• Title/Summary/Keyword: Chromic Oxide

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EFFECT OF FEEDING PATTERN ON DIURNAL VARIATION IN FAECAL CHROMIC LEVEL WHEN USING CONTROLLED RELEASE DEVICES IN SHEEP

  • Lee, G.J.;Mortimer, S.I.
    • Asian-Australasian Journal of Animal Sciences
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    • v.4 no.1
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    • pp.79-83
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    • 1991
  • Diurnal variation in faecal chromic oxide levels was estimated from 4 hourly faecal sampling of 56 wethers allotted to one of six different feeding patterns. Sampling occurred on days 6 and 7 (Period 1) after a controlled release device was administered, and was repeated on days 14 and 15 (Period 2) following re-randomisation of the wethers to the feeding patterns. Increasing the frequency of feeding tended to be associated with higher faecal chromic oxide levels (p < 0.05), particularly in wethers fed thrice daily at 8 hour intervals. There was no interaction between feeding pattern and period, sampling day or time within-day. There were significant period x time within-day (p < 0.05) and day x time within-day (p < 0.001) interactions, indicating that variation in faecal chromic oxide between sample times was not consistent. This implies that sampling at any time of day is unlikely to result in a biased estimate of pasture intake, providing sufficient samples are collected. Significant period (p < 0.001) and period x day (p < 0.01) effects were associated with slow faecal chromic oxide equilibration in period 1. Equilibration did not occur until after day 7, indicating a need for caution when commencing sampling.

Role of Added Metal Oxide in the Adherence Mechanism of Low Melting Glass to Several Metal Seals (저융점유리와 각종금속과의 봉착기구에 있어서 금속산화물의 역할)

  • 정창주
    • Journal of the Korean Ceramic Society
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    • v.11 no.1
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    • pp.3-9
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    • 1974
  • The role of added metal oxide in the adherence mechanism of low melting glass to several metal plates such as oxygen free high conducting copper, low carbon steel, chrominum galvanized on copper, and stainless steel was investigated. The metal oxide which added to glass were cupric oxide, ferric oxide, chromic oxide, and stainless steel oxide. The glass to that various metla oxide were added, sealed with several metal plates in the electric furnace at $650^{\circ}C$ for 5 minutes. The results as follows; 1) The interfacial reaction was promoted and strong chemical bonding with glass and metals by which the surface energy was decreased showed excellent sealing by addition of metal oxide. 2) When the interfacial reaction of glass and metals was promoted by addition of metal oxide found out that various adhernece mechanism were related to the sealing. 3) When the amount of metal oxide addition was 3-5% the excellent sealing was achieved.

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Dicobalt hexacarbonyl tert-butylacetylene와 ozone을 이용한 cobalt oxide의 원자층 증착 공정

  • Choe, Gyu-Ha;Jin, Gwang-Seon;Han, Byeol;Lee, Won-Jun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.113-113
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    • 2011
  • Cobalt oxide 박막은 gas sensor, electro-chromic 소자 그리고 energy storage 소자등 광범위한 분야에서 연구되고 있으며 sputtering, CVD 그리고 electrochemical deposition 를 포함한 다양한 방법으로 증착할 수 있다. 최근에는 원자층 증착 방법을 이용한 cobalt oxide박막 증착이 연구되었는데, cyclopentadienyl계열의 전구체와 ${\beta}$-diketonate계열의 전구체를 이용하였다. 하지만 전구체의 낮은 증기압으로 인해 낮은 growth rate (약 0.02~0.05 nm/cycle)을 보였다. 본 연구에서는 증기압이 높은 전구체인 CCTBA (dicobalt hexacarbonyl tert-butylacetylene) 를 선정하여 원자층 증착 공정의 growth rate를 향상시키고자 하였다. 반응기체로는 O3을 사용하여 cobalt oxide 박막을 증착하였다. 반응기체의 주입시간 및 공정온도를 달리하여 시편을 증착한 결과 $80^{\circ}C$에서 0.1 nm/cycle로 기존의 보고된 growth rate보다 높은 수치를 얻을 수 있었다. 또한 증착된 cobalt oxide 박막내 조성분석과 I-V 측정 등을 이용하여 물리적, 전기적 특성을 규명하였다

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Effects of dietary Chromic Oxide and Possible Use of the Animal By-product Mixture as a Dietary Fish meal Replacer (무지개송어 사료에 있어 산화크롬의 첨가효과와 축산 가공 부산혼합물의 어분대체 가능성)

  • JANG Hye-Kyung;OK Im-Ho;BAI Sungchul C.
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.32 no.4
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    • pp.470-475
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    • 1999
  • This study was conducted to evaluate the utilization of animal by-product mixture (ABPM) as a dietary animal protein source of fish meal replacer, and to determine the effect of dietary chromic oxide in growing rainbow trout, Oncorhynchus mykiss. ABPM is a mixture of five anmial by-products such as meat and bone meal (MBM) feather meal (FM), squid live, powder(SLP), poultry by-product (PBP) and blood- meal (BM) at a specific weight based ratio. Diet 1 and 2 were formulated on a isonitrogenous and a isocaloric basis of $46.5\%$ crude protein and 16.7 KJ/g diet; diet 1 (WFM 100), $100\%$ of the animal protein source came from white fish meal; diet 2 (ABPM 40), $60\%$ WFM+$40\%$ ABPM as the animal protein source; diet 3 (-Cr) commercial diet without chromic oxide; diet 4 (+Cr), commercial diet with chromic oxide. After eight weeks of feeding trials, fish fed diet 2 had a significantly lower body weight gain (WG) and feed efficiency (FE) than that of fish fed the other diets (P<0.05). When comparing diet 3 with diet 4, no significant differences were found in WG and FE (P>0.05). There were no significant differences on condition factor, hematocrit level, serum phosphorus, bone phosphorus, whole body phosphorus, and bone ash among fish from all four diet groups. Fish fed diet 4 had a significantly higher whole body lipid than that of fish fed the other diets (P<0.05), These results indicated that ABPM could be used less than $40\%$ in growing rainbow trout with a sufficient period of acclimation, In addition, the $0.5\%$ of chromic oxide can be used to determine the apparent digestibility of the nutrients in the feed without any adverse effects on growth and body composition.

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Anti-Icing Characteristics of Aluminum 6061 Alloys According to Surface Nanostructure (알루미늄 6061 합금의 표면 나노 구조물 변화에 따른 방빙 특성 연구)

  • Rian, Kim;Chanyoung, Jeong
    • Corrosion Science and Technology
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    • v.21 no.6
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    • pp.476-486
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    • 2022
  • Recently, aluminum 6061 instead of copper alloy is used for cooling heat exchangers used in the internal combustion of engines due to its economic feasibility, lightweight, and excellent thermal conductivity. In this study, aluminum 6061 alloy was anodized with oxalic acid, phosphoric acid, or chromic acid as an anodizing electrolyte at the same concentration of 0.3 M. After the third anodization, FDTS, a material with low surface energy, was coated to compare hydrophobic properties and anti-icing characteristics. Aluminum was converted into an anodization film after anodization on the surface, which was confirmed through Energy Dispersive X-ray Spectroscopy (EDS). Pore distance, interpore distance, anodization film thickness, and solid fraction were measured with a Field Emission Scanning Electron Microscope (FESEM). For anti-icing, hydrophobic surfaces were anodized with oxalic acid, phosphoric acid, or chromic acid solution. The sample anodized in oxalic acid had the lowest solid fraction. It had the highest contact angle for water droplets and the lowest contact hysteresis angle. The anti-icing contact angle showed a tendency to decrease for specimens in all solutions.

Effects of Casein and Protein-free Diets on Endogenous Amino Acid Losses in Pigs

  • Zhang, Yongcheng;Li, Defa;Fan, Shijun;Piao, Xiangshu;Wang, Jitan;Han, In K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.15 no.11
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    • pp.1634-1638
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    • 2002
  • Quantification of endogenous amino acid loss at the terminal ileum is an essential means for calculation of the true amino acid digestibility of a feedstuff. Since nitrogen appeared in the determined diet or not could shift the results very much, also, none of digestibility markers could be recovered with 100% rate at the terminal ileum, the objectives of the present study were: (1) to determine endogenous amino acid losses when fed either a casein diet or a protein-free diet and (2) to examine the reliability of chromic oxide or acid insoluble ash in the protein-free diet. Six ileal-cannulated pigs ($65{\pm}1.85 kg$ BW) with a simple T-cannula in the terminal ileum were used in a replicated $3{\times}3$ Latin square designed trial, after allowed a 14 d recuperation period. Each test period ran for 12 days comprised of a 10 d adjustment period and a 2 d collection period. The endogenous AA losses of His, Ile, Lys, Cys, Thr, Val, Trp, Asp, Glu, and Ser from pigs fed the casein diet were significantly higher than those of the protein-free diet (p<0.05). No significant difference was found in the amount of endogenous amino acid loss when determined with the different markers in the protein-free diet (p>0.05). These data suggest that endogenous amino acid loss could be underestimated when a protein-free diet is used. A direct effect of dietary peptides on the endogenous amino acid loss was found when the casein diet was fed. Our results also indicate that acid insoluble ash can be used as an inert marker as an alternative to chromic oxide when measuring endogenous amino acid loss.

Effects of applied voltages on nano-structures of anodized metal oixdes and their electrochromic applications (인가 전압에 따른 양극산화된 금속 산화물의 나노 구조 변화와 전기변색 응용)

  • Kim, Tae-Ho;Lee, Jae-Uk;Kim, Byeong-Seong;Jeon, Hyeong-Jin;Na, Yun-Chae
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.115.1-115.1
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    • 2016
  • Electrochemical anodization has been interested due to its useful way for the nano-scale architecture of metal oxides obtained from a metal substrate. By using this method, it is easy to control the morphology of the oxide materials by controlling electrochemical conditions. Among oxide materials obtained from the transition metals such as Ti, V, W, etc., in this paper, the morphological study of anodized $TiO_2$ was employed at various voltage conditions in fluoric based electrolyte, and the effects of applied voltage (sweep rate and retention time) on the tube morphologies were investigated. Furthermore, by using anodization of tungsten substrate (W), we fabricated the porous structure of $WO_3$ and provided merits of tailored structure for the hybridization of inorganic and organic materials as electrochromic (EC) applications. The hybrid porous $WO_3$ shows multi-chromic properties during the EC reactions at specific voltage conditions. From these results, the anodization process with tailoring nano-structure is one of the promising methods for EC applications.

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Preparation of Nano Wire by Anodic Oxidation I. Characteristics of Alumina Nano-Template by Anodic Oxidation (양극산화법에 의한 나노와이어 제조I. 알루미나 나노 템플레이트의 특성)

  • Jo, Su-Haeng;O, Han-Jun;Park, Chi-Seon;Jang, Jae-Myeong;Ji, Chung-Su
    • Korean Journal of Materials Research
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    • v.12 no.2
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    • pp.121-128
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    • 2002
  • Anodic alumina layer can be used as templates for preparation of nano-structured materials, because porous oxide layer on aluminum shows a uniform pore size and a high pore density. In order to find out possibility for template material to prepare nano wire, the effects of the anodic applied potential, anodic time and the temperature of electrolyte on pore diameter of anodic alumina layer were studied using SEM and AFM. The pore diameter of anodic alumina layer increased with applied anodic potential and electrolytic temperature. Especially, the pore diameter of anodic oxide layers formed in chromic acid can be well replicated by widening process in $H_3$$PO_4$solution.

The Effect of Coloring Condition on the Surface Characteristic of 304 Stainless Steel (304 스테인리스강의 착색 처리 조건이 표면 특성에 미치는 영향)

  • Kim, Ki-Ho
    • Journal of the Korean institute of surface engineering
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    • v.44 no.5
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    • pp.220-225
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    • 2011
  • 304 stainless steel plate was colored by hot dip and electrochemical treatment in a solution containing sulphuric and chromic acids. In the process, treatment variables such as operating time and methode were changed. The surface characteristics that changed by the treatment of the samples such as surface composition, oxide film thickness, color, surface roughness and reflectivity were studied. Surface composition was varied as follows. Fe was decreased, but Cr and O were increased. Ni was increased until 20 min, but reveals decreasing tendency as time passed after that. These means the surface film becomes chrome rich oxide phase as the treatment times increase. The thickness of film was about 220 nm at 30 min by dip treatment and it reduced as the treatment times increased. On the other hand, the thickness was about 150 nm at 10 min by electrochemical method and it doesn't increased with time. Surface color changed from metallic white of the base plate to gray, black, red, and green-blue, gradually, as the treating time increased. The reflectivity of colored surface measured by UVVIS-NIR spectrophotometer was reduced from max 38% of basis metal to min 3.5%.

A Study on the Physical Properties of Slag-based Glass-Ceramics (Slag를 위주로 한 Glass-Ceramics 의 물리적 성질에 관한 연구)

  • 장승현;정형진
    • Journal of the Korean Ceramic Society
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    • v.17 no.1
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    • pp.27-34
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    • 1980
  • The synthesis of glass-ceramic materials from glasses based on industrial wastes or natural rocks their physical properties were studied. Glasses of composition, CaO14.7∼16.1, MgO7.4∼9.0, Al2O38.3∼19.3, SiO2 48.9∼51.0wt% were prepared from domestic blast furnace slag, serpentine, sea sand and etc. with additions of chromic oxide, and fluoride as nucleating agent. The glasses were subjected to controlled heat treatments and yielded fine microstructure of glass-ceramics which were composed of monocrystalline phase of aluminous diopside. X-ray diffraction techniques were adopted to identify the crystalline phases and to determine the degree of crystallization quantitatively. Density, coefficient of thermal expansion, young's modulus, microhardness and modulus of rupture were measured and the resulting properties were discussed in terms of the heat-treatment conditions, the degree of crystallization, species of crystaline phase, the microstructures formed in glass-cramics and the chemical compositions of mother glasses.

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