• Title/Summary/Keyword: Clay mineral composition

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Clay Mineral Distribution in the Yellow Sea Surface Sediments: Absolute Mineral Composition and Relative Mineral Composition (황해 표층퇴적물의 점토광물 분포; 절대광물조성과 상대광물조성)

  • Moon, Dong-Hyeok;Yi, Hi-Il;Shin, Dong-Hyeok;Shin, Kyung-Hoon;Cho, Hyen-Goo
    • Journal of the Mineralogical Society of Korea
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    • v.21 no.3
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    • pp.289-295
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    • 2008
  • We studied the difference between the clay mineral content in the bulk marine sediments (absolute clay mineral composition) and clay mineral content only in total clay minerals (relative clay mineral composition) of the Yellow Sea marine sediments, and correlated the relationship between their distribution patterns. We used 56 Yellow Sea Surface sediments collected at the second cruise in 2001 of KORDI, and determined the absolute mineral composition using the quantitative X-ray diffraction analysis. Yellow Sea surface sediments consist of primary rock forming minerals including quartz (average 44.7%), plagioclase (15.9%), alkali feldspar (10.0%), hornblende (2.8%) together with clay minerals (illite 15.3%, chlorite 2.6% and kaolinite 1%) and carbonates (calcite 1.7%, aragonite 0.6%). Absolute clay mineral contents are very high in the region extending from the southeast of Sandong Peninsula to the southwest of Jeju Island. In contrast, it is very low along the margin of the Yellow Sea. Such distribution patterns of absolute clay mineral content are very similar to those of fine-grained sediments in the study area. The average relative clay mineral composition of illite, chlorite, and kaolinite is respectively 80.3%, 14.9% and 4.8%. The distribution pattern of relative mineral composition shows very different phenomenon when compared with those of absolute mineral composition, and also do not exhibit any positive relationship with that of fine-grained sediments in which clay mineral composition is abundant. Therefore, we suggest that the relative clay mineral compositions and their distribution patterns must be used very carefully when interpreting the origin of sediment provenance.

A Comparative Study on Absolute and Relative Clay Mineral Composition of the Surface Sediments around the Jeju Island (제주도 주변해역 표층퇴적물의 점토광물 절대함량 및 상대함량 비교연구)

  • Moon, Dong-Hyeok;Cho, Hyen-Goo;Yi, Hi-Il
    • Journal of the Mineralogical Society of Korea
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    • v.23 no.1
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    • pp.15-23
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    • 2010
  • The absolute clay mineral compositions and regional distribution of the 131 bulk marine surface sediments around the Jeju Island was compared to their relative compositions and distribution using quantitative X-ray diffraction analysis. Average absolute clay mineral composition is illite 15.3% (0.5~40.5%), chlorite 2.6% (0~7.9%), and kaolinite 1% (0~5.6%). Total contents of the clay minerals are very high in the South Sea of Korea, northwestern part and southern offshore of Jeju Island. The average relative composition is illite 70.9% (16.7~89%), chlorite 21.5% (8.4~68.5%), and kaolinite 7.6% (0~29.3%). Relative illite contents are high in the northwestern and southeastern part of study area, and southern part of Jeju Island. Chlorite contents are high in the eastern part of study area and western part of Jeju Island. Kaolinite contents are high in the western and southern part of Jeju Island, and southern offshore of Jeju Isand. Absolute Distribution patterns are very similar to those of fine-grained (from clay to silt) sediment, whereas relative distribution patterns do not show any relationship with those of fine-grained sediment.

Effect of Clay-Mineral Composition on Flexural Strength of Clay-based Membranes (점토 광물 조성이 점토기반 분리막의 곡강도에 미치는 영향)

  • Lee, Young-Il;Eom, Jung-Hye;Kim, Young-Wook;Song, In-Hyuck
    • Journal of the Korean Ceramic Society
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    • v.51 no.5
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    • pp.380-385
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    • 2014
  • Clay-based membranes with submicron pore size were successfully prepared by a simple pressing process using low-cost starting materials(e.g., kaolin (K), bentonite (B), talc (T), and sodium borate). The green bodies were sintered at $1000^{\circ}C$ for 2 h in air. The effect of clay-mineral composition on the flexural strength of clay-based membranes was investigated. The porosity of the clay-based membranes could be controlled within the range of 34 - 42% by adjusting the starting composition. The flexural strength of the low-cost membranes depended on both the porosity and the ${\alpha}$-quartz content. In turn, the porosity and ${\alpha}$-quartz content were affected by the (B+T) /(K+B+T) ratio. The plot of strength relative to this ratio, showed a maximum when the ratio was 0.4. The typical flexural strength of these clay-based membranes (with ratio 0.4) was 28 MPa at 34% porosity.

Variation of Rare Earth Element Patterns during Rock Weathering and Ceramic Processes: A Preliminary Study for Application in Soil Chemistry and Archaeology (암석의 풍화과정 및 도자기 제조과정에 따른 희토류원소 분포도의 변화: 토양화학 및 고고학적 응용을 위한 기초연구)

  • Lee, Seung-Gu;Kim, Kun-Han;Kim, Jin-Kwan
    • The Journal of the Petrological Society of Korea
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    • v.17 no.3
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    • pp.133-143
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    • 2008
  • On the basis of chemical composition of granite, gneiss and their weathering products, in this paper, rare earth elements (REEs) was estimated as tracer for clarifying a geochemical variance of earth surface material during weathering process. The chemical composition of clay, clay ware and pottery also were measured for testifying usefulness of REE geochemistry in clarifying the source material of pottery. It was observed that there was no systematic variation of chemical composition among source rock, weathered rock and soil during weathering process. The chemical composition of clay, clay ware and pottery also did not show systematic variation by baking pottery. However, PAAS (Post Archean Australian Shale)-normalized REE patterns of rock-weathered rock-soil and clay-clay ware-pottery are similar regardless of weathering process or ceramic art. Our results confirm that REE geochemistry is powerful tool for clarifying the source materials of surface sediment or archaeological ceramic products.

Mineralogy and Chemical Properties according to Particle Size Separation of Hwangto (Reddish Residual Soil) used in Feeding of Cattle (한우 사육에 이웅한 황토(풍화토)의 입도분리에 따른 광물성분 및 화학적 특성)

  • 황진연;박현진;양경희;이효민
    • Journal of the Mineralogical Society of Korea
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    • v.15 no.1
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    • pp.33-43
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    • 2002
  • Mineral composition and chemical properties of Hwangto (reddish residual soil) that used in feeding of cattles at Iksan, Jeollabuk-do, Korea were examined according to particle size separation such as gravel, sand, silt, coarse clay and fine clay. Mineral composition analyses reveal that gravel and sand are mainly composed of quartz and feldspars and that kaolin mineral and illite are dominant in clay and silt. Iron oxides are mainly included in fine clay. According to chemical analyses of major elements, Al, Fe and $H_2O$ contents are increased with decreasing of particle size. This trend well agrees with increase of clay minerals in smaller particles, Chemical analyses of trace elements indicate that contents of Zn, Rb, Sr, Ba, Pb significantly differ with particle sizes. Ba and Sr are included in feldspars since these elements are abundant in sand containing abundant feldspars. Pb and Sm are abundant in sample before particle size separation, but the contents are significantly decreased after separation. Therefore, most of these elements appear to be existed as removable phase. Nb, La, Th, Ce are more abundant in silt. The contents of all the other trace elements tend to be increased in smaller particles containing more clay minerals. The contents of changeable cations and teachable elements in acid and alkali solutions are high in clay samples. All the above results indicate that using the portion of smaller particle of Hwangto for livestock feed rather than bulk Hwangto can improve cation exchangeable capacity, ion leaching capacity and sorption properties.

Clay Mineral Composition of the Soils Derived from Residuum and Colluvium (잔적 및 붕적모재 토양의 점토광물 특성구명)

  • Zhang, Yong-Seon;Sonn, Yeon-Kyu;Jung, Sug-Jae;Lee, Gye-Jun;Kim, Myung-Sook;Kim, Sun-Kwan;Lee, Ju-Young;Pyun, In-Hwan
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.5
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    • pp.245-252
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    • 2006
  • This experiment was conducted to investigate the distribution and compositions of clay mineral and to replenish the soil classification system in Korea. Soil layer samples were collected from 26 residuum and colluvium soil series out of 390 soil series in Korea, and then analyzed for soil physical and chemical characteristics, mineral and chemical compositions of clay in B horizon soils. Major clay minerals of residuum and colluvium were illite and chlorite in soils originated from the sedimentary rock such as limestone, shale, sandstone and conglomerate; quartz and kaolin in soils originated from rhyolite, neogene deposits, porphyry and tuff; and kaolin and quartz in the soils originated from granite, granite gneiss and anorthosite. Clay minerals in Korean soils were divided into 4 groups: mixed mineral group(MIX) mainly contained with illite, kaolin and vemiculite; kaolin group(KA) with kaolin and illite; chlorite group(CH) with chlorite and illite; and smectite group(SM) with kaolin, illite and smectite. The most predominant clay mineral group was kaolin group(KA) with kaolin and illite; an mixed mineral group(MIX) with illite, kaolin and vemiculite. Cation exchange capacity (CEC) of clay was low in the soils mainly composed with MIX and KA groups and silica-alumina molar ratio of clay was high in the soils composed with SM group

Correlation Between Engineering Properties and Mineralogy of Clay Sediments in the Estuary of the Nakdong River (낙동강 하구지역 점토퇴적물의 광물조성과 토질물성과의 상관관계)

  • Lee Sonkap;Kim Jin-Seop;Um Jeong-Gi;Hwang Jin-Yeon
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.2
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    • pp.93-107
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    • 2005
  • The estuary of Nakdong River area including Noksan industrial complex and Busan New Port is composed of thick unconsolidified sediments containing abundant clay, and thus is a potential hazardous area of ground subsidence. We analyzed mineral compositions and geotechnical properties of the clay sediments that sampled from 4 boreholes of the area, and examined vertical variations and their correlations. The results showed correlations between some mineral constituents and geotechnical properties of clay sediments. A positive correlation showed between quartz content and wet unit weight, whereas a negative correlation showed between quartz content and liquid limit. Feldspar content and water content showed a negative correlation, whereas content of clay minerals and liquid limit showed a positive correlation. And also, there is a negative correlation between content of clay minerals and wet unit weight. Correlation equations are obtained from the multiple regression analyses among plastic index, content of clay mineral, smectite and clay fraction.

Effects of Dietary Addition of Bentonite on Manure Gas Emission, Health, Production, and Meat Characteristics of Hanwoo (Bos taurus coreanae) Steers

  • Lee, Sang-Moo;Kim, Young-Il;Kwak, Wan-Sup
    • Asian-Australasian Journal of Animal Sciences
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    • v.23 no.12
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    • pp.1594-1600
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    • 2010
  • A study was conducted to determine the dietary effects of a clay mineral (sodium bentonite, NaB) on manure gas emission, health, production, and meat characteristics of Hanwoo steers. Two diets fed to steers included a control diet (concentrate mix and rice straw) and a treatment diet (control diet+1.0% clay mineral/concentrate mix). Dietary NaB addition considerably reduced concentrations of gases ($H_2S$, $SO_2$ and $NH_3$) in the manure of Hanwoo steers. Growing steers fed NaB had similar blood profiles with the exception of lower (p<0.05) concentrations of blood alkaline phosphatase and lactate dehydrogenase. Dietary NaB addition tended to increase (p = 0.10) live weight by 30 kg at slaughtering and did not affect carcass yield and quality traits. Dietary NaB addition increased concentrations of P (p<0.01), Mg (p<0.01), Na (p<0.01), Zn (p<0.005), K (p = 0.08), Fe (p = 0.08) and Cu (p = 0.07) in the longissimus muscle compared to the control but did not affect (p>0.05) fatty acid composition. The study demonstrated that the dietary addition of a clay mineral could be effective in improving mineral bioavailability to Hanwoo steers, which could be one of the reasons for their improved performance.

Studies on Mineral Composition of Fault Clay in Quaternary Ipsil Fault: High Resolution Powder Diffraction Analysis (제4기 입실 단층 파쇄대에서 나타나는 단층점토의 산출상태에 따른 광물조성 연구: 고해상도분말회절 분석을 중심으로)

  • Park, Sung-Min;Kang, Han;Jang, Yun-Deuk;Im, Chang-Bock;Kim, Jeong-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.2 s.52
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    • pp.83-89
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    • 2007
  • XRD, HRPD and SEM were used for mineralogical characterization of fault clay in fracture zone from Ipsil. Variations of color in fault clay exhibit significant mineral composition difference. Fault clays from Ipsil are composed mainly of smectite, laumontite, and quartz. Laumontite, a distinct fault clay in Ipsil fault, might be resulted from alteration of bed rock in fracture zone based on the result that no laumontite was found near fault rock. Fault clays from Ipsil are composed mainly of smectite.

Petro-mineralogical and Mechanical Property of Fault Material in Phyllitic Rock Tunnel (천매암 터널 단층물질의 암석.광물학적 및 역학적 특성)

  • Lee, Kyoung-Mi;Lee, Sung-Ho;Seo, Yong-Seok;Kim, Chang-Yong;Kim, Kwang-Yoem
    • The Journal of Engineering Geology
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    • v.17 no.3
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    • pp.339-350
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    • 2007
  • Content, swelling, concentration, drainage of clay are critical factors that could control rock failures as well as discontinuous geological structures like faults and joints. Especially, the proportional components of clay minerals can be one of few direct indicators to a rock failure caused well by rainfall. Criticality of the role of clay mineral contents gets bigger in the slope and tunnel design. This study, using a horizontal boring core of pelitic/psammitic phyllite from the OO tunnel construction site, aims to investigate mineral composition changes related to fault distribution and their mechanical effects to the activity of these discontinuous layers (i.e., clay-filled fault layers), and eventually to define correlation among rock compositions, weathering products and rock instabilities. Field survey and lab tests were carried out for the composition and strength index of fault clay minerals within the core samples and microscopic analysis of fresh and weathered rock samples.