• Title/Summary/Keyword: Clogging effect

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Simultaneous Reduction of CH4 and NOx of NGOC/LNT Catalysts for CNG buses (CNG 버스용 NGOC/LNT 촉매의 CH4와 NOx의 동시 저감)

  • Seo, Choong-Kil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.6
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    • pp.167-175
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    • 2018
  • Natural gas is a clean fuel that discharges almost no air-contaminating substances. This study examined the simultaneous reduction of $CH_4$ and NOx of NGOC/LNT catalysts for CNG buses related to the improvement of the $de-CH_4/NOx$ performance, focusing mainly on identifying the additive catalysts, loading of the washcoat, stirring time, and types of substrates. The 3wt. % Ni-loaded NGOC generally exhibited superior $CH_4$ reduction performance through $CH_4$ conversion, because Ni is an alkaline, toxic oxide, and exerts a reducing effect on $CH_4$. A excessively small loading resulted in insufficient adsorption capacity of harmful gases, whereasa too high loading of washcoat caused clogging of the substrate cells. In addition, with the economic feasibility of catalysts considered, the appropriate amount of catalyst washcoat loading was estimated to be 124g/L. The NOx conversion rate of the NGOC/LNT catalysts stirred from $200^{\circ}C$ to $550^{\circ}C$ for 5 hours showed 10-15% better performance than the NGOC/LNT catalysts mixed for 2 hours over the entire temperature range. The NGOC/LNT catalysts exhibitedapproximately 20% higher $de-CH_4$ performance on the ceramic substrates than on the metal substrates.

Bioactive Foam Reactors for the Enhanced Biological Degradation of Toluene (계면활성제 거품을 이용한 미생물반응기에서의 기체상 톨루엔 분해)

  • Kim, Yong-Sik;Son, Young-Kyu;Khim, Jee-Hyung;Song, Ji-Hyeon
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.5
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    • pp.468-475
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    • 2005
  • Biofilters packed with various materials have emerged as a sustainable technology for the treatment of volatile organic compounds (VOCs); however, problems including low performance and clogging are commonly encountered. Recently, a bioactive foam reactor (BFR) using surfactants has been suggested to ensure efficient and stable VOCs removal performance. This study was mainly conducted to investigate the feasibility of BFRs using toluene as a model compound. Prior to bioreactor studies, a series of bottle tests were used to select a suitable surfactant for the BFR application. Experimental results of the batch bottle tests indicated that TritonX-100 was the most appropriate one among the surfactants tested, since it showed a minimal effect on the toluene biodegradation rate while the other surfactants lowered the toluene biodegradation rate significantly. Using the selected surfactant, the BFR performance was determined by changing operating parameters including gas residence time and toluene loading. As the gas residence time increased from 0.5 minutes to 2 minutes, the toluene removal efficiency increased from approximately 50% to 80%. In addition, an increase of the toluene loading from $38\;g/m^3/hr$ to $454\;g/m^3/hr$ resulted in a decrease of toluene removal efficiency from approximately 70% to 20%. The BFR had a maximum elimination capacity of $108\;g/m^3/hr$ for toluene, which was much higher than those generally reported in the literature. The high toluene-elimination performance indicates that the BFR be a potential alternative to the conventional, packed-type biofilters. However, the limitation of toluene solubilization and foam stability at either high or low gas flow rate are still problems to be challenged.

A Study on Reduction of Nitrogen Oxide (NOx) and Stability of Incineration Facility by the Food Wastewater Incineration (음식물류 폐수 소각처리에 따른 질소산화물 저감 및 소각설비의 안정성 평가에 관한 연구)

  • Hwang, Seung-Min;Chung, Jin-Do;Song, Jang-Heon
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.10
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    • pp.901-908
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    • 2009
  • We examine the processing method of the food wastewater to direct spray at living waste incinerator. The demoscale stoker system is used as a incineration facility. The results show that it brings effect on the reduction of nitrogen oxide ($NO_x$) concentration as well as the ammonia ($NH_3$) amount in SNCR (selective non-catalytic reduction) by the incineration of food wastewater which is containing a plentiful ammoniac nitrogen ($NH_3$-N). Furthermore, the stability of incineration facility and the extension of operation period is actualized as a improvement of clogging phenomenon on outer wall of water pipe as the 870~$950^{\circ}C$ maintain of exit temperature in a second combustor by spray of the food wastewater. The 26 items of air pollution matter of nitrogen oxide ($NO_x$), sulfur oxide ($SO_x$) and dioxin etc. are measured. The results show that it is under the value of allowable exhaust standard.

Comparison & Analysis for Fine Sand Migration in Filter (조립 Filter내에서 세상의 이동현상에 대한 비교분석)

  • Kim, Hyun-Ki;Kwon, Moo-Nam
    • Current Research on Agriculture and Life Sciences
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    • v.16
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    • pp.15-23
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    • 1998
  • This experiment did comparison and analysis that protected soil particle migration have affect on function of the filter and therefore fall function of the filter. Results obtained are as follows: 1.High water head makes to be much movement of fine sand and out flow of particle to the outside. The filter have large opening size that reached stability an early stage, but much fine sand is washed away. If the velocity turns fast and becomes small, blocking phenomenon is remarkable nearby the filter-sand interface. 2. The movement of fine sand that effect on function of filter depend on opening size and change of water head. Under the same condition, USCE filter and USSPL filter is reached earlier than other filter that is stability of stage, because it's opening size is large. 3. Residual quantity of fine sand migration was largly come out in order of USSPL, USCE, USBR, Newton & Hurley, Bertram filter. 4. The time required to stability of flow was taken less in order of Bertram, Newton & Hurley, USBR, USSPL, USCE filter and coefficient of permeability was highly come out in order of USBR, Bertram, Newton & Hurley, USSPL, USCE filter. 5. It proved that USCE and USSPL is suitable for the filter criteria.

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Improving Physical Fouling Tolerance of PES Filtration Membranes by Using Double-layer Casting Methods (PES 여과막의 물리적 막오염 개선을 위한 기공 구조 개선 연구)

  • Chang-Hun Kim;Youngmin Yoo;In-Chul Kim;Seung-Eun Nam;Jung-Hyun Lee;Youngbin Baek;Young Hoon Cho
    • Membrane Journal
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    • v.33 no.4
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    • pp.191-200
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    • 2023
  • Polyethersulfone (PES) is a widely employed membrane material for water and industrial purification applications owing to its hydrophilicity and ease of phase separation. However, PES membranes and filters prepared using the nonsolvent induced phase separation method often encounter significant flux decline due to pore clogging and cake layer formation on the dense membrane surfaces. Our investigation revealed that tight microfiltration or loose ultrafiltration membranes can be subject to physical fouling due to the formation of a dense skin layer on the bottom side caused by water intrusion to the gap between the shrank membrane and the substrate. To investigate the effect of the bottom surface porosity on membrane fouling, two membranes with the same selective layers but different sub-layer structures were prepared using single and double layer casting methods, respectively. The double layered PES membrane with highly porous bottom surface showed high flux and physical fouling tolerance compared to the pristine single layer membrane. This study highlights the importance of physical optimization of the membrane structure to prevent membrane fouling.

Change of Hydraulic Characteristics due to Well Drilling and Well Development in an Unconsolidated Aquifer (미고결대수층에서 우물 굴착 및 개량에 의한 대수층의 수리특성 변화)

  • Kim, Byung-Woo;Kim, Gyoo-Bum;Kim, Geon-Young
    • The Journal of Engineering Geology
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    • v.22 no.1
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    • pp.27-37
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    • 2012
  • To investigate the effect of aquifer disturbance on hydraulic properties while well drilling at unconsolidated aquifer, the following tests were conducted: the surge block and air-surging methods, which are well development methods used after well drilling; and step-drawdown tests and constant-rate pumping tests, which are used to assess changes in the aquifer after well drilling and development. The result of step-drawdown tests indicated that drawdown for a pumping-rate of $700m^3/day$ was 21.62 m after well development, decreasing 4.39 m from 26.01 m after well drilling. The skin factor used to identify the well properties decreased from 7.92 after well drilling to 5.04 after well development, respectively, which shows the improvement of well. Constant-rate pumping tests revealed a small increase in aquifer transmissivity after well development at MW-2, -3, and -4, centering around pumping well, from $1.684{\times}10^{-3}{\sim}4.490{\times}10^{-3}m^2/sec$ to $4.002{\times}10^{-3}{\sim}4.939{\times}10^{-3}m^2/sec$. MW-1, however, showed decline in hydraulic conductivity from $1.018{\times}10^{-2}m^2/sec$ to $6.988{\times}10^{-3}m^2/sec$, which was caused by a small decrease of aquifer permeability around monitoring well MW-1 due to latent factor of air interception and clogging in aquifer during surging. This finding indicates that fine particles have an effect on hydraulic properties at unconsolidated aquifers during well drilling; therefore, we consider that well drilling and development have an effect on hydraulic properties.