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The Effect of Coloring Condition on the Surface Characteristic of 304 Stainless Steel

304 스테인리스강의 착색 처리 조건이 표면 특성에 미치는 영향

  • Kim, Ki-Ho (Department of New Materials Engineering, Chungbuk National University)
  • 김기호 (충북대학교 신소재공학과)
  • Received : 2011.07.28
  • Accepted : 2011.10.28
  • Published : 2011.10.31

Abstract

304 stainless steel plate was colored by hot dip and electrochemical treatment in a solution containing sulphuric and chromic acids. In the process, treatment variables such as operating time and methode were changed. The surface characteristics that changed by the treatment of the samples such as surface composition, oxide film thickness, color, surface roughness and reflectivity were studied. Surface composition was varied as follows. Fe was decreased, but Cr and O were increased. Ni was increased until 20 min, but reveals decreasing tendency as time passed after that. These means the surface film becomes chrome rich oxide phase as the treatment times increase. The thickness of film was about 220 nm at 30 min by dip treatment and it reduced as the treatment times increased. On the other hand, the thickness was about 150 nm at 10 min by electrochemical method and it doesn't increased with time. Surface color changed from metallic white of the base plate to gray, black, red, and green-blue, gradually, as the treating time increased. The reflectivity of colored surface measured by UVVIS-NIR spectrophotometer was reduced from max 38% of basis metal to min 3.5%.

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