• Journal of Applied Biological Chemistry
• /
• v.64 no.4
• /
• pp.391-397
• /
• 2021

Four compounds were isolated from Salvia plebeia aerial parts. Silica gel open column chromatography with a gradient elution system was used to isolate and purify these compounds. Nuclear magnetic resonance spectroscopy and mass spectroscopy were used for structural elucidation and identification, while electronic circular dichroism was used to confirm the absolute configuration. The structures were determined to be 𝛽-sitosterol (1), (-)-1S,5S,8S,10R-1-acetoxy-8-hydroxy-2-oxoeudesman-3,7(11)-dien-8,12-olide (2), ursolic acid (3), and N-methylhydroxylamine (4). Compounds 2 and 4 were isolated for the first time from this plant. Compound 2 was quantitatively analyzed via HPLC/UV. The results showed that the methanol extract of S. plebeia had a higher content of compound 2 (1.20 mg/g) than the ethanol extract (0.55 mg/g). This study could be used as a preliminary step in conducting HPLC/UV analysis of sesquiterpenoids in S. plebeia extract to assess their bioavailability and potency.

• Steel and Composite Structures
• /
• v.30 no.6
• /
• pp.591-601
• /
• 2019

This research study investigates experimentally and analytically the axial compressive behaviour of Concrete Filled Fiber Reinforced Polymer Tube (CFFT) columns with and without Fiber Reinforced Polymer (FRP) bars. The experimental program comprises five circular columns of 204-206 mm outer diameter and 800-812 mm height. All columns were tested under concentric axial compressive loads. It was found that CFFT columns with and without FRP bars achieved higher peak axial compressive loads and corresponding axial deformations than conventional steel reinforced concrete (RC) column. The contribution of FRP bars was about 12.1% of the axial compressive loads carried by CFFT columns reinforced with FRP bars. Axial load-axial deformation ($P-{\delta}$) curves of CFFT columns were analytically constructed, which mapped well with the experimental $P-{\delta}$ curves. Also, an equation was proposed to predict the axial compressive load capacity of CFFT columns with and without FRP bars, which adequately considers the contributions of the circumferential confinement provided by FRP tubes and lower ultimate strength of FRP bars in compression than in tension.

• International Journal of High-Rise Buildings
• /
• v.7 no.4
• /
• pp.327-342
• /
• 2018

Geopolymer concrete (GPC), which is recognised as an environmentally friendly alternative to ordinary Portland cement (OPC) concrete, has been reported to possess high fire resistance. However, very limited research has been conducted to investigate the behaviour of geopolymer concrete-filled steel tubular (GCFST) columns at either ambient or elevated temperatures. This paper presents the compressive test results of a total of 15 circular concrete-filled steel tubular (CFST) stub columns, including 5 specimens tested at room temperature, 5 specimens tested at elevated temperatures and the remaining 5 specimens tested for residual strength after exposure to elevated temperatures. The main variables in the test program include: (a) concrete type; (b) concrete strength; and (c) curing condition of geopolymer concrete. The test results demonstrate that GCFST columns have similar ambient temperature behaviour compared with the conventional CFST counterparts. However, GCFST columns exhibit better fire resistance than the conventional CFST columns. Meanwhile, it is found that the GCFST column made with heat cured GPC has lower strength loss than other columns after exposure to elevated temperatures. The research results highlight the possibility of using geopolymer concrete to improve the fire resistance of CFST columns.

• Journal of the Korean GEO-environmental Society
• /
• v.12 no.8
• /
• pp.59-67
• /
• 2011

The interaction of the ground deformation and composite piles, which is made of fiber glass, was analyzed for the effective pile application under vertical loads. This study was performed to conduct experimentation test and propose the material characteristics of the new type concrete injection circular FRP pile for the improvement of the defect of CFFT-Concrete composition piles and FRP-Concrete composition piles(FRP reinforced column direction). Additionally, in order to analyze the behaviour characteristics of composite pile and steel pile the numerical analyses were carried out.

• Steel and Composite Structures
• /
• v.43 no.5
• /
• pp.625-637
• /
• 2022

Axial compression capacity (P_u) is a significant yet complex parameter of concrete-filled steel tube (CFST) columns. This study offers a novel ensemble tool, adaptive neuro-fuzzy inference system (ANFIS) supervised by equilibrium optimization (EO), for accurately predicting this parameter. Moreover, grey wolf optimization (GWO) and Harris hawk optimizer (HHO) are considered as comparative supervisors. The used data is taken from earlier literature provided by finite element analysis. ANFIS is trained by several population sizes of the EO, GWO, and HHO to detect the best configurations. At a glance, the results showed the competency of such ensembles for learning and reproducing the P_u behavior. In details, respective mean absolute errors along with correlation values of 4.1809% and 0.99564, 10.5947% and 0.98006, and 4.8947% and 0.99462 obtained for the EO-ANFIS, GWO-ANFIS, and HHO-ANFIS, respectively, indicated that the proposed EO-ANFIS can analyze and predict the behavior of CFST columns with the highest accuracy. Considering both time and accuracy, the EO provides the most efficient optimization of ANFIS and can be a nice substitute for experimental approaches.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.43 no.3
• /
• pp.277-285
• /
• 2023

Recently, as the magnitude and frequency of earthquakes increases, research is needed to increase the ductility of the columns in order to prevent the collapse of structures. In this study, to evaluate the performance of columns reinforced with continuous transverse reinforcing bars, the FE model for the dynamic analysis of structures reinforced with continuous transverse reinforcing bars for circular and rectangular columns is to be verified using the results of uniaxial compression experiments in the previous study. As a result, the experimental value of the column reinforced with continuous transverse reinforcement and the result value related to the dynamic analysis showed similar behavior, and the reliability was high. As a result of the analysis, the usability of the rectangular column reinforced with continuous lateral reinforcing bars was confirmed because the dissipated energy performance of the columns reinforced with spiral reinforcing bars was higher than that of the columns reinforced with band reinforcing bars.

• International Journal of Highway Engineering
• /
• v.9 no.3
• /
• pp.39-50
• /
• 2007

Barrier VII program is normally used for the design of flexible barrier, but if modelled properly it can be used for the analysis of vehicle impact to small sign posts. In this paper sign post is shown to be modelled as flexible barrier by combining beam and column elements at each beam node. Simulations with the Barrier VII program have been made for 7 impact cases composed of sign posts of circular and H section with rigidly connected support and breakaway support system. The impact speed used for the simulation ranged from 30km/h to 110km/h. The study shows that in the vehicle impacts to a circular sign post with high speed, the large deflection and high inertia force causes the sign plate to hit the windshield leading to a hazard to the occupants. It is also shown that impact to H section post results in small deflection of the post and abrupt velocity change and high deceleration of the impact vehicle causing severe damage to both the vehicle and occupants. Simulation study also shows that breakaway support system eliminates the potential danger of the vehicle impact to the rigidly connected small sign posts by reducing deflection of the post, abrupt change in velocity and deceleration level.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.22 no.1
• /
• pp.116-122
• /
• 2021

This study quantitatively evaluated the performance improvement of a circular reinforced concrete pier under dynamic load with strengthening using a steel plate. Various three-dimensional elements were applied using the finite element program ABAQUS. The analytical parameters included the ratios of the steel cover length to the pier's total height and the ratios of the steel cover thickness to the pier diameter for inelastic-nonlinear analysis. The lower part of the pier had fixed boundary conditions, and lateral repetitive loads were applied at the top of the pier. The pier was investigated to evaluate the dynamic performance based on the load-displacement curve, stress-strain curve, ductility, energy absorption capability, and energy ratio. The yield and ultimate loads of piers with steel covers increased by 3.76 times, and the energy absorption capability increased by 4 times due to the confinement effects caused by the steel plate. A plastic hinge part of the column with a steel plate improved the ductility, and the thicker the steel plate was, the greater the energy absorption capacity. This study shows that the reinforced pier should be improved in terms of the seismic performance.

• Proceedings of the Ginseng society Conference
• /
• 1988.08a
• /
• pp.122-128
• /
• 1988

Several major polyacetylene compounds were isolated from the petroleum-ether fraction of fresh Korean ginseng roots through solvent fractionation. partition and silica gel column chromatography. Further separation of acetylenic compounds was accomplished by bonded normal phase HPLC utilizing a moderately nonpolar microparticulate column. The preparative separation for the various spectral measurements was carried out by low pressure preparative liquid chromatography. The chemical structure of these polyacetylenes separated was determined by UV. IR/FTIR. $^{1}H$ NMR. mass spectral and elemental analysis. These are identified to be heptadeca-1-en-4.6-diyn-3.9.l0.-triol [1] heptadeca-1.9-dien-4.6-diyn-3-ol. heptadeca-1.8-dien-4.6-diyn-3.10-diol and the 4th was denatured polyacetylene. heptadeca-1.4-dien-6.8-diyn-3.10-diol. Two different p-substituted benzoates of panaxynol were synthesized for the determination of exciton chirality. The circular dichroism spectra in the UV region show that panaxynol p-bromobenzoate and p-dimethyl-aminobenzoate constitute negative exciton chirality [2]. Isolated major polyacetylene compounds were irradiated in aerated solution with 300 nm UV light to obtain the oxidized product at the allylic alcohol center to corresponding carbonyl compounds such as heptadeca-1-en-4.6-diyn-9.10-diol-3-one and heptadeca-1.9-dien-4.6-diyn-3-one. These photooxidation compounds have en-on-diyne chromophore and undergo nucleophilic addition reaction with methanol to yield ${\beta}-methoxy$ carbonyl compounds such as heptadeca-9-en-4.6-diyn-1-methoxy-3-one and heptadeca-4.6-diyn-1-methoxy-9.10-diol-3-one.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
• /
• 2003.05a
• /
• pp.214-214
• /
• 2003

During a model test of Hutton TLP, a "ringing" response was first observed about 20 years ago. This phenomenon is a resonant build up over the time of wave period and this burst-like motion can cause the extreme load on the TLP tether. It is often detected in the large and steep irregular waves but the generation mechanism leading to the "ringing" is not yet well understood. According to the research since then, the higher order harmonic components may account for the "ringing" on the floating offshore structures. The main purpose of the present research is, thus, to measure the higher harmonic forces exerted on a vertical truncated circular column and to compare them with available data. A vertical truncated cylinder with a diameter of 3.5inch and a draft of 10.5inch is used as a test structure, which is a scaled model of ISSC TLP column. The cylinder is installed at a distance of 45ft from the wave maker in order to avoid parasitic waves created in the wave flap. Attached to the upper part of the cylinder are two force gages to measure the horizontal (surge) and vertical (heave) forces on the cylinder. The incoming waves are Stokes waves with a slope ranging from 0.06 to 0.24. The forces and waves are measured for 60 seconds with a sampling rate of 50 Hz. Among the recorded data, the first 10 waves are excluded because of transient behavior of the waves and the next The horizontal and vertical forces are analyzed up to 5th order harmonics. The horizontal forces are then compared to the values from the theoretical model called "FNV model". In addition, force transfer functions are also investigated. Major findings in this research are below. 1) The first order forces measured are slightly larger than the theoretical values of "FNV model" 2) The "FNV model" considerably overpredicts the second order forces. 3) The larger the amplitude and more extreme the wave slope, the smaller the predictions are compared to the experimental. 4) The higher harmonic forces are significantly smaller than the first harmonic force for all wave parameters. 5) The normalized forces vs. waves slopes are almost constant in the lower harmonics but vary a lot in the higher harmonics. 6) The trend of forces is more nonlinear in the horizontal forces than in the vertical forces as the wave slope increases. 7) The part of the results above is also observed by other researchers and confirmed again through the present work.