• Journal of the Korean Chemical Society
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• v.9 no.2
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• pp.67-70
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• 1965

Polarographic studies of reduction of Ni(Ⅱ)-CN complex on Hg-electrode have indicated that $Ni(CN)_4^{2-}$ is reduced by two paths, via one electron process Ni(CN)42- + e [1]↔[2] Ni(CN)43- =(eq) Ni(CN)2- + 2CN- and via two electron process Ni(CN)42- + 2e [3]→ 1/2[Ni(CN)33-]2 + CN- of which reduction [1] must be faster than reduction [3]. At very dilute cyanide concentration (0.004 to 0.01 M) cathodic wave is practically responsible for reaction [1] and two cyanide ions appear to contribute to the reaction. As increasing cyanide ion concentration the rate of oxidation reaction [2] catalysed by Hg increases and reaction [1] and [2] approach to equilibrium. Therefore, reaction [3] represents the cathodic wave at high concentration of cyanide (above 0.2 M). This mechanism can also explain the fact that limiting current at $[CN^-]$ = 8 M is approximately twice of that at 0.004 M CN.

• Transactions of the Korean Society of Automotive Engineers
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• v.19 no.3
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• pp.106-112
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• 2011

This study is to investigate the effect of an aromatic content in high cetane number (CN) fuels on exhaust emissions under low temperature diesel combustion, which expands the previous research about an aromatic content in low CN fuels. A 1.9L common rail direct injection diesel engine was run at 1500 rpm 2.6 bar BMEP with four fuel sets: an aromatic content of 20% (A20) or 45% (A45) with CN30, i.e. low CN fuels, and CN55, i.e. high CN fuels. Given experimental conditions, the trend of exhaust emissions in high CN fuels was inconsistent with that of low CN fuels which all produced nearly zero smoke but higher NOx for the high aromatic fuel (CN30-A45). For high CN fuels, however, the low aromatic fuel (CN55-A20) produced lower smoke than the high one (CN55-A45) while NOx was similar to each other. The cause of this discrepancy between high CN and low CN fuels is unclear whether it comes from that CN may be a dominant factor to govern exhaust emissions rather than an aromatic content or that the actual CN value of CN55-A45 is lower than CN55-A20. More decent fuel matrix should be prepared and further experiments are needed to confirm it.

• Journal of the Korean Institute of Gas
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• v.19 no.3
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• pp.44-48
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• 2015

The equations of hydrocarbon dew points(DT) of the fuel gas mixtures have been derived using the multiple regression analysis. In QSDR(Quantitative Structure Dew-point Relationship), the principal descriptors are CN(average carbon number) and BI(the ratio of the branched isomers). QSDRs studied by changing the pressures of the fuel gas mixtures in the range of 100 kPa ~ 500 kPa are as follows; $$DT(^{\circ}C)=-683.1+1224.98CN-898.01CN^2+308.58CN^3-49.56CN^4+3.02CN^5-12.42BI$$ (at 100 kPa, $$R_{adj}{^2}=0.99$$) (1) $$DT(^{\circ}C)=-745.2+1351.66CN-978.1CN^2+332.7CN^3-52.96CN^4+3.20CN^5-12.84BI$$ (at 200 kPa, $$R_{adj}{^2}=0.99$$) (2) $$DT(^{\circ}C)=-795.4+1457.1CN-1051.1CN^2+357.53CN^3-57.07CN^4+3.46CN^5-13.10BI$$ (at 300 kPa, $$R_{adj}{^2}=0.99$$) (3) $$DT(^{\circ}C)=-868.1+1608.4CN-1156.0CN^2+393.38CN^3-63.06CN^4+3.85CN^5-13.39BI$$ (at 500 kPa, $$R_{adj}{^2}=0.99$$) (4) As the average carbon numbers in the mixed fuel being reduced or the ratio of the branched isomers having a boiling point lower increase, The hydrocarbon dew point becomes lower, The differences between the hydrocarbon-dew points determined by the multiple regression and those calculated by the commercial program, VMGSim are negligible.

• Bulletin of the Korean Chemical Society
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• v.31 no.12
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• pp.3771-3776
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• 2010

The dynamics of the $CN^-$-ligated ferric cytochrome c (CytcCN) in $D_2O$ at 283 K following Q-band photoexcitation at 575 nm was observed using femtosecond time-resolved vibrational spectroscopy. The equilibrium vibrational spectrum of the CN stretching mode of CytcCN shows two overlapping bands: one main band (82%) at $2122\;cm^{-1}$ with $23\;cm^{-1}$ full width at half maximum (fwhm) and the other band (18%) at $2116\;cm^{-1}$ with $7\;cm^{-1}$ fwhm. The time-resolved spectra show bleaching of the CN fundamental mode of CytcCN and two absorption features at lower energies. The bleach signal and both absorption features are all formed within the time resolution of the experiment (< 200 fs) and decay with a life time of 1.9 ps. One transient absorption feature, appearing immediately red to the bleach signal, results from the thermal excitation of low-frequency modes of the heme that anharmonically couple to the CN fundamental mode, thereby shifting the CN mode to lower energies. The shift of the CN mode decays with a lifetime of 2 ps, equivalent to the time scale for vibrational cooling of the low-frequency heme modes. The other transient absorption feature, which is 3.3 times weaker than the bleach signal and shifted $27\;cm^{-1}$ toward lower energies, is attributed to the CN mode in an electronically excited state where the CN bond is weakened with a lowered extinction coefficient. These observations suggest that photoexcited CytcCN mainly undergoes ultrafast radiationless relaxation, causing photo-deligation of $CN^-$ from CytcCN highly inefficient. As also observed in $CN^-$-ligated myoglobin, inefficient ligand photodissociation might be a general property of $CN^-$-ligated ferric hemes.

• Journal of Environmental Science International
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• v.29 no.1
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• pp.95-108
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• 2020

Silver nanoparticles were loaded onto g-C₃N₄ (CN) with a nanoroll-type morphology (Ag/CN) synthesized using a co-polymerization method for highly selective conversion of toxic nitrobenzene to industrially-valuable aminobenzene. Scanning electron microscopy and high-resolution transmission electron microscopy (HRTEM) images of Ag/CN revealed the generation of the nanoroll-type morphology of CN. Additionally, HRTEM analysis provided direct evidence of the generation of a Schottky barrier between Ag and CN in the Ag/CN nanohybrid. Photoluminescence analysis and photocurrent measurements suggested that the introduction of Ag into CN could minimize charge recombination rates, enhancing the mobility of electrons and holes to the surface of the photocatalyst. Compared to pristine CN, Ag/CN displayed much higher ability in the photocatalytic reduction of nitrobenzene to aminobenzene, underscoring the importance of Ag deposition on CN. The enhanced photocatalytic performance and photocurrent generation were primarily ascribed to the Schottky junction formed at the Ag/CN interface, greater visible-light absorption efficiency, and improved charge separation associated with the nanoroll morphology of CN. Ag would act as an electron sink/trapping center, enhancing the charge separation, and also serve as a good co-catalyst. Overall, the synergistic effects of these features of Ag/CN improved the photocatalytic conversion of nitrobenzene to aminobenzene.

• Journal of the Korean Society for Heat Treatment
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• v.13 no.5
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• pp.324-329
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• 2000

Microstructure, mechanical and fatigue behaviors of TiCN and TiN/TiCN thin films, deposited on quenched and tempered STD61 tool steel, were investigated by using XRD, XPS, hardness, adhesion and fatigue tests. The TiCN thin film is grown along the (100), (111) orientation, whereas the TiN/TiCN thin film is grown along the (111) orientation. The preferred orientation of TiN/TiCN thin film strongly depends on the TiN buffer layer whose orientation is (111), as is well-known. The TiN/TiCN thin film showed the higher adhesion compared with TiCN single layer because the TiN buffer layer, having good toughness, reduces the effects of the lower hardness of substrate. In the high cycle tension-tension fatigue test, the fatigue life of the TiCN and the TiN/TiCN coated steel increased approximately two to four times and five to nine times respectively compared with uncoated specimens. The TiN buffer layer in multilayer thin films plays an important role in reducing residual stress and fatigue crack initiation, and then in restraining the fatigue propagation.

• Proceedings of the Korea Water Resources Association Conference
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• 2017.05a
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• pp.215-215
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• 2017

NRCS-CN 방법은 총 강우량으로부터 유출량을 계산하는 방법으로, 국내에서는 설계홍수량 산정 시 NRCS-CN 방법의 사용을 권장하고 있다. CN값은 토지이용 및 피복, 토양특성, 수문학적 조건(AMC)에 따른 함수로 결정할 수 있으나, 보통의 경우 미국의 National Engineering Handbook (NEH-4)에서 제시한 표를 활용한다. 그러나, 우리나라의 토지피복 및 토지이용 현황은 미국과 다르기 때문에 현실 조건을 반영한 조정이 필요함에도 불구하고, 충분한 관측 자료가 확보되지 않아 이러한 조정이 어려운 실정이다. NRCS-CN 방법에서는 결과 값이 총 강수량보다 CN에 크게 의존적이기 때문에 부정확한 CN 값의 산정은 큰 오차를 야기할 수 있다. 또한 소유역에서는 초기손실량이 설계홍수량 산정에 큰 영향을 미치지만 우리나라는 초기손실률을 20%의 고정된 값을 일괄적으로 적용하고 있으며, 이는 제주도와 같은 특수한 투수성 지층에서는 적합하지 않다는 지적을 받아왔다. 여러 선행연구에서 강수량과 CN 사이에는 특정 관계식이 존재하며, 고정된 CN 값이 아닌 강수량에 따라 변화하는 값을 적용하는 것이 기존의 NRCS-CN 방법보다 더 정확한 결과를 나타낸다는 것이 확인된 바 있다. 본 연구에서는 NRCS-CN 방법의 CN 값과 초기손실률을 유역에 적합하게 개선하기 위해서 기존의 NRCS-CN 모형에 점근 유출곡선지수방법(Asymptotic CN Regression Method)을 통해 산정된 CN값과 각기 다른 초기손실률(0.01, 0.05, 0.10, 0.20, 0.40)을 적용하여 개선된 총 8개의 모형을 한강 권역 소유역에 적용하였다. RMSE, MAE 및 R-square 등의 지표를 이용하여 모형 검정을 수행하였으며, 최적의 모형 및 미개변수를 선정하였다. 그 결과 기존의 NRCS-CN 방법보다 점근 유출곡선지수방법을 적용했을 때 더 작은 오차를 나타내는 것을 확인하였으며, 대부분의 유역에서 0.01 또는 0.05 등 기존보다 더 작은 초기손실률을 채택 시 실측값과 가장 적은 오차를 나타냈다.

• Journal of The Korean Astronomical Society
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• v.38 no.2
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• pp.23-31
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• 2005

CN and CH band strengths for fourteen bright giants in the globular cluster M71 have been measured from archival spectra obtained with the Multiple Mirror Telescope. Adding the collected. data from the literature we confirm a bimodality of CN distribution on the red giant branch and the honzontal branch, and CN-CH anti-correlations on the lower giant branch and horizontal branch. However a CN-CH anti-correlation on the upper red giant branch is not quite clear as those of other branches. The small number If statistics could not be excluded as a possible cause. To confirm this, a greater number of sample stars are needed. We also confirm that the ratio of CN-strong to CN-weak stars is quite different from that in 47 Tuc, although the anti-correlation between CN and CH bands, the bimodality of the CN distribution, and the spatial distribution of CN stars in M71 are found to be similar to those III 47 Tuc.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.34 no.4
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• pp.1171-1180
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• 2014

The NRCS-CN method is generally used to estimate effective rainfalls in a basin. However, since the curve number which plays a critical role in the NRCS-CN method was originally developed for US watersheds, it is limited to be directly applied to other basins outside the United States. Therefore various modifications have been suggested to revise the NRCS-CN for specific watershed condition. This study introduced the weighted average method and the slope-based CN to estimate effective rainfalls available for Korean watersheds and compared with the observed direct runoff. The overall results achieved from this study indicated that the adjusted slope-based CN considerably increases effective rainfalls in general and makes the duration of effective storm longer. Based on the statistical error analysis performed for various modifications of NRCS-CN, the weighted average method with the adjusted slope-based CN has highest precision with the observed direct runoff. In addition, after analyzing the relation between the initial loss estimated from rainfall-runoff observations and the potential maximum retention from GIS-based data, it turns out that the assumption of linear relationship between the initial loss and the potential maximum retention is not available for Korean watersheds.

• Journal of Korea Water Resources Association
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• v.48 no.6
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• pp.491-500
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• 2015

In order to improve the runoff estimation accuracy of the Natural Resources Conservation Service (NRCS) curve number (CN) model, this study incorporated rainfall and maximum potential retention as contributors for initial abstraction. The modification was proposed based on 658 rank-order data of rainfall and subsequent runoff from 15 watersheds. The NRCS-CN model (M1), one of its inspired modified model (M2), and the proposed model (M3) were analyzed employing different CN approaches. Using tabulated, calculated and least squares fitted CNs ($CN_T$, $CN_C$, $CN_{LSF}$, respectively), the models' performances were evaluated based on Root Mean Square Error (RMSE), Nash-Sutcliffe Efficiency (NSE), and Percent Bias (PBIAS). Applications of model M1, M2, and M3, respectively exhibited watershed cumulative mean [RMSE (23.60, 18.12, 16.04), NSE (0.54, 0.73, 0.79), and PBIAS (36.54, 20.25, 12.00)]. Similarly, using CNC (for M1 and M2 model) and $CN_{LSF}$ (for M3 model), the performance of three models respectively were assessed based on watershed cumulative mean [RMSE (17.17, 15.88, 13.82), NSE (0.76, 0.80, 0.85), and PBIAS (3.06, 4.47, 0.11)]. The proposed model (M3) that linked all of the NRCS-CN variants showed more statistically significant agreement between the observed and estimated data.