• Corrosion Science and Technology
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• v.19 no.4
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• pp.189-195
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• 2020

Two air vents situated on a heat transport pipe in district heating system were exposed to the same environment for 10 years. However, one air vent was more corroded than the other. It also had a hole on the top of the front-end pipe. Comparative analysis was performed for these air vents to identify the cause of corrosion and establish countermeasures. Through experimental observation of the damaged part and analyses of powders sampled from air vents, it was found that corrosion was initiated at the top of the front-end pipe. It then spread to the bottom. Energy dispersive X-ray spectroscopy results showed that potassium and chlorine were measured from the corroded product in the damaged air vent derived from rainwater and insulation, respectively. The temperature of the damaged air vent was maintained at 75 ~ 120 ℃ by heating water. Rainwater-soaked insulation around the front-end pipe had been hydrolyzed. Therefore, the damaged air vent was exposed to an environment in which corrosion under insulation could be facilitated. In addition, ion chromatography and inductively coupled plasma measurements indicated that the matrix of the damaged front-end pipe contained a higher manganese content which might have promoted corrosion under insulation.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.35 no.2
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• pp.143-148
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• 2011

Corrosion at the top of a distillation column is a common problem in refineries and chemical plants. In particular, severe damage has been inflicted in refineries by corrosive materials such as hydrogen sulfide and chlorine. Therefore, the mechanism of the corrosion occurring at the top of a distillation column has been analyzed, and a model for forecasting the corrosion rate has been developed. Four major materials were selected for modeling: $H_2S$, $CO_2$, $H^+$ and $Cl^-$. These were selected by taking into consideration their effect on the corrosion rate. Studies on the transport phenomenon and reaction engineering for this model were carried out, and the reliability of the model was verified on the basis of the data measured at a real refinery.

• Journal of the Korean Ceramic Society
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• v.24 no.1
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• pp.77-85
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• 1987

Hardened cement paste is mainly affected by corrosion of sulphate and chlorine ions in sea water. In this investigation, many specimens were made with the cement clinker minerals such as C3S, C3A, C4AF and their mixture according to cement composition added various blending materials. After the specimens were immersed in 4% MgSO4 and MgCl2 solutions, the product of reaction, the microstructure of specimen and Ca+2 ion leached in the solution were studied. The formation of Ca(OH)2 in the specimen of C3S is reduced relatively by adding pozzolanic admixtures. The chlorine ion is easily diffuse into the C3S specimen and produced CaCl2 compound, and it makes the specimen porous by leaching out itself into the solution. The specimen of C3A, C4AF are broken down by expanding reaction of ettringite and gypsum compound produced in the MgSO4 solution. At a later period, the ettringite is transformed into gypsum and 5MgO.2Al2O3·15H2O. The C3A in the MgCl2 solution combines chlorine ion to form Friedel's salt and prevents the diffusion reaction of chlorine ion into the specimen. Granulated slag shows inferior effect on the resistance of the specimen in MgSO4 solution by forming ettringite and gypsum, but good result in MgCl2 solution. Pozzolanic materials, on the whole, offer noticable effect on the resistance of the specimen in both solutions.

• Journal of the Korean Institute of Telematics and Electronics D
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• v.35D no.1
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• pp.27-33
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• 1998

In this study, chlorine(Cl)-based gas chemistry is generally used to etching for AlCu films metallization.The corrosion phenomena of AlCu films were examined with XPS (X-ray photoelectron spectroscopy), SEM 9Scanning electron microscopy), and TEM (Transmission electron microscopy). SF$_{6}$ plasma treatment sulbsequent to the etching process preventas the corrosion effectively in the pressure of 300 mTorr. It is found that the cholrine atoms on the etched surface are not substituted for fluorine atoms during SF$_{6}$ treatment, but a passivation layer on the surface by fluorine-related compounds would be formed. The passivation layer prevents the moisture penetration on the SF$_{6}$ treated surface and suppresses the corrsion sucessfully.fully.

• Journal of Environmental Science International
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• v.11 no.5
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• pp.445-454
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• 2002

Material exposure experiments were performed to evaluate the relationship between air pollution and material corrosion rates based on collaboration with researchers in China, Japan, and Korea. Qualitative and quantitative atmospheric corrosion was estimated from damage caused to bronze, copper, steel, marble, cedar, cypress, and lacquer plates exposed to outdoor and indoor conditions in certain East Asian cities. The effects of atmospheric and meteorological factors on the damage to the copper plates and marble pieces were estimated using a regression analysis. The results indicated that sulfur dioxide produced the most destruction of the materials, especially in South Korea and China. In Japan, the copper plates were damaged as a result of natural conditions and sea salt. Copper was also found to be damaged by the surface deposition of sulfur and chlorine. Meanwhile, marble was substantially degraded by gaseous sulfur dioxide, yet sulfate ions in rain had no effect. Accordingly, the analysis of air pollution from the perspective of material damage was determined to be very useful in evaluating and substantiating the intensity of air pollution in East Asia.

• Journal of Korean Society of Water and Wastewater
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• v.34 no.5
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• pp.373-383
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• 2020

The purpose of this study was to evaluate the corrosion damage of large diameter metallic pipes buried in reclaimed land due to the corrosion effect by soil, and to propose a method of installing metal pipes in the reclaimed land. The results are as follow. First, the soil of the reclaimed land was gray clay, the soil specific resistance indicating soil corrosiveness was at least 120 Ω-cm, the pH was weakly acidic(5.04 to 5.60), the redox potential was at least 62 mV, the moisture content was at most 48.8%, and chlorine ions and sulfate ions were up to 4,706.1 mg/kg and 420 mg/kg. Therefore, the overall soil corrosivity score was up to 19, and the external corrosion effect seems to be very large. Second, the condition of straight part of pipes was in good condition, but most of KP joints were affected by corrosion at a severe level. The reason for this seems to be that KP joints accelerated corrosion due to stress and crevice corrosion in addition to galvanic corrosion in the same environment. Third, as a result of evaluating correlations of each item that affects the corrosion on the external part, the lower the soil resistivity and redox potential, the greater the effect on the KP joints corrosion, and the moisture content, chloride ion, and sulfate ion, the higher the value, the greater the effect on the corrosion of KP joints. In addition, among soil corrosion items, the coefficient of determination of soil resistivity with corrosion of KP joints was the highest with 0.6439~0.7672. Fourth, when installing metal pipes or other accessories because the soil of the reclaimed land is highly corrosive, it is necessary to apply a corrosion preventive method to extend the life of pipes and prevent leakage accidents caused by corrosion damage to the joint.

• Computers and Concrete
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• v.26 no.4
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• pp.367-375
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• 2020

Today, the use of special technologies in the admixture of concrete has made tremendous progress, but the problem that has always existed in the construction of concrete members is the brittleness and lack of loading bearing after cracking, which leads to reduced strength and energy absorption. One of the best ways to fix this is to reinforce the concrete with steel fibers. Steel fibers also control cracks due to dry shrinkage, reduce structural crack width, and improve impact resistance. In this study, recycled steel fibers from worn tires have been used in the manufacture of concrete samples, the secondary benefits of which are the reduction of environmental pollution. One of the disadvantages of steel fiber reinforced concrete is the corrosion of steel fibers and their deterioration in harsh environments such as coastal areas. Corrosion caused by chlorine ions in metal fibers causes deterioration and early decommissioning of structures in corrosive environments. In this study, the effect of the dosage of steel fibers (dosages of 15, 30, and 45 kg of fibers per cubic meter of concrete) and aspect ratio of fibers (aspect ratio of 25 and 50) on compressive and flexural strength of concrete samples are investigated. In the following, the effect of fiber corrosion on the results of the mechanical properties of concrete samples is examined. The results show that the increase in fiber causes a relative increase in compressive strength, and a significant increase in flexural strength, and corrosion of steel fibers without reducing workability reduces compressive strength and flexural strength by up to 6 to 11%, respectively.

• Corrosion Science and Technology
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• v.9 no.5
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• pp.187-195
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• 2010

Hyper duplex stainless steels have been developed in Korea for the purpose of application to the seawater system of Korean nuclear power plants. This system supplies seawater to cooling water heat exchanger tubes, related pipes and chlorine injection system. In normal operation, seawater is supplied to heat exchanger through the exit of circulating water pump headers, and the heat exchanged sea water is extracted to the discharge pipes in circulating water system connected to the circulating water discharge lines. The high flow velocity of some part of seawater system in nuclear power plants accelerates damages of components. Therefore, high strength and high corrosion resistant steels need to be applied for this environment. Hyper duplex stainless steel (27Cr-7.0Ni-2.5Mo-3.2W-0.35N) has been newly developed in Korea and is being improved for applying to nuclear power plants. In this study, the physical & mechanical properties and corrosion resistance of newly developed materials are quantitatively evaluated in comparative to commercial stainless steels in other countries. The properties of weld & HAZ (heat affected zone) are analyzed and the best compositions are suggested. The optimum conditions in welding process are derived for ensuring the volume fraction of ferrite(${\alpha}$) and austenite(${\gamma}$) in HAZ and controlling weld cracks. For applying these materials to the seawater heat exchanger, CCT and CPT in weldments are measured. As a result of all experiments, it was found that the newly developed hyper duplex stainless steel WREMBA has higher corrosion resistance and mechanical properties than those of super austenitic stainless steels including welded area. It is expected to be a promising material for seawater systems of Korean nuclear power plants.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.8
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• pp.798-807
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• 2008

Due to economic impairment derived from metal corrosion of pumping station installed around coastal area, it was needed for related cause-effect to be investigated for understanding practical corrosion behavior and providing proper control. This research was thus carried out to determine whether the microbe can influence on metal corrosion along with its control in the laboratory. For this study, groundwater was sampled from the underground pump station(i.e. I Gas Station) where corrosion was observed. Microbial diversity on the samples were then obtained by 16S rDNA methods. From this, microbial populations showing corrosion behaviors against metals were reported as Leptothrix sp.(Iron oxidizing) and Desulfovibrio sp.(Sulfur reducing) Iron oxidizing bacteria were dominantly participating in the corrosion of iron, while sulfate reducing bacteria were more preferably producing precipitate of iron. In case of galvanized steel and stainless steel, iron oxidizing bacteria not only enhanced the corrosion, but also generated its scale of precipitate. Sulfate reducing bacteria had zinc steel corroded greater extent than that of iron oxidizing bacteria. In the inactivation test, chlorine or UV exposure could efficiently control bacterial growth. However as the inactivation intensity being increased beyond a threshold level, corrosion rate was unlikely escalated due to augmented chemical effect. It is decided that microbial corrosion could be differently taken place depending upon type of microbes or materials, although they were highly correlated. It could be efficiently retarded by given disinfection practices.

• Journal of the Microelectronics and Packaging Society
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• v.6 no.1
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• pp.75-79
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• 1999

We have studied electrical properties of polyimide for the next generation interlayer low dielectric during plasma etching. Dielectric constant of polyimide exposed to Cl-based plasma, which is used in aluminum etching, increased, while that of polyimide exposed to $SF_{6}$ plasma decreased. The results are related to fluorine or chlorine bonds as examined by FTIR ana XPS analyses. So, we expect that Cl-based 1)miasma etching of aluminum followed by $SF_{6}$ plasma exposure results in the prevention of post-etch corrosion and decrease of dielectric constant.