine. In this experiment, an air cooler and a heater were installed on the intake air line and a gas flow controller was installed to maintain the flow rate. It was found that intake air temperature induced the evaporation characteristics of the fuel, and it affects the maximum in-cylinder pressure, IMEP(indicated mean effective pressure), and fuel consumption. As the temperature of intake air decreases, the fuel evaporation characteristics deteriorate even as the fuel temperature has reached the auto-ignition temperature, so that ignition delay is prolonged and the maximum pressure of cylinder is also reduced. Based on the increase in intake air temperature, nitrogen oxides(NOx) increased. In addition, the carbon monoxide(CO) and unburned hydrocarbons(UHC) increased due to incomplete fuel combustion at low intake air temperatures.

Tube-bundle형 열교환기의 액막 유동에 관한 시뮬레이션 (Numerical study on the flow characteristics of horizontal tube bundle)

  • 김필환;최두열;우주식;정효민;정한식;김경석
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2009년도 하계학술발표대회 논문집
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    • pp.1256-1261
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    • 2009
  • Seawater amounts to 70% of the earth and represents a quite unlimited resource for the production of fresh water by desalination processes and for the extraction of dissolved salts present in it. Recently, the falling film evaporation has increased in interest as an efficient method for seawater desalination system. In the desalination system, the flow characteristics of the falling film is very important issue to make highly efficient system. So, this study is taken to investigate numerically the falling film thickness on the inlet Renold Number ranges are 400 to 700. Numerical simulations are performed using FLUENT6.3.26, a commercial CFD code.

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드럼형 증발기를 적용한 2단 압축 해수 제빙시스템의 성능 특성 (Performance Characteristics of Two-stage Compression Seawater Ice Machine Applied Drum type Evaporator)

  • 손창효;윤정인;전민주;이현경;허성관
    • 동력기계공학회지
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    • 제21권2호
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    • pp.77-82
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    • 2017
  • In the fishing boat, freshwater ice is loaded on the fishroom in advance and it is used for storage of fishes. However, it causes degradation of catches' freshness. Therefore, seawater ice machine on board is necessary for the fishing industry. In this study, seawater ice machine with drum type evaporator was manufactured, and the system was tested under various operating conditions having an influence on the COP and amount of ice produced. The main results are as follow : The COP of the system gets larger when the evaporation temperature and rotation speed of the drum in the evaporator increases. The most effective refrigerant is R22 and the value of the COP was 1.43 times higher than that of R404A. The amount of produced ice increases with respect to increment of the evaporation temperature, while that decreases with respect to increment of the evaporator drum rotation speed.

Heat Transfer Correlation to Predict the Evaporation of a Water Droplet in Superheated Steam during Reflood Phase of a LOCA

  • Kim, Yoo;Ban, Chang-Hwan
    • 에너지공학
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    • 제9권3호
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    • pp.261-268
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    • 2000
  • A heat transfer correlation to predict the vaporization of a water droplet in highly superheated steam during a loss-of-coolant accident(LOCA) of a nuclear power plant is provided. Vaporization of liquid fuel or water droplets in superheated air or steam and subsequent interface heat transfer between a liquid droplet and superheated gas is typically correlated by way of a Nusselt number as a function of Reynolds number, Prantl number, and in some cases including mass transfer number. Presently available correlations and experimental data of the evaporation of liquid droplets in air or steam are analyzed and a new Nusselt number correlation is proposed taking Schmidt number into consideration in order to account for binary diffusion of the vapor as well, Nu$\_$f/(1+B)$\^$0.7/=2+0.53Sc$\_$f/$\^$-1/5/Re$\_$M/$\^$$\sfrac{1}{2}$/Pr$\_$f/$\^$$\sfrac{1}{3}$/ for which properties are evaluated at film condition except the density of Reynolds number evaluated at ambient condition. Diverse correlations for various combinations of liquid and gas species are put into single equation. The blowing correction factor of (1+B)$\^$0.7/ is confirmed appropriate, and a criterion to distinguish so-called high- and low-temperature condition of ambient gas is set forth.

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레이저 가공시 에너지 전달과 Plume 효과 (Laser- Plume Effects on Radiation Energy Transfer in Materials Processing)

  • Kang, Kae-Myung;Kim, Kwang-Ryul
    • 한국재료학회지
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    • 제12권1호
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    • pp.27-35
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    • 2002
  • In laser materials processing, localized heating, melting and evaporation caused by focused laser radiation forms a vapor on the material surface. The plume is generally an unstable entity, fluctuating according to its own dynamics. The beam is refracted and absorbed as it traverses the plume, thus modifying its power density on the surface of the condensed phases. This modifies material evaporation and optical properties of the plume. A laser-produced plasma plume simulation is completed using axisymmetric, high-temperature gas dynamic model including the laser radiation power absorption, refraction, and reflection. The physical properties and velocity profiles are verified using the published experimental and numerical results. The simulation results provide the effect of plasma plume fluctuations on the laser power density and quantitative beam radius changes on the material surface. It is proved that beam absorption, reflection and defocusing effects through the plume are essential to obtain appropriate mathematical simulation results. It is also found that absorption of the beam in the plume has much less direct effect on the beam power density at the material surface than defocusing does and helium gas is more efficient in reducing the beam refraction and absorption effect compared to argon gas for common laser materials processing.

SmBCO 박막형 초전도 테이프의 lamination 공정을 위한 soldering 연구 (Study on soldering process of SmBCO coated conductor for lamination)

  • 하동우;김태형;오재근;김호섭;하홍수;고락길;송규정;이남진;양주생;오상수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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    • pp.236-237
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    • 2007
  • Lamination of coated conductor is important to commercialize for electrical stabilizer and mechanical support. It should be known the properties of soldering interface and the variation of superconductivity on coated conductor with various kinds of solders. $SmBa_2Cu_O_x$ thin films were deposited by co-evaporation method (EDDC, Evaporation using Drum in Dual Chambers). 4 kinds of solders were used to investigate interface properties of SmBCO conductors. In-Bi solder could maintain good connection.

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