• Title/Summary/Keyword: Co salt

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Catalytic effect of metal oxides on CO2 absorption in an aqueous potassium salt of lysine

  • Dharmalingam, Sivanesan;Park, Ki Tae;Lee, Ju-Yeol;Park, Il-Gun;Jeong, Soon Kwan
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.335-341
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    • 2018
  • We report the catalytic effects of metal oxides on the $CO_2$ absorption rate in an aqueous potassium salt of ${\text\tiny{L}}-lysine-HCl$ using the vapor liquid equilibrium method. The best $CO_2$ absorption rate obtained through testing metal oxides in a highly concentrated potassium salt of amino acids (2.0 M) was identified using CuO. The recyclability of the metal oxides was tested over three cycles. The catalyst CuO was found to enhance the absorption rate of $CO_2$ by 61%. A possible mechanism was proposed based on NMR spectroscopy studies. Further, the effect of change in liquid absorbent viscosity on $CO_2$ absorption is discussed.

A Study on Vapour Explosion Caused by the Contact Between Molten Salt of Na$_2$CO$_3$-NaOH Mixture and water (Na$_2$CO$_3$-NaOH 혼합용융염과 물의 접촉에 의한 증기폭발에 관한 연구)

  • Mok, Yun-Soo;Chiaki Ogiso;Yoichi Uehara
    • Journal of the Korean Society of Safety
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    • v.4 no.1
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    • pp.41-46
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    • 1989
  • Molten salt-water explosion caused by the contact between molten salt and water is one of vapour explosions. An experimental study of the vapour explosion, which occurs when the molten mixture of Na$_2$CO$_3$-NaOH and water come in contact was performed. The pressure wave generated in each composition Of molten mixtures was measured. The results obtained are as follows: 1) The vapour explosion didn't occur for a molten salt of 100%-Na$_2$CO$_3$- 2) For a molten salt of Na$_2$CO$_3$ 80%-NaOH 20% mixture, a small vapour explosion occured initially, and a large vapour explosion, which showed the largest pressure wave among the present experiments, occurred after an induced period. 3) For molten salt of Na$_2$CO$_3$60% - NaOH 40% mixture and Na$_2$CO$_3$ 40% - NaOH 60% mixture, the vapour explosion occurred near the water surface shortly after they come in contact with water. This explosion would be caused by fragmentation of the molten salts due to impulse generated when thee molten salts and water come in contact.

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Application of the Combination of Soybean Lecithin and Whey Protein Concentrate 80 to Improve the Bile Salt and Acid Tolerance of Probiotics

  • Gou, Xuelei;Zhang, Libo;Zhao, Shiwei;Ma, Wanping;Yang, Zibiao
    • Journal of Microbiology and Biotechnology
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    • v.31 no.6
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    • pp.840-846
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    • 2021
  • To improve the bile salt and acid tolerance of probiotics against gastrointestinal stresses, we investigated the effects of soybean lecithin and whey protein concentrate (WPC) 80 on the bile salt tolerance of Lacticaseibacillus paracasei L9 using a single-factor methodology, which was optimized using response surface methodology (RSM). The survival rate of L. paracasei L9 treated with 0.3% (w/v) bile salt for 2.5 h, and combined with soybean lecithin or WPC 80, was lower than 1%. After optimization, the survival rate of L. paracasei L9 incubated in 0.3% bile salt for 2.5 h reached 52.5% at a ratio of 0.74% soybean lecithin and 2.54% WPC 80. Moreover, this optimized method improved the survival rate of L. paracasei L9 in low pH condition and can be applied to other lactic acid bacteria (LAB) strains. Conclusively, the combination of soybean lecithin and WPC 80 significantly improved the bile salt and acid tolerance of LAB. Our study provides a novel approach for enhancing the gastrointestinal tolerance of LAB by combining food-derived components that have different properties.

A Study On Properties and Thermal Decomposition of W-Co Salt Powders Synthesized by Spray Drying (분무 건조된 W-Co 복합염의 열분해 및 분말 특성에 관한 연구)

  • Gwon, Dae-Hwan;An, In-Seop;Ha, Guk-Hyeon;Kim, Byeong-Gi;Kim, Yu-Yeong
    • Korean Journal of Materials Research
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    • v.11 no.11
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    • pp.953-959
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    • 2001
  • Homogeneous spherical W-Co salt powders were made by spray drying of aqueous solution of ammonium $metatungstate(NH_4)_6(H_2W_{12}O_{40}){\cdot}4H_2O,\; AMT)$ and cobalt nitrate $hexahydrate(Co(NO_3)_2{\cdot}6H_2O)$. The thermal decomposition process of spray dried W-Co salt powders was studied by TG, XRD, SEM, TEM and FT-IR. Spray dried W-Co salt powders were calcined for 1 hour in the temperature from$ 350^{\circ}C$ to $800^{\circ}C$ in atmosphere of air. At the temperatures over $600^{\circ}C$, spherical $CoWO_4/WO_3$ composite oxide powders were obtained. The primary particle size of W/Co composite oxide powders increased with increasing thermal decomposition temperature due to the particle growth. The observed crystallite size by TEM was in the range of 60nm and that of $CoWO_4$ calculated by Scherrer's formula at $800^{\circ}C$ was smaller than 55nm. The crystallite site was identified by XRD and TEM.

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Immunotoxicity study of JukYom(bamboo salt) in rats

  • Kim, Su-Hyon;Lee, Hye-Yeong;Kim, Sun-Hee;Kim, Yun-Jung;Shim, Yhong-Hee;Park, Sun-Hee;Kang, Seong-Kwi;Park, Chan-Sung;Kang, Jong-Koo
    • Proceedings of the Korea Environmental Mutagen Society Conference
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    • 2004.05a
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    • pp.135-135
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    • 2004
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Improving the Mechanical Properties of Salt Core through Reinforcing Fibers

  • Ahrom Ryu;Soyeon Yoo;Min-Seok Jeon;Dongkyun Kim;Kiwon Hong;Sahn Nahm;Ji-Won Choi
    • Journal of Sensor Science and Technology
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    • v.32 no.3
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    • pp.159-163
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    • 2023
  • Salt cores have attracted considerable attention for their application to the casting process of electric vehicle parts as a solution to ecological issues. However, the salt core still has low mechanical strength for use in high-pressure die casting. In this study, we investigated the improvements in the bending strength of KCl-based salt cores resulting from the use of reinforcing materials. KCl and Na2CO3 powders were used as matrix materials, and glass fiber and carbon fiber were used as reinforcing materials. The effects of carbon fiber and glass fiber contents on the bending strength properties were investigated. Here, we obtained a new fiber-reinforced salt core composition with improved bending strength for high-pressure die casting by adding a relatively small amount of glass fiber (0.3 wt%). The reinforced salt core indicates the improved properties, including a bending strength of 49.3 Mpa, linear shrinkage of 1.5%, water solubility rate of 16.25 g/min·m2 in distilled water, and hygroscopic rate of 0.058%.

The Formation and Deliveries of CO in Reconstituted Tobacco Leaves by Decreasing of Combustion Temperature (제지식 판상엽으로 제조된 권련에서 연소점 온도 내림이 CO의 생성과 이행에 미치는 영향)

  • 김대종;송태원;이문수;제병권
    • Journal of the Korean Society of Tobacco Science
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    • v.19 no.1
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    • pp.64-69
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    • 1997
  • Deliveries of tar, nicotine, CO and $CO_2 in main stream smoke decreased as the potassium salt content of reconstituted tobacco leaves increased. The peak temperatures of the central region of a burning cone during a puff was in the range 940$^{\circ}C$∼430$^{\circ}C$ by IR thermal video system. The exogenous Potassium salt contents influenced the reduction of carbon-monoxide delivery through a decrease in the Peak temperature of the burning cone. Consequently, the amount of CO formed in the combustion Process was reduced by potassium salt. Moreover, the temperature of the burning cone was lowered, and the CO formed from carbonaceous reduction was decreased.

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Synthesis of TiC/Co Composite Powder by the Spray Thermal Conversion of Metallic Salt Solution (금속염용액의 분무열분해에 의한 TiC/Co복합분말 제조)

  • 이길근;문창민;김병기
    • Journal of Powder Materials
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    • v.10 no.4
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    • pp.228-234
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    • 2003
  • In the present study, the focus is on the synthesis of titanium carbide/cobalt composite powder by the spray thermal conversion process using metallic salt solution as the raw materials. Two types of oxide powders of Ti-Co-O system were prepared by the spray drying of two types of metallic salt solutions : titanium chloride-cobalt nitrate and $TiO_2$ powder-cobalt nitrate solutions. These oxide powders were mixed with carbon black, and then these mixtures were carbothermal reduced under a flowing argon atmosphere. The changes in the phase structure and thermal gravity of the mixtures during carbothermal reduction were analysed using XRD and TG-DTA. In the case of using the titanium chloride-cobalt nitrate solution, it could not be obtained TiC/Co composite powder due to contamination of the impurities during the spray drying of the solution. However, in tile case of using the $TiO_2$ powder-cobalt nitrate scullion, TiC-15 wt. %Co composite powder could be synthesized by the spray thermal conversion process. The synthesized TiC-15 wt. %Co composite powder at 120$0^{\circ}C$ for 2 hours has average particle size of 150 nm.

$CO_2$ Production in Fermentation of Dongchimi (Pickled Radish Roots, Watery Radish Kimchi) (동치미의 발효중 $CO_2$ 발생특성)

  • 이동선;이영순
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.26 no.6
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    • pp.1021-1027
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    • 1997
  • $CO_2$production in fermentation of dongchimi was measured and interrelated with changes in pH and titratable acidity. The effects of salt content and temperature on $CO_2$production rate were analysed. Fermentation of dongchimi showed drastic pH decrease in early stage and subsequent levelling off around 3.9, with linearly increased acidity up to 0.3~0.4% optimum quality. $CO_2$production of dongchimi could be analysed to consist of two consecutive stages of constant rate. The first stage $CO_2$production of higher rate moved to the second stage of lower rate when acidity rose beyond 0.3%. When compared to those of 1 and 2% salt content, dongchimi of 3% salt showed lower $CO_2$production rate in the 1st stage and slower acidity change through the whole fermentation period. However, it resulted in the product of highest $CO_2$accumulation at optimal ripeness because of consistent $CO_2$production of longer 1st stage period and relatively high $CO_2$production rate in 2nd stage. $CO_2$production depended on temperature less compared to acidity change(activation energy: 57.3 and 44.3kJ/mol for $CO_2$production of 1st and 2nd stages, respectively; 79.3kJ/mol for acidity change), which means higher ratio of $CO_2$production rate relative to acidity increase at lower temperature. Slower increase in acidity at low temperature also was shown to extend the period of 1st stage $CO_2$production. Therefore, low temperature fermentation was effective in producing the high $CO_2$content dongchimi at adequate acidity, which is desirable organoleptically.

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