• Title/Summary/Keyword: Co-58

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Gas Permeation Characteristics of PEBAX Mixed Matrix Membranes Containing Polyethylenimine-modified GO (Polyethylenimine으로 개질된 GO를 함유한 PEBAX 혼합막의 기체투과 특성)

  • Yi, Eun Sun;Hong, Se Ryeong
    • Membrane Journal
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    • v.31 no.6
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    • pp.404-416
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    • 2021
  • In this study, a mixed matrix membrane was prepared by varying the contents of GO and PEI-GO synthesized in PEBAX2533, and the permeation characteristics of N2 and CO2 were studied. The N2 and CO2 permeability of the PEBAX/GO mixed membrane decreased as the GO content increased, and showed the highest CO2/N2 selectivity of 58.9 at GO 0.3 wt%. For the PEBAX/PEI-GO mixed membrane, the N2 permeability decreased as the PEI-GO content increased, and the CO2 permeability showed a different trend according to the PEI-GO content. Overall, the CO2/N2 selectivity was higher than that of the PEBAX/GO mixed membrane. In particular, PEI-GO 0.3 wt% showed the highest CO2/N2 selectivity of 73.5 among the mixed membranes, and a positive result was obtained as it was located above the Robeson upper bound. This is believed to be due to the molecular sieving channel effect resulting from the original GO structure, the functional groups present in the structure of GO having affinity for CO2, and the effect of amine bound to PEI by modifying GO into PEI.

Basic Economic Analysis for Co-production Process of DME and Electricity using Syngas Obtained by Coal Gasification (석탄 가스화를 통한 전력 생산과 DME 병산 공정에 대한 기초 경제성 분석)

  • Yoo, Young Don;Kim, Su Hyun;Cho, Wonjun;Mo, Yonggi;Song, Taekyong
    • Korean Chemical Engineering Research
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    • v.52 no.6
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    • pp.796-806
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    • 2014
  • The key for the commercial deployment of IGCC power plants or chemical (methanol, dimethyl ether, etc.) production plants based on coal gasification is their economic advantage over plants producing electricity or chemicals from crude oil or natural gas. The better economy of coal gasification based plants can be obtained by co-production of electricity and chemicals. In this study, we carried out the economic feasibility analysis on the process of co-producing electricity and DME (dimethyl ether) using coal gasification. The plant's capacity was 250 MW electric and DME production of 300,000 ton per year. Assuming that the sales price of DME is 500,000 won/ton, the production cost of electricity is in the range of 33~58% of 150.69 won/kwh which is the average of SMP (system marginal price) in 2013, Korea. At present, the sales price of DME in China is approximately 900,000 won/ton. Therefore, there are more potential for lowering the price of co-produced electricity when comparing that from IGCC only. Since the co-production system can not only use the coal gasifier and the gas purification process as a common facility but also can control production rates of electricity and DME depending on the market demand, the production cost of electricity and DME can be significantly reduced compared to the process of producing electricity or DME separately.

Oxalate Decarboxylase from Agrobacterium tumefaciens C58 is Translocated by a Twin Arginine Translocation System

  • Shen, Yu-Hu;Liu, Rui-Juan;Wang, Hai-Qing
    • Journal of Microbiology and Biotechnology
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    • v.18 no.7
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    • pp.1245-1251
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    • 2008
  • Oxalate decarboxylases (OXDCs) (E.C. 4.1.1.2) are enzymes catalyzing the conversion of oxalate to formate and $CO_2$. The OXDCs found in fungi and bacteria belong to a functionally diverse protein superfamily known as the cupins. Fungi-originated OXDCs are secretory enzymes. However, most bacterial OXDCs are localized in the cytosol, and may be involved in energy metabolism. In Agrobacterium tumefaciens C58, a locus for a putative oxalate decarboxylase is present. In the study reported here, an enzyme was overexpressed in Escherichia coli and showed oxalate decarboxylase activity. Computational analysis revealed the A. tumefaciens C58 OXDC contains a signal peptide mediating translocation of the enzyme into the periplasm that was supported by expression of signal-peptideless and full-length versions of the enzyme in A. tumefaciens C58. Further site-directed mutagenesis experiment demonstrated that the A. tumefaciens C58 OXDC is most likely translocated by a twin-arginine translocation (TAT) system.

Measurement of Fast Neutron Spectrum and Flux in Central Thimble of TRIGA MARK-II Reactor

  • Kim, Dong-Hoon;Kim, Hong-Sik;Yang, Jae-Choon
    • Nuclear Engineering and Technology
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    • v.2 no.2
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    • pp.67-72
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    • 1970
  • The measurements of the fast neutron flux and its spectrum have been carried out by the threshold detectors in the central thimble of TRIGA Mark-II reactor operating at 250 KW. The following reactions have been employed for these measurements, viz : Ni$^{58}$ (n, p) Co$^{58}$$Mg^{24}$ (n, p) Na$^{24}$$Al^{27}$ (n, $\alpha$) Na$^{24}$ . From the activation data the fast neutron spectrum were calculated by CDC-3600 computer making use of two semi-empirical methods. It has been verified that the validity of assumption of a fission spectrum in the central thimble exists only above 1 to 2 Mev energy level. With this spectrum, a fast neutron flux in the range of 1 $\times$ 10$^{12}$ n/$\textrm{cm}^2$-sec above the energy of 2.6 Mev was observed in the central thimble of TRIGA MARK-II reactor.

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Magnetoresistance effects in [Co/Cu/NiFe/Cu] Spin-valve Multilayers ([Co/Cu/NiFe/Cu] 다층박막의 자기저항효과에 관한 연구)

  • 정진봉;박창만;이기암;황도근;이상석
    • Journal of the Korean Magnetics Society
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    • v.5 no.3
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    • pp.203-209
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    • 1995
  • A study of the dependence of the magnetoresistance in $glass\[Cu_{x\AA}\NiFe_{50\AA}\Cu_{x\AA}\Co_{50\AA}](X;\=\;8,\;10,\;14,\;18,\;22,\;26,\;28,\;38,\;48,\;58\;\AA,\;N\;=\;2,\;3,\;4,\;10,\;20)$ multilayers prepared by dc magnetron sputtering on the interlayer thickness of Cu (X), the number of multylayer(N) and annealing temperature has been performed. Resistance measurement were made by four terminal method, and the magnetic field applied to perpendicular and parallel for the current. The maximum magnetoresistance(MR) ratio(%) was appeared in the vicinity of $10\;\AA$ in Cu layer, and it was oscillated with the thickness of Cu. The MR ratio was increased with the number of layers N, however the ratio for the N = 4 layers decreased rather than the N = 3 layers. The dependence of the ratio on the annealing temperature was increased to $250^{\circ}C$.

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Heavy Metal Distributions of Soils in the Vicinity of Shi-Hwa Industrial Complex Region (시화공업단지 주변지역 토양의 중금속 분포)

  • 송영배;이상모
    • Journal of Soil and Groundwater Environment
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    • v.8 no.2
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    • pp.87-91
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    • 2003
  • This study was carried out to investigate the heavy metal distributions of soils in the vicinity of Shi-Hwa industrial complex region, where the air pollutants from industrial area could affect the soil environment of near residential and green areas. The ranges of contents of As, Cd, Co, Cr, Cu, Hg, Ni, Pb and Zn in soils were 0.58~3.81, ND~0.91, 0.15~6.33, ND~l.86, 0.14~110.27, ND~l.17, 0.04~10.59, 1.16~86.48 and 1.83~212.65 mg/kg, respectively. For all industrial, residential and green areas, the heavy metal contents were much lower than the standard of Korean Soil Environmental Preservation Act or the critical concentration which phytotoxicity is considered to be possible. Mean values of contents of As were similar in industrial, residential and green areas. However, the mean values of contents of Cd and Cr in industrial area were higher 10 and 5 times than those in residential and green area, respectively. And also the mean values of contents of Co, Cu, Hg, Ni, Pb and Zn in industrial area were higher 2~3 times than those in residential and green area.

Analysis of Low Field Microwave Absorption Properties in CoFe/MnIr Thin Film (CoFe/MnIr 박막 재료에서 저자장 마이크로파 흡수 특성 분석)

  • Kim, Dong Young;Yoon, Seok Soo
    • Journal of the Korean Magnetics Society
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    • v.25 no.3
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    • pp.74-78
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    • 2015
  • We measured the low field microwave absorption (LFMA) and ferromagnetic resonance (FMR) signals at various magnetic field angle in exchange biased CoFe/MnIr thin film. The LFMA signals were dominantly related to the magnetization rotation process. In order to analyze the LFMA signal, we calculated transverse magnetization ($M_{\tau}$) and permeability (${\mu}_{\tau}$) for CoFe/MnIr thin film by using S-W model, which magnetic parameters of exchange bias ($H_{ex}$ = 58.5 Oe) and uniaxial anisotropy field ($H_k$ = 30Oe) was obtained from FMR signals. The LFMA signal at hard axis showed similar behavior compared with that of $M_{\tau}$. As the magnetic field angle approach to the perpendicular to hard axis, the LFMA signals were depending on both of $M_{\tau}$ and ${\mu}_{\tau}$.

The impact of two doses of coenzyme Q10 on semen parameters and antioxidant status in men with idiopathic oligoasthenoteratozoospermia

  • Alahmar, Ahmed T
    • Clinical and Experimental Reproductive Medicine
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    • v.46 no.3
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    • pp.112-118
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    • 2019
  • Objective: Oxidative stress contributes to male infertility, and antioxidants have been recommended for treating idiopathic oligoasthenoteratozoospermia (OAT). There is, however, a lack of agreement on the type, dosing, and use of individual antioxidants or combinations thereof. The purpose of this study was to compare the effects of two doses of coenzyme Q10 (CoQ10) on semen parameters and antioxidant status in men with idiopathic OAT. Methods: In this prospective study, patients with idiopathic OAT received 200 mg/day (n = 35) or 400 mg/day (n = 30) of CoQ10 orally for 3 months. All patients underwent semen analysis according to the fifth editions of the World Health Organization criteria. Total antioxidant capacity (TAC), catalase (CAT) activity, and superoxide dismutase (SOD) activity were measured both before and after treatment. Results: Treatment with CoQ10 (200 mg/day or 400 mg/day) resulted in a significant increase in sperm concentration from baseline ($8.22{\pm}6.88$ to $12.53{\pm}8.11million/mL$, p= 0.019; $7.58{\pm}5.41$ to $12.33{\pm}6.1million/mL$, p= 0.002, respectively), progressive motility ($16.54%{\pm}9.26%$ to $22.58%{\pm}10.15%$, p=0.011; $14.22%{\pm}12.85%$ to $26.1%{\pm}14.52%$, p= 0.001, respectively), and total motility ($25.68%{\pm}6.41%$ to $29.96%{\pm}8.09%$, p= 0.016; $23.46%{\pm}12.59%$ to $34.82%{\pm}14.17%$, p= 0.001, respectively). CoQ10 therapy also increased TAC (p= 0.009, p= 0.001, respectively), SOD activity (p= 0.004, p= 0.001, respectively), and CAT activity (p= 0.039, p= 0.024, respectively). Furthermore, antioxidant measures correlated significantly with seminal fluid parameters (r = 0.36-0.76). Conclusion: CoQ10 supplementation improved semen parameters and antioxidant status in men with idiopathic OAT, with a greater improvement shown in men who took 400 mg/day than in those who took 200 mg/day.

설비전용 종합 소프트웨어 개발 위한 CO-ME 설립

  • 이홍규
    • 월간 기계설비
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    • s.52
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    • pp.58-66
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    • 1994
  • 설비설계업계가 UR 타결로 인한 국제화 개방화 시대에 대비하기 위해 하나로 뭉쳤다. 지난 1월초부터 국내 굴지의 5개 기계설비용역회사들이 모여 설비설계의 전산화 및 기술개발을 공동으로 모색하기 위한 모임 CO-ME(Computer Mechanical Engineering)를 조직, 컴퓨터에 의한 설계의 표준화작업을 서두르고 있다. CO-ME의 회장을 맡고 있는 이홍규 기계설비엔지니어링협의회 회장(무애청우엔지니어링 대표)은 '국내 실정에 맞는 CAD를 개발, 설비업계에 종사하는 모든 업체가 손쉽게 사용할 수 있고 나아가 해외에서도 사용 가능한 프로그램을 개발할 계획' 이라면서 '각 업체의 적극적인 지원으로 빠른 성과를 보이고 있으나 투자액이 2억원을 넘고 있지만 아직 회수를 못하고 있어 안타깝다' 고 말하고 '그러나 지금은 고생이 되더라고 개척해 놓으면 개방화시대를 당당히 맞이할 수 있을 것' 이라고 덧붙였다. 이 회장은 또 설비업계의 5개 단체인 기계설비협의회가 상호 협력하여 공존공생할 수 있는 방안을 모색중이라고 밝혔다. 본지는 이홍규 회장의 CO-ME에 대한 자세한 소개를 게재한다.

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A Study on the Environmental Load of Office Buildings in Seoul

  • Lee, Sang-Hyung;Lee, Yun-Gyu;Yang, Kwan-Seob;Ahn, Tae-Kyung;Lee, Seung-Eon;Park, Hyo-Soon
    • International Journal of Air-Conditioning and Refrigeration
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    • v.9 no.1
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    • pp.58-64
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    • 2001
  • This study is to examine the emission quantity of $CO_2$ gas as the environmental load in office buildings. After the investigation of monthly consumption of each energy source(electricity and natural gas), it is analyzed that the $CO_2$ emission quantity of 34 office buildings surveyed is 22.4 kg-c/$m^2$-year, which consists of 17.5 kg-c/$m^2$-year by consurunlelectncif. and 4.9 kg-c/$m^2$-year by consuming natural gas. And the $CO_2$ emission quantity of each load in those buildings consists of 68% emitted by general electricity, 16% by cooling load and 16% by beating load. It is also proposed that the $CO_2$ emission quantity of cooling and heating load is profoundly pertinent to the variation of outdoor temperature.

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